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《Chemistry》 2011-09
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Aspects of Recent Developmemts of Chemical Multiway Calibration Methodologies

Wu Hailong,Yu Ruqin# (State Key Laboratory of Chemo/Biosensing and Chemometrics,College of Chemistry and Chemical Engineering,Hunan University,Changsha 410082)  
Multiway calibration methodologies are gaining more and more attention in the field of analytical chemistry.Multivariate calibration(two-way calibration,first-order calibration) methods including PCR and PLS methods have been widely applied,for instance,in on-site real-time analysis and on-line monitoring and control coupled with near-infrared spectroscopy.Three-way calibration(second-order calibration) methods have many advantages:(1)it is a smart and green quantitative analysis strategy based on "mathematical separation" for complex chemical systems when combined with advanced instruments capable of generating multidimensional arrays,such as EEMs,HPLC-DAD and LC-MS;(2) it enables one to quantify the component(s) of analytical interest even in the presence of unknown interferences not included in the calibration samples,which has been known as "second-order advantage".It makes the final goal of analytical chemistry achievable even without the aid of complicated separation procedures.Some multiway calibration algorithms based on the alternating(weighted) least-squares principle have been introduced in the past decades.These methods especially three-way calibration can be used to resolve different problems of qualitative and quantitative analysis in complex chemical systems.They have been applied to simultaneous or direct determinations of multiple components of analytical interest in many fields such as food,environmental,biomedical,pharmaceutical sciences.The main points on successful applications of these chemometric methods combined with analytical instruments have been also summarized.
【Fund】: 国家自然科学基金项目(29735150 29975007 20475014 20775025);; 国家科技部973预研课题(2007CB216404);; 国家教育部创新团队项目资助
【CateGory Index】: O651
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Chinese Journal Full-text Database 10 Hits
1 NIE Lanying,WANG Gang,JIN Dan,ZHANG Ning Editorial Department of Chinese Journal of Orthopaedic Trauma,510515,Guangzhou,China;Building of teams of peer reviewers for academic journals[J];Acta Editologica;2008-03
2 Zhu Xia;Chen Huanjiang;Sun Zhaocai;Zhang Yuchang Institute of Petroleum Geology, Ministry of Geology and Mineral Resources;THE MESOZOIC-CENOZOIC TECTONICS AND PETROLIFEROUS BASINS OF CHINA[J];Acta Geological Sinica;1983-03
3 WANG Xue-Mei,WU Hai-Long,NIE Jin-Fang,YU Ru-Qin(State Key Laboratory of Chemo/Biosensing and Chemometrics,Hunan University,Changsha 410082);Rapid Determination of Bitertanol Content in Banana Using Three Dimensional Fluorescence Coupled with Second-order Calibration[J];Chinese Journal of Analytical Chemistry;2009-06
4 WU Hai long, LIANG Yi zeng and YU Ru qin (College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082), Fenxi Shiyanshi,1999,18(6):94~102;Analytical Chemometrics[J];ANALYTICAL LABORATORY;1999-06
5 梁逸曾? 俞汝勤(湖南大学化学化工学院化学计量学与化学传感技术研究所 长沙 410082);化学计量学在我国的发展[J];CHEMISTRY;1999-10
6 Cai Qing,Wu Hailong*,Li Yuanna,Tang Leiming,Liu Yixuan,Yu Ruqin#(State Key Laboratory of Chemo/Biosensing and Chemometrics,The National Basic Chemistry Experimental Teaching Demonstration Center,Hunan University,Changsha 410082);Rapid Determination of α-Naphthylacetic acid and Indole-3-acetic acid in Fruits Extract by using Three-Dimensional Fluorescence Coupled with Second-order Calibration Method[J];Chemistry;2011-01
7 WANG JianYao, WU HaiLong, ZHANG Juan, ZHANG XiaoHua & YU RuQin State Key Laboratory of Chemo/Biosensing and Chemometrics; College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China;Determination of adriamycin in cell culture media by using excitation-emission matrix fluorescent spectra coupled with second-order calibration[J];Scientia Sinica(Chimica);2011-05
8 Zhang Huifeng, Wu Hailong , Xia Alin, Zhu Shaohua and Yu Ruqin State Key Laboratory of Chemo/Biosensing and Chemometrics; Collage of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, Hunan, China.;Determination of polycyclic aromatic hydrocarbons by using matrix fluorescence spectra coupled with second-order calibration algorithms[J];Computers and Applied Chemistry;2007-01
