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《Chemical Reagents》 2003-05
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Synthesis and studies on fluorimetric quenching reaction be- tween beryllium and a new spectrofluorimetric reagent 2-hy- droxy-1-naphthaldehydene-hydrazinecarbothioamide

GE Xiao-xia, LIU Jin-kai, JIANG Chong-qiu" (Department of Chemistry, Shandong Normal University, Jinan 250014), Huaxue Shiji, 2003,25(5), 279-281  
A new fluorescent reagent 2-hydroxy-l-naphth-aldehydene-hydrazinecarbothioamide was synthesized. This reagent exhibited fluorescent excitation and emission maxima at 406 and 460nm, respectively. In pH 8. 7 buffer solution the reaction of this reagent with beryllium, magnesium, calcium, strontium and barium formed complexes to cause the quenching of its fluorescence . The smaller the ionic radius of the alkali earth metals, the greater their fluorescence quenching was. Based on this a method for the determination of beryllium was developed. The linear range of the method was from 0. 0 to 40 μg/L. The detection limit was 1. 42 μg/L. The relative standard deviation was 0.86%. Interferences of other ions were studied. The method has been successfully applied to the determination of beryllium in tap water and mineral water.
【CateGory Index】: O625.7
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