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《Acta Chimica Sinica》 1984-10
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A STUDY ON DIFFERENTIAL PULSE POLAROGRAPHY OF SODIUM β-[3-(DIMETHYLAMINO) METHYLENAMINO-2, 4, 6-TRIIODOPHENYL] PROPIONATE

WANG ZHAI-ZHONG~* YUNG HONG-LIANG (Chemistry Department, Yunnan University, Kunming)  
This paper reports the differential pulse polarographic analysis of the title compound. In Britton-Robinson buffer solution at pH7.0 two cathodic waves of the compound appear at-0.46V and -0.65 V (vs. 1MKCl Ag-AgCl) respectively. The first wave is used for quantitative analysis. A linear relationship exists between the wave height and the concentration of the compound in the range of 5.0×10~(-7)M to 5.0× 10~(-5)M. The detection limit is about 3.0×10~(-7)M. Furthermore, we have studied the polarographic behaviors and the reaction mechanism. The electrode process has also been investigated by means of cyclic voltammetry. It shows that the polarographic wave is an adsorption wave and that the electrode reaction is irreversible. The analytical procedure proposed in this paper ia simple, rapid and accurate for the determination of the compound in the capsule and crude medicine with satisfactory results.
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【References】
Chinese Journal Full-text Database 2 Hits
1 Ruan Chuanmin, Wang Zhaizhong~*, Xu Qiheng (Department of Chemistry, Yunnan University, Kunming 650091);Oscillographic Polarography of 5-(4-Antipyrinylazo)-8-aminoquinoline[J];Chinese Journal of Analytical Chemistry;1991-12
2 Li Nanqiang (Department of Chemistry, Peking University);Electroanalytical Chemistry in China[J];Analytical Laboratory;1987-Z1
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 Jiao Kui Zhang Manping Gao XiaoxiaDepartment of Chemistry;Electroanalytical Determination of Micro Amount of Bare Earth Elements in Plants by Polarographic Adsorptive Complex Wave[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1982-06
2 Li Nanqiang, Gao Xiaoxia Department of Chemistry;Studies on the Mechanism of the Polarographic Catalytic Wave of Molybdotartrate Complex with Chlorate[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1983-04
3 Ye Xianzhen, Jiang Ziwei, Zhou Shengwn, Zhang Zhenyyu, Gao XianxiaDepartment of Chemistry;Polarographic Determination of Tetracycline[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1983-06
4 Jiao Kui He Chengjie Zhang Xiyu Department of Chemistry;The Determination of Trace Amounts of Selenium By Single-Sweep Polarography Ⅰ. On the mechanism of the polarographic catalytic wave of SeSO_~3=-KIO_3[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1984-04
5 Li Nanqiang Zhang Jiankang Department of Chemistry;Studies On the Polarographic Adsorptive Complex Wave of Indium-Alizarin Red S[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1984-06
6 Ye Xianzeng Guan Fuyu Zhao Changming (Department of Chemistry);Single-Sweep Polarographic Determination of Bare Earth Ions by the Substitution Beaction of Cd(Ⅱ)-EDTA in the Presence cf 2,2'-bipyridyl[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1985-04
7 Li Nanqiang Cos Mingxiang (Department of Chemistry);Studies on the Polarographic Behaviours of Dipicolinic Acid[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1986-02
8 Zhang Shousong Li Wenhong (Changchun Institute of Applied Chemistry,Academia Sinica);Potentiometric Stripping Analysis with a Thin Film Mercury Glassy Carbon Electrode[J];Chinese Journal of Analytical Chemistry;1982-01
9 Tan Zhengzhi (Laboratory of Geological Bureau of Hunan Province);Cathode-ray Polarographic Determination of Microamounts of Tantalum[J];Chinese Journal of Analytical Chemistry;1982-05
10 Guo Du Wang Erkang (Changchun Institute of Applied Chemistry,Academia Sinica);Polarographic Study of Calcium Complex with Murexide[J];Chinese Journal of Analytical Chemistry;1982-05
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 Zhao Jianwei,Xu Qiheng ,Ai Ping (Department of Chemistry, Yunnan University, Kunming 650091);Enhancement of Hydrogen Peroxide for Fluorescence System of 8-Aminoquinoline Derivative-Copper (Ⅱ )and Cobalt ( Ⅱ ) and Related Mechanism[J];Chinese Journal of Analytical Chemistry;1993-01
2 Yang Yunfa(Changchun Institute of Applied Chemistry, Chinese Academy of Sciences,National Analyical Research Center of Electrochemistry and Spectroscopy, Changchun 130022);Anodic Differential Pulse Voltammetric Determination of Hydroxyethylrutin on a Glassy Carbon Electrode[J];Chinese Journal of Analytieal Chemistry;1996-02
3 Jiang Zhiliang; Qin Chenszhe(Guangxi Normal University, Cuilin, P. R. China);Oscillopolarographic Study on the Catalytic System of V (Ⅴ)-(NH_4) _2S_2O_8-Benzoglycolic Acid-OP and Its Application[J];JOURNAL OF ANALYTICAL SCIENCE;1995-02
4 Li Zhiliang, Tan ShenLian(Hunan University, Changsha, 410082), peng Ping(Nankai University), Shi Leming(China University of Science and Technology);Enhancing Reagents in Electro Analytical Chemistry[J];Analytical Laboratory;1990-03
5 Xu Lishen and Zhou Tonghui (Department of Analytical Chemistry, Institute of Materia Medica, CAMS, Beijing 100050);Pharmaceutical Analysis in China[J];Analytical Laboratory;1992-03
6 Jiang Zhiliang, Li Xiaojin, Wu Daqiang and Dai Guozhong (Department of Chemistry, Guangxi Normal University, Guilin 541004);OscillopolarographicDetermination of Manganese in ng/L Level by Catalytic Reaction[J];Analytical Laboratory;1992-05
7 Zhang Yonghua and Wang Erkang (Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022);Electroanalytical Chemistry[J];Analytical Laboratory;1993-05
8 ZHANG Jun,YUAN Zhuo-bin(Institute of Applied Chemistry,Graduate School of Chinese Academy of Sciences,Beijing 100049),ZHANG Jun and YUAN Zhuo-bin(Institute of Applied Chemistry,Graduate School,University of Science and Technology of China,Beijing 100049),Fenxi Shiyanshi,2005,24(11): 80~90;Opportunity and challenge of modernization of Chinese medicine to analytical chemistry[J];Analytical Laboratory;2005-11
9 Zhang Zhengqi Lu Ruanhui Zhang Xumin Cao Zhixiong(Department of Chemistry and Chemical Engineering);Polarographic Determination of Penfluridol[J];JOURNAL OF HUNAN UNIVERSITY(NATURNAL SCIENCES);1994-01
10 Kong Jilie \=(Department of Chemistry, Fudan University, Shanghai 200433, China);Applications and Prospects for Advanced ElectroanalyticalTechniques in Chinese Medicine Analysis[J];PROGRESS IN CHEMISTRY;1999-03
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