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《Journal of Hunan University (Natural Science)》 2003-03
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Consistency among Reaction Rate Equation and State Equations of Solid Explosive

HUAN Shi1 , ZHANG Zhengyu2(1.Dept of Engineering Mechanics, Hunan Univ,Changsha410082,China;2.Dept of Applied physics,National Univ of Defense Technology, Changsha410073,China)  
The constitutive relationships for describing the initiation and detonation in solid explosives are composed of state equations of explosive and its products,reaction rate equation and their mixing law.Because the state equations and the reaction equation have many forms,each of which is calibrated independently,but they are compatible with a supposed mixing law,so the compatibility is not verified.Moreover,the guarantee of using the constitutive relationships to describe the chemical nonequilibrium state under high pressure and high temperature in reaction zone is not verified.The method of using Lagrangian tests and analysis techinque is suggested for determing the consistency of the constitutive relationships?The constitutive relationships of three condensed explosives (TNT) have been calibrated,they are used directly in onedimensional numerical simulations,and fairly well simulate the results of Lagrangian tests and wedge tests.
【Fund】: 国家自然科学基金委员会——中国工程物理研究院联合基金资助项目(10276015)
【CateGory Index】: O381
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