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《Progress In Chemistry》 2007-01
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Ring-Opening Polymerization of Ethylene Oxide and Propylene Oxide

Zhang Zhiguo~(**) Yin Hong(UNILAB Research Center of Chemical Reaction Engineering,Zhejiang University,Hangzhou 310027,China)  
Polyether(primarily homopolymers and copolymers of ethylene oxide and propylene oxide) which has the properties of excellent surface activity,flexibility of hydrophile_lipophile balance(HLB) and low toxicity has been widely used in surfactant and polyurethane industries.The progress in the catalytic ring-opening polymerization of ethylene oxide and propylene oxide is reviewed in this paper.The different catalytic mechanisms of cationic catalysts,anionic catalysts and coordination catalysts are discussed respectively.The application of coordination catalysts in the catalytic ring-opening polymerization is intensively introduced and the further research trends are pointed out.
【Fund】: 浙江省科技计划项目资助(No.2004C31058)
【CateGory Index】: TQ316.341
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