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《Journal of Huaqiao University(Natural Science)》 2004-02
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Solid Phase Grafting Polymerization of Octyl Methacrylate onto Polypropylene

Lin Shuidong ① Lin Zhiyong ② Xiao Fengying ② (① Longyan Normal College, 364000, Longyan, China; ② Dept. of Mater. Sci. & Eng., Huaqiao Univ., 362011, Quanzhou, China)  
Polypropylene(PP) grafted octyl methacrylate(OMA)was prepared by solid state phase grafting polymerization. Under the protection of nitrogen, the authors investigated the effects of reaction temperatwre, reaction time, initiator concentration and monomer amount on solid phase graft percentage. The results showed a high graft percentage up to 7.46% under optimum conditions. These reaction conditions include: BPO amount of 0.20%, reaction time of 4 hrs, reaction temperature of 80 ℃, and OMA monomer amount of 1.0me. Structural Characterization of graft polymer was performed by Infrared spectrograph and differential scanning calorimeter.
【Fund】: 福建省自然科学基金资助项目 (E0 2 0 6 )
【CateGory Index】: TQ325.14;TQ316
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