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《Chemical World》 2009-08
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Preparation and Phase Behavior of Microemulsion of Gemini Surfactant

ZHONG Yu,LIU Chuan-fang,BIAN Jie-ping(Department of Chemistry and Life Sciences,Wanxi University,Anhui Lu'an 237012,China)  
The microemulsion of the gemini surfactant/alcohol/alkane/water system was prepared using sodium α-sulfonated stearic acid polyethyleneglycol diester.The pseudo-ternary phase diagrams were constructed.The influence of various alcohols with different carbon chain length 0.1 mol/L KCl,NaOH and HCl on the microemulsion was investigated.Furthermore,the structure of microemulsion was analyzed with its conductivity.The results showed that stable microemulsion could be prepared with sodium α-sulfonated stearic acid polyethyleneglycol diester as emulsifier.For auxiliary surfactant,the increase of carbon length was of advantage to formation and stabilization of the microemulsions within middle range.In general,the microemulsion area was shrinked in electrolyte solution.The trend of conductivity change of the microemulsion in electrolyte solution and water was similar.
【Fund】: 安徽省教育厅自然科学研究项目资助(2006KJ027C);; 皖西学院青年研究项目资助(WXZQ0503)
【CateGory Index】: TQ423.11
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