Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Acta Chimica Sinica》 1988-09
Add to Favorite Get Latest Update

Using Ion-Selective Electrodes to Study the Thermodynamics of Solution——Ⅳ.The Standard Gibbs Free Energies and Entropies of Transfer of Sodium Chloride from Water to N,N-Dimethylformamide—Water Mixture at Nine Temperatures from 5℃ to 45℃

Chu De-Ying~* Zhang Ying Yi Ying Liu Rui-Lin (Department of Chemistry,Peking University,Beijing)  
The standard electromotive forces of the reversible cells without liquid junctionconsists of the sodium ion glass-electrode and chloride selective electrode,namelyCl-selective electrode |NaCl(m),w or s|Na~+ glass-electrode have been measured,andthe standard Gibbs free energies of transfer of NaCl from water to N,N-dimethylfor-mamide—water mixtures have been calculated.The standard transfer entropies have beenalso calculated from temperatures coefficient of △G_t~° at nine temperatures from 5℃to 45℃.The behaviour of the change of △G_t~° and △S_t~° with organic composition andtemperature,the change of solvations of NaCl from the pure water to mixed solvents andthe structure of the liquid studied were discussed.
【Fund】: 中国科学院科学基金
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 10 Hits
1 Li Linwei Chu Deying Liu Ruilin (College of Chemistry and Molecular Engineering,Beijing University,Beijing 100871);USING ION SELECTIVE ELECTRODE TO STUDY THE THERMODYNAMICS OF SOLUTION ⅠⅩ.Determinations of Relative Partial Molar Free Energies, Enthalpies and Entropies of RbCl in Water and Mixtures[J];JOURNAL OF CENTRAL CHINA NORMAL UNIVERSITY(NATURAL SCIENCES);1998-02
2 Zhang Luzheng Lu Xiaohua Wang Fanru Shi Jun (Department of Chemical Engineering);A SHORT-CUT DETERMINATION OF ACTIVITY COEFFICIENTS FOR ELECTROLYTE IN MIXED SOLVENT BY ADDING CONTINUOUSLY A CONCENTRATED ELECTROLYTE SOLUTION[J];Journal of Nanjing University of Technology(Natural Science Edition);1992-01
3 Xu Lamei; Ni Liang; Lu Jie;(Zhenjiang Educational Bureau, 212001, Zhenjiang, PRC; Department of Chemistry, Zhenjiang Teacher's College 212003, Zhenjiang, PRC.);Study on the Influence of Solvent on the Equilibrium Properties of Thermodynamics[J];JOURNAL OF NANJING NORMAL UNIVERSITY(NATURAL SCIENCE EDITION);1995-04
4 Li Linwei 1) Diao Zhaoyu 2) Chu Deying 3) Liu Ruilin 3) ( 1)Department of Chemistry,Liaocheng Teachers' College,252059,Liaocheng,Shandong,P R C; 2)Department of Chemistry,Shandong Normal Universitry,250014,Jinan,P R C;;THE MEDIUM EFFECT OF RbCl IN MIXED SOLVENTS[J];JOURNAL OF SHANDONG NORMAL UNIVERSITY (NATURAL SCIENCE);1998-04
5  Li Linwei1) Li Daocheng1) Chu Deying2) Liu Ruilin2)(1) Department of Chemistry of Liaocheng Teachers University,Liaocheng,Shandong,252059; 2) Collge of Chemistry and Molecular Engineering,Peking University,Bei;Using Ion-selective Electrode to Study the Thermodynamics of Solution (VI)-Determination of Standard Free Energies of Transfer of RbCl from H2O to (H2O-MeOH)and (H2O-DMF)Mixtures at 298.15K[J];JOURNAL OF LIAOCHENG TEACHERS UNIVERSITY;1998-01
6 Li Linwei1) Du Maoxi1) Li Dacheng1) Chu Deging2) Liu Ruilin2) (1)Department of Chemistry,Liaocheng Teachers University,Liaocheng,Shandong,252059;2)College of Chemistry and Molecular Engineering,Beijing Uni;Using Ion Selective Electrode to Study Thermodynamics of SolutionDetermination of Activity Coefficients of RbCl in(H2O CH3OH) Mixtures at 298.15K[J];Journal of Liaocheng Teachers College(Natural Science Edition);1998-02
