Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Chemical Reagents》 2010-10
Add to Favorite Get Latest Update

Study on synthesis and adsorption property of molecularly imprinted polymer of semicarbazide

GAO Wen-hui,PEI Hong,YANG Gui-jun (College of Biological Science and Engineering,Hebei University of Science and Technology,Shijiazhuang 050018,China)  
A series of molecularly imprinted polymers(MIP) were prepared in different solvents using semicarbazide as the template molecule,methacrylic acid as the functional monomer and ethylene glycol dimethacrylate as the cross-linker.The effects of the composition of polymerization systems on the adsorption property of MIP were investigated and subjected to the Scatchard analysis.The results indicated that the best adsorption property between MIP and the template was obtained under the following conditions:the ratio of template to functional monomer was 1∶4,and the solvent was CH3OH/CH3CN(at a ratio of 1∶1,V/V),and a kind of the same binding sites which could specially bind semicarbazide by the interaction of hydrogen bonding was formed in the polymer with its dissociation constant equating to 1.44 mmol/L.
【Key Words】: semicarbazide molecular imprinting polymers adsorption property selectivity of identification
【Fund】: 河北省自然科学基金资助项目(B2008000669);; 河北省科技厅重大科技支撑项目(09227134D);; 河北省科技支撑计划项目(10276902D)
【CateGory Index】: O631.3
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 1 Hits
1 SHEN Yan-zheng1,CHEN Si1,WANG Su-fang2,TANG Hong-zhe1,ZHANG Li-bin1,GUI Xiang1,HE Juan*1(1.School of Chemistry and Chemical Engineering,Henan University of Technology,Zhengzhou 450001,China;2.Henan Entry-Exit Inspection And Quarantine Bureau of P.R.C.,Zhengzhou 450003,China);Synthesis and optimization of molecularly imprinted microspheres for ethyl paraben[J];Chemical Reagents;2012-06
【Citations】
Chinese Journal Full-text Database 4 Hits
1 LI Li~1,HU Shu-Guo~1,HE Xi-Wen~(1*),LI Wen-You~1,CHEN Lang-Xing~1,ZHANG Yu-Kui~(1,2*)(1.College of Chemistry,Nankai University,Tianjin 300071,China;2.Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,China);Solid-phase Extraction of Active Component of Chinese Traditional Medicine Fisetin by Using Molecularly Imprinted Polymers[J];Chemical Journal of Chinese Universities;2006-04
2 HOU, Neng-Bang LIU, Yuan-Lin WANG, Guo-Song ZHU, Xiu-Fang DING, Zhong-Tao CAO, Qiu-E* (Key Laboratory of Medicinal Chemistry for Natural Resource of Ministry of Education, Department of Chemistry, Yunnan University, Kunming 650091);Studies on Preparation and Characteristics of Molecular Template Polymer with Coumarin[J];Acta Chimica Sinica;2006-16
3 SHENG Wei,LI Ji,XU Ting(College of Resource and Environment,China Agricultural University,Beijing 100094,China);Advances of Detection for Residues of Nitrofuran and Analoguesin Foods Derived from Animals[J];Journal of Agro-Environment Science;2006-S1
4 Zhou Jie,He Xiwen (Department of Chemistry,Nankai University,Tianjin 300071);Application of Molecular Template Polymers in Analytical Chemistry[J];JOURNAL OF INSTRUMENTAL ANALYSIS;1998-05
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 YANG Xiao-ping,XIE Yue-qin,DING Ru(Department of Chemistry and Chemical Engineering,Hefei Normal University,Hefei 230061,China);HPLC Determination of "Exclamation Mark" Brand Compound Paracetamol and Amantadine Hydrochloride Tablets Caffeine[J];Journal of Hefei Normal University;2011-03
2 XI Shan,HU Xiao-ling,LIANG Liang,GAO Jie(Department of Applied Chemistry,School of Science,Northwestern Polytechnical University,Xi'an 710072,China);Progress in Preparation of New Molecularly Imprinted Polymer Hybrid Membranes[J];Development and Application of Materials;2010-06
3 GAN Ning1,LI Rong-sheng1,CHEN Ya-dong1,2,XU Wei-Ming1,CAO Yu-ting1(1.The State Key Laboratory base of Novel Functional Materials and Preparation science,The Faculty of Materials science & Chemical Engineering,Ninbo University,Ningbo 315211,China;2.Huafeng Institute of Ningbo Career College,Ningbo 315200,China);Determination of Four Tea Catechins Content with Molecular Imprinting-SPE Extraction and Electrospray Mass Spectrometry[J];Journal of Tea Science;2009-03
