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《CHINESE JOURNAL OF CHEMICAL PHYSICS》 1994-01
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Theoretical Calculation of Activity Coefficient of Electrolytes

Zhang Suobang; Han Shijun(Chem. Dep. of Zhejiang Univ ., Hangzhou 310027)  
Abstract In this paper a new formula of activity coemcicnt of electrolytes has been proposed in termsof Stokes and Robinson Theory (1948). The new formula has all of the advantages of Stokesand Robinson formula (1948), but does not contain osmotic coemcicnt(9). Futhermore, the newformula is applicable to single--solvent and mixed--solvent electrolyte systems. The achvitycoefficients of 22 electrolyte -- containing systems are calculated by the new formula. The resultshave shown good accuracy. The mean or relative deviation of every processed system is less than1%.
【Fund】: 国家教委博士学科点专项基金
【CateGory Index】: O604
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【References】
Chinese Journal Full-text Database 4 Hits
1 QIN Dongmian,LIU Guihua,LI Xiaobin,PENG Zhihong,ZHOU Qiusheng(School of Metallurgical Science and Engineering,Central South University,Changsha 410083);Research Progress of Debye-Hckel Theory[J];Materials Review;2010-13
2 Yang Hongmei Li Xubing;Present situation of study of phase Equilibria and phase Diagrams of salt-water sytems[J];Sea-lake Salt and Chemical Industry;2002-05
3 Yuan Honggang Zhou Lidai Zhang Zhenbin (Liaoning Institute of Technology,Jinzhou 121001,China);Research advance of thermodynamic properties for electrolyte solutions[J];Journal of Chemical Industry & Engineering;2006-05
4 WANG Rong 1 LI Quan 2 ( 1. Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610064, Sichuan; 2. Department of Chemistry, Sichuan Normal University, Chengdu 610066, Sichuan);Progresses of Studies on the Properties of Electrolyte Solutions[J];JOURNAL OF SICHUAN NORMAL UNIVERSITY(NATURAL SCIENCE);1999-03
【Citations】
Chinese Journal Full-text Database 2 Hits
1 Zhang Suojiang;A Study on the Thermodynamic Properties of the Electrolyte in the Mixed-Solvents Ⅰ. A System of HCl(m)+DMSO(x) + H_2O( 1-x), 25-45℃[J];Journal of Henan University (Natural Science);1990-03
2 Wei Dongqing Lu Jinsuo Zhu Jianjun Zhou Xishun (Department of Chemistry,Normal University of Henan);THE STUDIES ON SALT EFFECT OF THE ISOTHERMAL VAPOUR-LIQUID EQUILIBRIUM——ORGANIC SOLVENT-WATER-INORGANIC SALT SYSTEM[J];Acta Physico-Chimica Sinica;1987-05
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Wang Xuezhi (Anhui Institute of Mechanical and Electrical Engineering Wuhu 241000);The Determination of Stability Constans of Coordination Compounds by Ultraviolet Spectrometry[J];JOURNAL OF ANHUI INSTITUTE OF MECHANICAL AND ELECTRICAL ENGINEERING;1997-01
2 GUO Jin-bao,DU Ying-chun,HU Qiu-feng(Department of Material Engineering,Beijing Institute of Clothing Technology,100029,China);New Technology of Synthesis of Normal Butyl Acetate with Catalytic Distillation[J];;2006-01
3 YIN Zu-ping1,2,JU Jian-yong1,2,LIU Yun-yi3(1.Baotou Research Institute of Rare Earth,Baotou 014030,Nei Monggol,China;2.National Engineering Research Center of Rare Earth Metallurgy and Function Materials,Baotou 014030,Nei Monggol,China;3.Shenyang University of Chemical Technology,Shenyang 110142,Liaoning Province,China);Thermodynamic Calculations and Experiments for Preparation of Neodymium Fluoride with Hydrogen Fluoride[J];Science & Technology of Baotou Steel;2010-01
4 GUO Zhongxian\ LI Yuanzong (College of Chemistry and Molecular Engineering, Peking University,Beijing,100871) SHEN\ Hanxi (Department of Chemistry,Nankai University,Tianjin,300071);Study on Catalytic Property of Hemin in the Presence of Anion Surfactant[J];Acta Scicentiarum Naturalum Universitis Pekinesis;2001-02
5 Wang DongGuo HongjieLiang GuozhuLiu Yin(School of Astronautics,Beijing University of Aeronautics and Astronautics,Beijing 100191,China);Preliminary experimental investigation on nitrous oxide/propane igniter[J];Journal of Beijing University of Aeronautics and Astronautics;2010-10
