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《Chemical Reaction Engineering and Technology》 2008-03
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Optimization of Cyclohexanol Synthesis from Hydration of Cyclohexene

Shah Xianglei Cheng Zhenmin (State Key Laboratory of Chemical Engineering,East China University of Science and Technology,Shanghai 200237,China)  
Effects of molar ratio of SiO_2 to Al_2O_3,particle size of HZSM-5 zeolite and the operating conditions were investigated on the catalytic hydration of cyclohexene to cyclohexanol.The experimental results showed that the catalytic performance of HZSM-5 (SiO_2/Al_2O_3=25) with small particle size was the best.The optimal condition for the hydration of cyclohexene was temperature 120℃,HZSM-5 zeolite mass fraction 30% and volumetric ratio of aqueous to organic phase 1:2. The yield of cyclohexanol was 15.4% in reaction 3 h under the optimal conditions.
【CateGory Index】: TQ233.1
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【Citations】
Chinese Journal Full-text Database 5 Hits
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【Co-citations】
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