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《Journal of South China University of Technology(Natural Science Edition)》 2008-07
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Effects of Extrinsic Physical Fields on the Coordinated Reaction for Chitosan-Fe(Ⅱ)

Jiang Yin Wang Zhao-mei Ye Sheng-quan Guo Hua Guo Si-yuan(Research Institute of Light Industry and Chemical Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China)  
The effects of several extrinsic physical fields,such as the magnetic field,the ultrasonic wave and the microwave irradiation,on the rate and yield of chitosan-Fe(Ⅱ) complexing reaction were investigated.The results show that ultrasonic has the greatest effect on the reaction rate and complexing capacity,followed by the magnetic field and the microwave irradiation,and that there is a threshold for the enhancement by the physical fields.UV and IR spectra show that the structure of chitosan-Fe(Ⅱ) complex treated with magnetic field is almost the same as that of the control.The authors also propose the enhancement mechanisms of the complexing reaction by the three physical fields in the end.
【Fund】: 高等学校博士学科点专项科研基金资助项目(20050561014)
【CateGory Index】: O641.4
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