6 FENG Chang-jun MU Lai-long(Department of Chemistry,Xuzhou Normal University,Jiangsu Xuzhou 221116,China);Edge valence topological study on standard entropies of chain hydrocarbons[J];Journal of Beijing University of Chemical Technology;2005-06
7 Huang Zhenyu Xu Wencan (School of Mechano Electronics Engineering, Beijing Institute of Technology, Beijing100081);Numerical Simulation for Non Equilibrium Chemically Reacting Jet Flow[J];JOURNAL OF BEIJING INSTITUTE OF TECHNOLOGY;1999-S1
8 Li Ruxiong (Chemical Engineering Department);Some Problems on the Value of Cp -Cv for Liquids and Solids[J];Journal of Beijing Institufe of Petrochemical Technology;1994-01
9 Gong Liangfa Li Ruxiong Xu Xin Yang Tao(Department of Chemical Engineering, Beijing Institute of Petro-chemical Technology, Beijing 102600);Surface Tension of Aqueous Solutions of Inorganic Salts and Those+Surfactant[J];Journal of Beijing Institufe of Petrochemical Technology;2000-01
10 WANG Wei-dong,WU Hui-juan,LIN Shu-xiong(College of Chemistry and Environmental Engineering,Hubei Normal University,Huangshi 435002,Hubei,China);Determination of the infinite dilution molar conductivity of DyCl_3 in isopropanol[J];Journal of Baoji University of Arts and Sciences(Natural Science Edition);2009-02
China Proceedings of conference Full-text Database 9 Hits
1 CHEN Yikun LUO Lan CHEN Wei and ZHANG Gancheng (Shanghai Institute of Ceramics,Chinese Academy of Sciences,Shanghai 200050,China);PHASE TRANSITION OF GLASS-CERAMICS FROM MgO-Al_2O_3-SiO_2-TiO_2-CeO_2 SYSTEM[A];[C];2005
2 ChEN Wei~1 WANG De-Qiang~2 CHENG Ji-Jian~2 (1.Shanghai Institute of Ceramics,Chineses Academy of Sciences Shanghai 200050.China) (2.Research institute of Inorganic Materials,ECUST,Shanghai,200237,China);The Ion-exchange of New Chalcohalide Glasses[A];[C];2005
3 Yang Di~(1,2) Xie Gang~(1*) Li Rongxing~1 Yang Dajin~3 Zhang Haodong~1 (1.Faculty of Materials and Metallurgical Engineering,Kunming University of Science and Technology,Kunming 650093,China;2.Department of Computer Science and Technology,Yunnan University of Finance and Economy,Kunming 650034,China;3.Yunnan Metallurgy Co.Ltd.,Kunming 650031,China);Study on Electrolyte System of Preparing High-Purity Zinc[A];[C];2008
4 WANG Wei-Dong (Department of Chemistry and Environmental Engineering of Hubei Normal University, Huangshi 435002);Use the Electric Conductivity to Assay the Activity Coefficient of LiCl in H_2O[A];[C];2005
5 Wang Zhenfeng, Fang Zheng(College of Chemistry & Chemical Engineering, Central South University, Changsha 410083, China);Determination of Entropy Change of Half-Cell Reaction by A Thermo-Electrochemical Method[A];[C];2006
6 ZUO Huai-ying WEI Ji-he (College of Materials Science and Engineering,Shanghai University,Shanghai 200072,China);Mass Transfer Characteristics in an AOD Bath under Conditions of Combined Side and Top Blowing[A];[C];2008
7 WANG Yun-yan CHAI Li-yuan WANG Qing-wei SHU Yu-de (School of Metallurgical Science and Engineering,Central South University,Changsha 410083,China);Thermodynamic equilibrium of hydroxyl complex ions in heavy metals(Cu~(2+),Pb~(2+),Zn~(2+),Cd~(2+))-H_2O system[A];[C];2008
8 ZHAO Xiao-feng,SHAO Gang-qin,DUAN Xing-long,ZHAO Ming,YAN Li (State Key Laboratory of Advanced Technology for Materials Synthesis & Processing, Wuhan University of Technology,Wuhan 430070,China);Preparation and Properties of Ce_(0.8)Sm_(0.2)O_(1.9) as A New Kind of SOFC Eletrolyte Material[A];[C];2007
9 MO Xue-kui LI Yan-jun (School of Materials Science and Engineering,University of Jinan,Jinan 250022,China);Influence of Assistants on Synthesizing Barium Titanate Powder by Hydrothermal Technique[A];[C];2007
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 HAO Li fang, AN Lian ying, TANG Ming lin, YIN Hui an, LONG Zuo ping(College of Materials and Bioengineering, Chengdu University of Technology, China);STUDY OF THE EXTRACTION METHOD OF POTASSIUM IN POLYHALITE[J];Journal of Chengdu University of Technology(Science & Technology Edition);2003-02
2 QIN Dongmian,LIU Guihua,LI Xiaobin,PENG Zhihong,ZHOU Qiusheng(School of Metallurgical Science and Engineering,Central South University,Changsha 410083);Research Progress of Debye-Hckel Theory[J];Materials Review;2010-13
3 Guo Qiti;PHASE DIAGRAMS OF UNARY MULTISYSTEMS[J];Geochimica;1979-04