4 YANG Xin1,2,ZHANG Hua1,DONG Aijun1,ZHANG Yingchun1,ZHAO Haitian1,YAO Lei1,SHE Yongxin2,WANG Jing2(1.School of Food Science and Engineering,Harbin Institute of Technology,Harbin 150090,China;2.Chinese Acedemy of Agricutureal Sciences,Beijing 100081,China);Application of molecular imprinting technology in separation and purification of active ingredients from natural products[J];Journal of Northeast Agricultural University;2011-08
5 YOU Jing CHEN Shulian WANG Guojun LU Haojie (Lanzhou Institute of Chemical Physics, the Chinese Academy of Sciences Lanzhou 730000);Molecular Imprinting Technique[J];ANALYSIS AND TESTING TECHNOLOGY AND INSTRUMENTS;1999-04
6 Lai Jiaping, He Xiwen *, Guo Hongsheng (Department of Chemistry, Nankai University, Tianjin 300071) Liang Hong (Chemistry and Life College, Guangxi Normal University, Guilin 541004);A Review on Molecular Imprinting Technique[J];Chinese Journal of Analytieal Chemistry;2001-07
7 XUE Min1,WANG An1,WANG Yu2,WANG Dan1,L Zhi1, MENG Zi-Hui1,ZHANG Wei-Bing2 1(School of Chemical & Environmental Engineering,Beijing Institute of Technology,Beijing 100081) 2(School of Chemistry & Molecularly Engineering,East China University of Science & Technology,Shanghai 200237);Application of Molecularly Imprinted Solid Phase Extraction for Determination of Estrogens in River Water,Milk and Urine Samples[J];Chinese Journal of Analytical Chemistry;2011-06
8 ZHOU Jie, HE Xi wen (The State Key Lab of Functional Polymer Materials for Adsorption and Separation, Department of Chemistry, Nankai University, Tianjin, 300071);Preparation of a New Kind of Biomimetic Analytical Reagents ——Recent Progress of Molecular Template Technique[J];JOURNAL OF ANALYTICAL SCIENCE;2000-02
9 FU Ruo-nong(Department of Chemistry,Beijing Institute of Technoligy,Beijing 100081);Advances on SPE-chromatography in China in recent two years[J];Chinese Journal of Analysis Laboratory;2007-02
10 Feng Xiwen1,Du Ping2,Zhang Li2(1.School of Material and Chemical Engineering,Sichuan University of Science & Engineering,Zigong 643000;2.School of Chemistry and Pharmaceutical Engineering,Sichuan University of Science & Engineering,Zigong 643000,China);The Application of Molecular Imprinting Technologies on Active Ingredients Extraction and Purifica tion from Natural Drug[J];Guangdong Chemical Industry;2011-02
China Proceedings of conference Full-text Database 1 Hits
1 He Jun(Department of Pharmacy,China-Japan friendship hospital,Beijng 100029);Studies on molecular imprinting technology in the separation andpurification of natural products[A];[C];2012
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 CUI Wei-wei et al (Faculty of Natural Resource and Information Technology,China University of Petroleum(Beijing) Beijing 102249);Advance in Studies on the Harms and Exposure of Pesticide Residues[J];Journal of Anhui Agricultural Sciences;2010-02
2 LV Lin-lan et al (College of Chemistry and Biology Engineering,Yancheng Institute of Technology,Yancheng,Jiangsu 224003);The Effect of Malathion on the Activity of Antioxidant Enzyme of Perinereis aibuhitensis Grube[J];Journal of Anhui Agricultural Sciences;2010-11
3 SUN Tai-fan (College of Arts and Sciences,Heilongjiang August First Land Reclamation University,Daqing,Heilongjiang 163319);Enzyme-Linked Immunosorbent Assay and Application in Pesticide Residues Analysis[J];Journal of Anhui Agricultural Sciences;2010-22
4 ZHAO Guang-chao,XU Ya-qi(College of Environmental Science and Engineering,Anhui Normal University,Wuhu 241003,China);An Electrochemical Platform for Selective Response to Parathion Based on Molecularly Imprinted Membrane Technique[J];Journal of Anhui Normal University(Natural Science);2010-03
5 SU Lei,WU Gen-hua,WANG Zhu-qing(School of Chemistry and Chemical Engineering,Anqing Teachers College,Anqing 246011,China);Preparation and Property of Microspheric Cu(Ⅱ) Ion Imprinted Polymer[J];Journal of Anqing Teachers College(Natural Science Edition);2010-01
6 LIU Yanyan,WU Yaoguo,CHAO Jifu,LIU Kai,YU Xiuju(Department of Applied Chemistry,School of Science,Northwestern Polytechnical University,Xi'an 710129);Preparation of Surface Molecular Imprinting Microspheres and Its Application in Water Treatment[J];Materials Review;2011-07
7 FENG Jian-yong,ZHU Quan-hong,LUO Jia-bo School of Traditional Chinese Medicine,Southern Medical University,Guangzhou 510515,China;Removal of the template molecules from vinblastine-imprinted polymer[J];Journal of Southern Medical University;2007-03