9 DAI Min, NIE Tao, YAO Hao-qun,OUYANG Hui,ZHONG Shi-zhang,LI Ming-jing (Department of Orthopaedics Surgery, The First Affiliated Hospital, Jiangxi Medical College, Nanchang 330006, China);The Investigation and Analysis of the Short-term Effectiveness of Periodic Blocked Regional and High-dose Arterial Limb Infusion for Chemotherapy of Osteosarcoma[J];Acta Academiae Medicinae Jiangxi;2005-02
10 ZHU Xin-xia;Analysis on the Innovation of Document Bibliography of ZHENG Qiao[J];Sci-Tech Information Development & Economy;2008-11
Chinese Journal Full-text Database 10 Hits
1 Fang Guozhen, Fang Mei and Wang Jing(Department of Chemistry, Sichuan University, Chengdu 610064; Institute of Chemistry, Academy of Sciences of China, Beijing 10080);Application of Chromometrics to Species Analysis for Elements by Atomic Emission Spectrometry[J];Sichuan Nonferrous Metals;1999-01
2 SI Sheng-zhu(Department of Chemistry,Anhui Institute of Education,Hefei,230061);A Multivariate Calibration Method of Partial Least Square Technique for Simultaneous Determination of Pigments in Ternary Mixtures[J];Journal of Anhui Institute of Education;2006-03
3 SI Sheng-zhu,WANG Li-ping,DONG Xiong-zi(Department of Chemistry and Chemical Engineering,Hefei Normal University,Hefei 230061,China);Study on Simultaneous Determination of Pigments in Tetrad Mixtures by Spectrophotometry with Wavelet Transform-Principal Component Regression Method[J];Journal of Hefei Teachers College;2009-06
4 CHENG Zi-yu et al (College of Pharmacy,Lanzhou University,Lanzhou,Gansu 730000);Study on the Extraction Technology of Salidroside from the Root of Rhodiola rosea L.under High Pressure[J];Journal of Anhui Agricultural Sciences;2008-19
5 XU Shi you, TANG Gia hua (Department of Chemistry ,Chaohu Teachers' College, Chaohu,Anhui 238000,China);THE TOPOLOGICAL INDEX ~mE OF VALENCE ELECTRON ORBIT ENERGY AND CALCULATION OF ACIDITY OF P AREA HYDRIDE[J];Journal of Anhui Normal University(Natural Science);2002-03
6 JIA Hong?min,ZHU Xiu?hui,LI Jing?hui, GAO Zhi?ming,WU Ying?chun,KONG Ling?jun (School of Chemistry Engineering,Anshan Institute of I.& S.Technology,Anshan 114002,China);Optimization of the Complex Prescription of Water Treatment Reagent by Simplex Methods[J];JOURNAL OF ANSHAN INSTITUTE OF IRON AND STEEL TECHNOLOGY;2000-03
7 WU Xiu_hong 1,LI Jing_hui 1,GUAN Yong_yi 2 (1..School of Chemical Engineering,Anshan Institute of I.& S.Technology,Anshan 114002,China; 2.Chemical Engineering Factroy Anshan Iron and Steel Complex,114021 Anshan,China);Simultaneous Determination of Benzene and Methyl Benzene by Artificial Neural Networks Ultraviolet Spectrophotometry[J];Journal of Anshan Institute of Iron and Steel Technology;2002-03
8 Wang Guilong Xiang Yang Department of Orthopedics,Affiliated Hospitalof Guiyang Medical College,Guiyang 550004,China;Progress of local chemotherapy for the malignant bone tumors[J];Oncology Progress;2007-02
9 Zhang Bo; Lin Jun; Shao Mingwu; Li Tichuan; Xu Lian (College of Environment and Energy Engineering, Beijing Polytechnic University, Beijing, 100022 );Determination of Mixed Nitrobenezenes by Chemonetrics-Spectrophotometry[J];JOURNAL OF BEIJING POLYTECHNIC UNIVERSITY;2000-02
10 Li Xinyun Wang Jingjing Li Tichuan Zhang Baoquan Qiu Xuemei ( Department of Chemisty and Environmental Engineering, Beijing Polytechnic University, 100022) Cheng Weihu ( Department of Applied Mathematics, Beijing Polytechnic University, 100022);Simultaneous Determination of Multicomponent Phenols With Flow Injection Spectrophotometry by Fuzzy Cluster-Factor Analysis Decomposition in Waste Water Samples[J];JOURNAL OF BEIJING POLYTECHNIC UNIVERSITY;1997-01
China Proceedings of conference Full-text Database 10 Hits
1 Zhao Yong Liu Zhicun Wang Zhongyi Huang Lan College of Information and Electrical Engineering,China Agricultural University,Beijing 100083,China) Hou Ruifeng Xu Zhilong National Engineering Research Center for Information Technology in Agriculture,Beijing 100089,China;The Investigation on Fast Detection for Quality of Milk Powder by Using near Infrared Spectroscopy[A];[C];2006
2 Su Yuliang Wu Jie Fang Li (Water Quality Monitoring and Research Center,Zhuhai Water Supply General Corporation,Zhuhai 519020,China);Determination of Carbaryl in Water by High Performance Liquid Chromatography with Direct Injection[A];[C];2007
