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《Chemical Sensors》 2004-04
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Preparation of poly(thionine) nanoparticles modified electrode and its application to determine hemoglobin

Zhang Cheng-lin, Liu Mei-chuan, Li Ping, Zhang Li, Cheng Yu-xiao, Jin Li-tong~*(Department of Chemistry, East China Normal University, Shanghai 200062, China)  
A poly(thionine) nanoparticles modified glassy carbon electrode had been prepared by a novel two-step eleetrepolymerization method. Atomic force microscopy (AFM), UV-vis spectrum and Fourier Transform Infrared Spectrometry (FTIR) were used to evaluate poly(thionine) nanoparticles. The electrochemical properties of poly (thionine) nanoparticles as well as the electrochemical behaviors of hemoglobin(Hb) on PTn/GCE had been studied. The results showed that the modified electrode exhibited significantly electroeatalytie activity for the reduction of Hb, and the reduction currents were linear to the concentrations of Hb in aqueous solutions. In addition, the results of flow injection analysis (FIA) further suggested high stability and reproducibility of PTn/GCE and this method was applied to the determination of hemoglobin (Hb) of whole blood.
【Fund】: 国家自然科学基金(No.20175006)资助项目
【CateGory Index】: Q503
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