4 Zhao Dejun Han Weitian Cai Keqin Gao Jianhua ( Wuhan College of Geology, Wuhan 430074);THE STUDY OF POLYHALITE GENESIS AND ITS SIGNIFICANCE OF POTASH-FINDING IN DAWENKOU DEPRESSION, SHANDONG PROVINCE[J];;1987-04
5 SHENTU Yan-Ming, LI Yi-Gui (Department of Chemical Engineering, Tsinghua University, Beijing, 100084);Prediction for Partial Molar Volumes in Mixed Electrolyte Aqueous Solutions by Pitzer Theory[J];Chemical Research In Chinese Universities;1993-05
6 Xu Guohua;Chen Weiniu (Department of Chemical Engineering, Zhejiang University, Hangzhou);Droplet Rupture under High-Intensity Electric Fields[J];JOURNAL OF CHEMICAL ENGINEERING OF CHINESE UNIVERSITIES;1994-03
7 Yu Yangxin\ \ Gao Guanghua\ \ Lu Jiufang\ \ Li Yigui (Department of Chemical Engineering, Tsinghua University, Beijing 100084);Prediction of Solid liquid Equilibria for Mixed Electrolyte Aqueous by the Modified Mean Spherical Approximation[J];JOURNAL OF CHEMICAL ENGINEERING OF CHINESE UNIVERSITIES;1997-04
8 Lin Xia(Guangxi college Of Sanitary Administration,Nanning 530021 );An Elementary Indroduction to Electolyte Solution Theory[J];JOURNAL OF GUANGXI TEACHERS COLLEGE;1997-03
9 Hu Ying Xu Yingnian (Thermodynamics Research Laboratory, East China Institute of Chemical Technology) J. M. Prausnitz (Dept. Chem. Eng., University of California, Berkeley);Molecular Thermodynamics of Gas Solubility ( I ) Henry's Constants of Gases in NonpolarSolvents[J];Journal of Chemical Industry and Engineering(China);1987-01
10 Song Pengsheng (Qinghai Institute of Salt Lakes, Academia Sinica, Xining);Calculation of Isohydrores on the Phase Diagram for a Multicomponent Salt-water System[J];Journal of Chemical Industry and Engineering(China);1989-01
【Secondary References】
Chinese Journal Full-text Database 7 Hits
1 CHEN Yuan-yuan YU Bing-song(School of Earth Sciences and Resources,China University of Geosciences,Beijing 100083);Dissolution-Precipitation Thermodynamic Models of Carbonate Rock and the Application in the Northern Part of Tarim Basin[J];Acta Sedimentologica Sinica;2012-02
2 LU Jiang-lin,CHENG Yin-fang,HUANG Ting,WANG Wei-dong(College of Chemistry and Environmental Engineering,Hubei Normal University,Huangshi 435002,China);The study on ternary system phase equilibrium of KCl-NH_4Cl-H_2O at 301.15K[J];Journal of Hubei Normal University(Natural Science);2010-04
3 GUO Han-jie~1 ZHAO Wei-jie~1 LI Lin~1 YANG Xue-min~2 (1.School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing,Beijing 100083,China; 2.State Key Lab of Multiphase Complex System,Institute of Process Engineering,CAS,Beijing 100080,China);A Universal Thermodynamic Model of Calculating Mass Action Concentrations of Components in Strong Electrolyte Binary Aqueous Solutions[J];The Chinese Journal of Process Engineering;2007-02
4 LI Wen-jie,CHEN Yun,YU Xun-min,LI Qing-xin,GUAN Hong-liang(School of Environment and Civil Engineering,Wuhan Institute of Technology,Wuhan 430074,China);Kinetics of leaching gold from processed sludge of nonferrous metal smelting waste water[J];Journal of Wuhan Institute of Technology;2012-05
5 XU Xian Feng,CHU Jun](The University of Petroleum, Dongying, Shandong 257061, China);Progress in the Study of Electrolyte Water Solution and Applications of the Electrolyte Water Solution in Petroleum Industry[J];Journal of Xi'an Petroleum Institute;2001-03
6 YANG Hai-tang1,2,ZENG De-wen*1,2,YAO Yan3(1.College of Chemistry and Chemical Engineering,Central South University,Changsha 410083,China; 2.Key Laboratory of Resource Chemistry of Nonferrous Metals,Central South University,Changsha 450083,China; 3.Qinghai Institute of Salt Lakes,Chinese Academy of Scienes,Xining 810008,China);Determination of NH_4~+ and NO_3~- in salt-water system by distillation—acid-base titration[J];Metallurgical Analysis;2012-05
7 Guo Wang, Chen Jianfa, Cao Qing et al State Key Laboratory of Petroleum Resource and Prospecting, China University of Petroleum (Beijing), Beijing City,102249, China;Occurrence and significance of gaseous water in reservoir[J];Petroleum Geology and Recovery Efficiency;2013-01
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