8 Hong Jiang-xing (Analytical and TestingCenter,Fuzhou University,Fuzhou,Fujian350002,China);Determination of Anthraquinone in Hydrogen Peroxide Working-solution by High Performance Liquid Chromatography[J];Fujian Analysis & Testing;2010-03
9 Feng Ningchuan, Gong Guoquan * (College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000);Determination of Protein with Brilliant Yellow by the Rayleigh Light Scattering Method Using Triton X-100 as Sensitizer[J];Chinese Journal of Analytieal Chemistry;2002-04
10 Du Xiaoyan, Peng Tao, Li Junsuo  (College of Veterinary Medicine, Chinese Agriculture University, Beijing 100094);Preparation and Binding Characteristics of Molecularly Imprinted Polymers for Sarafloxacin[J];Chinese Journal of Analytical Chemistry;2003-06
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 Meng Zihui. (Institute of Pharmacology and Toxicology, Academy of Military Medical Sciences, Beijing 100850) Zhou Liangmo, Wang Jinfang, Wang Qinghai, Zhu Daoqian (Dalian Institute of Chemical and Physics, Chinese Academy of Sciences, Dalian 116012);The Structure Characterization for Molecule Imprinting polymers and the Thermodynamic Study in the Chiral Separation Process[J];CHINESE JOURNAL OF ANALYTIEAL CHEMISTRY;2000-08
2 You Jing, Lao Wenjian, Huang Minjia, Wang Guojun (Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000);A Study of Molecular Imprinted Polymer as the Adsorbent in the Clean-up Step after Supercritical Fluid Extraction[J];Chinese Journal of Analytieal Chemistry;2002-05
3 Zuo Yanjun, Yu Jianhua, Huang Qibin* (Institute of Chemical Defence, Beijing 102205) Lin Yuan (Center of Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100101);The Preparation of Molecularly Imprinting Nanometer Layer and Its Application in Detecting Nerve Agent Sarin[J];Chinese Journal of Analytical Chemistry;2003-07
4 Yin Junfa 1, Yang Gengliang 1,2 , Li Zhiwei 1, Liu Haiyan 1, Fan Zilin 1, Chen Yi 2 1(College of Chemistry and Environmental Science, Baoding 071002) 2(Center for Molecular Science, Institute of Chemistry, Chinese Academy of Science, Beijing 100080);Determination of Stachyose in Stachys Sieboldii Miq. by High Performance Liquid Chromatography with Evaporative Light Scattering Detection[J];Chinese Journal of Analytical Chemistry;2003-12
5 YU Jian-xin, HU Xiao-zhong, LIN Yan-fei, WANG Peng, LI Ya-fei, LI Jin (Technology Center of Hubei Entry-Exit Inspection and Quarantine Bureau, Wuhan 430022);High-performance Liquid Chromatography-tandem Mass Spectrometry for the Determination of the Metabolites of Nitrofuran Antibiotics in Honey and Shrimp[J];Journal of Analytical Science;2004-04
6 GUO Hong Sheng, HE Xi Wen , DENG Chang Hui, LI Yi Jun (Department of Chemstry, The Key Lab of Functional Polymer Materials for Adsorption and Separation, Nankai University, Tianjin 300071, China);Studies of Selective Enrichment and Recognized Characteristics of Paracetamol Molecular Template Polymer[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;2000-03
7 CAO Guo-Ying HU Xing SONG You-Hua FU De-Xing (Beijing Hospital, Beijing,100730);Nonsulfonylurea PGR--Nateglinide[J];The Chinese Journal of Clinical Pharmacology;2001-03
8 WANG Jin - Fang ZHOU Liang - Mo MENG Zi - Hui WANG Qing - Hai ZHU Dao - Qian ( Dalian Institute of Chemical Physics , The Chinese Academy of Sciences , Dalian, 116012 ) ( The People' s Liberation Army Academic of Military Medicine Sciences , Beijing, 100850 );Highly Efficient Molecule Imprinting Chiral Stationary Phase Utilizing Combined Basic Functional Monomers[J];Acta Chimica Sinica;1999-10
9 XIE, Jian-Chun ZHU, Li-Li XU, Xiao-Jie (College of Chemistry and Molecular Engineering, Beida Yangshengtang Laboratory for Natural Products, Peking University, Beijing 100871);Efficient Separation and Identification of Active Compounds from Herb by Combining Molecular Imprinting Affinity Chromatography with Mass Spectrometry[J];Acta Chimica Sinica;2002-03
10 LU, Chun-Yang MA, Xiang-Xia HE, Xi-Wen* LI, Wen-You CHEN, Lang-Xing (Department of Chemistry, State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Nankai University, Tianjin 300071);Preparation and Selective Permeation Characterization of Molecularly Imprinted Membranes with o-Vanillin as Template[J];Acta Chimica Sinica;2005-06
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved