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《Progress in Chemistry》 2009-04
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Environmental-Friendly Synthesis of Adipic Acid by Catalytic Oxidation

Ren Shuiying Xie Zhengfeng Xie Xiaopeng Qin Gaofei Wang Jide(Key Laboratory of Oil & Gas Fine Chemicals,Ministry of Education,Xinjiang University,Urumqi 830046,China)  
Adipic acid is a most important organic synthetic intermediate,and much attention has been paid for its green synthesis process because of disadvantages in current technology.In this paper,recent developments on catalytic oxidation systems of environmental-friendly synthesis of adipic acid are reviewed,in which hydrogen peroxide,oxygen or ozone is used as clean oxidant and cyclohexene,cyclohexone and/or cyclohexanol as substrate.The focus is especially on the catalytic system of tungstate-H_2O_2,and several other new synthetic methods of adipic acid are also summarized.At the same time,advantages and disadvantages of each catalytic system are discussed on the aspects of solvent,yield and post-processing.Based on the discussions for these systems,the supported catalyst-hydrogen peroxide system will be a perfect one for the industrialization in the future.
【Key Words】: adipic acid catalytic oxidation hydrogen peroxide oxygen environmental-friendly oxidation
【Fund】: 教育部新世纪优秀人才支持计划项目(No.NCET-04-0987);; 新疆维吾尔自治区科技攻关重大专项项目(No.200732139-3)资助
【CateGory Index】: TQ225.146
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