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《Acta Chimica Sinica》 1981-03
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IDENTIFICATION OF THE STRUCTURES OF CORYDALIS F, I, J AND K

ZHU DA-YUAN SONG CHUN-QING GAO YAO--LIANG XU REN-SHENG (Shanghai Institute of Materia Medica, Academia Sinica)  
T. Q. Chou reported the isolation of 13 alkaloids from the tubers of Corydalis ambigua Chan et schlecht (now corrected as Corydalis turtshaninovii Bess. f. Yanhusuo Y. H. Chou et C. C. Hsu). Seven of them have been identified as follows: A, d-corydalin; B, dl-tetrahydropalmatine; C, protopine; D; tetrahydrocoptisine; E, dl-tetrahydrocoptisine; G, d-corybulbine and M, allo-crytopine. In this paper the structures of corydalis; I and K have been identified as d-glaucine and l-tetrahydrocolumbamine respectively by spectral analysis. Besides, corydalis J has been proved to be identical with corydalis I, and F the same as K, in agreement with the postulation originally made by Huang Minlon.
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