3 Zhang Debao Qin Yuanxi Zhang Liangchou (IGMR,Nanjing) Zhang Wenrong Wu Shigu Luo Jiechong (Research Institute of Jianghang Petroleum Exploration and Development,Petroleum Deppartment);THE STUDY ON TECTONIC DEFORMATION AND EVOLOTION IN THE SOUTHERN TONGBE-DABIE MOUNTAIN AND ITS FORELAND ARER[A];[C];1990
4 Zhou Liangren (Xi'an Institute of Geology and Mineral Resources,CAGS) Cai Houwei (Geological Surveying Party, Jiuquan,Gansu,BGMR);YENSHAN MOVEMENT IN NORTHWESTERN CHINA[A];[C];1990
5 Xue-guang Shao* Department of Chemistry, Nankai University, 300071, Tianjin;Adaptive Algorithms for Resolution of Complex Analytical Signals[A];[C];2006
6 Shao-Hua Zhu Hai-Long Wu A-Lin Xia Qing-Juan Han Yan Zhang Ru-Qin Yu (State Key Laboratory of Chemo/Biosensing and Chemometrics,College of Chemistry and Chemical Engineering,Hunan University,Changsha 410082,China.;Quantitative analysis of carbaryl hydrolysis process in river water by excitation-emission matrix fluorescence coupled with second-order calibration[A];[C];2007
7 ;Application of Chemometrics Methods in Pesticide Residues Analysis and Food Safety[A];[C];2007
8 Xue-guang Shao Wensheng Cai Da Chen Yankun Li Zhichao Liu College of Chemistry,Nankai University,300071,Tianjin;Resolution and Quantitative Algorithms for Complex Analytical Signals[A];[C];2007
9 Peisheng Cong,Zhongliang Zhu Department of Chemistry,Tongji University,Shanghai,200092,;Calculation of Chemometrics in WEB[A];[C];2009
10 Qinghua Zhang,Zhongliang Zhu~*,Peisheng cong,Mingyue Shen,Xiangdong Deng (Department of Chemistry,Tongji University,Shang hai,200092,);The analysis of experimental data for mixed pigment measured by Multivariatecalibration-UV-Vis Spectrophotometry[A];[C];2009
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 Li Xinyun Wang Jingjing Li Tichuan Zhang Baoquan Qiu Xuemei ( Department of Chemisty and Environmental Engineering, Beijing Polytechnic University, 100022) Cheng Weihu ( Department of Applied Mathematics, Beijing Polytechnic University, 100022);Simultaneous Determination of Multicomponent Phenols With Flow Injection Spectrophotometry by Fuzzy Cluster-Factor Analysis Decomposition in Waste Water Samples[J];JOURNAL OF BEIJING POLYTECHNIC UNIVERSITY;1997-01
2 Selection and management of peer-reviewers // Huang Jinsong, Peng Chaoqun, Yang Bing;Selection and management of peer-reviewers[J];Acta Editologica;2003-01
3 Li Mingzhi, Suo Zhihai, Zhao Daliang Journal Publishing Department, Beijing Forestry University, 100083, Beijing, China;Development and use of peer reviewer database for scientific journals[J];Acta Editologica;2004-04
4 Li YunxiaThe Editorial Department of Scientia Agricultura Sinica,100081,Beijing,China;Dynamical management of reviewers[J];Acta Editologica;2005-01
5 Chen Rong,Lü Saiying Periodical Department, Chongqing University, 400030, Chongqing, China;Editors' communication and cooperation with peer reviewers[J];Acta Editologica;2005-03
6 Xu Huatao,Liu Shuhua,Fu Xiaoqin,Li Jia Editorial Department of Journal of South China University of Technology,510640, Guangzhou,China;Realization of peer reviewer system for academic journals[J];Acta Editologica;2005-05
7 Li Jinli,Xu Yongji,Lin QinghuaEditorial Department of Journal of Northeastern University,110004,Shenyang,China;Choosing appropriate peer reviewers using China Education and Research Network[J];Acta Editologica;2006-02
8 Guo Xiairong, Yu Fu Zong Geming Li Zhi Liang (Dept of Machan & Electr Eng. Changsha Communications CollegeChangsha 410076 Dept of comput Sci, Hubei Automobile college . Dept of chem & chem Eng. ICP. Hunan University, Changsha 410082);On Wavelets Transfor and Applications: Extraction of Useful Information from Comleticated Analeytical Systems.[J];Journal of Changsha University;1998-02
9 Ma Lin;Zhu Wansen;Wang Duan;Gu Wei (Deprtment of chemistry);The Simultaneous Determination of Trace Cu,Bi and Fe by Spectrophotometry-CPA Matrix Method[J];Journal of Fudan University;1998-03
10 Xia Zhining Li Zhiliang Matsumoto S.(Department of Applied Chamistry,Chongqing University);Extended Kalman Filtering Algorithm Trained Neural Networks and Its Application to the Multicomponent Pharmaceutical Spectrophotometric Analysis[J];JOURNAL OF CHONGQING UNIVERSITY(NATURAL SCIENCE EDITION);1998-03
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