7 Chu Deying;Zhang Ying;Hu Jingdan;Liu Ruilin Department of Chemistry, Peking University;EXCESS MOLAR VOLUMES OF MIXTURES OF N, N-DIMETHYLFORMAMIDE AND WATER AND APPARENT MOLAL VOLUMES AND PARTIAL MOLAL VOLUMES OF N, N-DIMETHYLFORMAMIDE IN WATER FROM 278. 15K TO 318. 15K[J];Acta Physico-chimica Sinica;1990-02
8 Li Linwei; Chu Deying; Liu Rmhn(College of Chemiastry and Moleculer Engineering. Peking University Beijing 100871: Departmentof Chemistry, Liaocheng Teache's College' Liaocheng 252O59);Determination of Activity Coefficients of RbCl in (H_2O-DMF) Mixed Solvents at 283.15 to 318.15K[J];ACTA PHYSICO-CHIMICA SINICA;1998-08
9 Li Linwei1 Chu Deying Liu Ruilin ( College of Chemistry and Molecular Engineering,Peking University, Beijing 100871; 1Department of Chemistry,Liaocheng Teachers College, Liaocheng City 252059);Determination of Standard Transfer Entropies of RbCl from H_2O to Mixtures of H_2O-DMF [J];ACTA PHYSICO-CHIMICA SINICA;1999-03
10 Li Linwei (Dept. of Chem., Liaocheng Teach. Coll., Liaocheng 252059) Chu Deying Liu Ruilin (Coll. of Chem. and Molecular Engin., Pejing Univ.,Beijing 100871);Determination and Study on Properties of Thermodynamics of RbCl in Water Containing Mixtures at 298.15K[J];JOURNAL OF XIAMEN UNIVERSITY(NATURAL SCIENCE);1998-06
【Citations】
Chinese Journal Full-text Database 2 Hits
1 FANG LI-QI LIU RUI-LIN (Institute of Physical Chemistry,Peking University Beijing);THE FREE ENERGIES AND ENTROPIES OF THE TRANSFER OF NaCl,KCl,FROM WATER TO WATER AND BUTANOL MIXTURES——DOUBLE CELL EMF DETERMINATION[J];Acta Chimica Sinica;1985-05
2 Chu Deying Liu Li Liu Ruilin (Department of Chemistry,Peking University);THE STANDARD GIBBS ENERGIES OF TRANSFER AND THE ACTIVITY COEFFICIENTS OF NaF AND NaCl FROM WATER TO DIOXAN+WATER MIXTURES——USING IONSELECTIVE ELECTRODES TO STUDY THE THERMODYNAMICS OF SOLUTIONS[J];Acta Physico-Chimica Sinica;1987-05
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Zhang Suojiang; Han Shijun (Dept. of Chemistry, Zhejiang Univ., Hangzhou 310027);General Activity and General Activity Coefficient[J];CHINESE JOURNAL OF CHEMICAL PHYSICS;1994-04
2 Li Linwei Chu Deying Liu Ruilin (College of Chemistry and Molecular Engineering,Beijing University,Beijing 100871);USING ION SELECTIVE ELECTRODE TO STUDY THE THERMODYNAMICS OF SOLUTION ⅠⅩ.Determinations of Relative Partial Molar Free Energies, Enthalpies and Entropies of RbCl in Water and Mixtures[J];JOURNAL OF CENTRAL CHINA NORMAL UNIVERSITY(NATURAL SCIENCES);1998-02
3 Zhou Xianghong Chemical Engineering School et al;The Determination of Activity Coefficients for HCI in Ethanol+Water Mixtures.[J];Journal of Nanjing University of Science and Technology;1991-03
4 Zhang Weiquan Chemical Engineering School;The Standard Thermodynamic Quantities for the Transfer of HCl from Water to Water-acetic Acid Mixtures at 288, 3~318.2 K[J];Journal of Nanjing University of Science and Technology;1993-03
5 Li Linwei 1) Diao Zhaoyu 2) Chu Deying 3) Liu Ruilin 3) ( 1)Department of Chemistry,Liaocheng Teachers' College,252059,Liaocheng,Shandong,P R C; 2)Department of Chemistry,Shandong Normal Universitry,250014,Jinan,P R C;;THE MEDIUM EFFECT OF RbCl IN MIXED SOLVENTS[J];JOURNAL OF SHANDONG NORMAL UNIVERSITY (NATURAL SCIENCE);1998-04
6  Li Linwei1) Li Daocheng1) Chu Deying2) Liu Ruilin2)(1) Department of Chemistry of Liaocheng Teachers University,Liaocheng,Shandong,252059; 2) Collge of Chemistry and Molecular Engineering,Peking University,Bei;Using Ion-selective Electrode to Study the Thermodynamics of Solution (VI)-Determination of Standard Free Energies of Transfer of RbCl from H2O to (H2O-MeOH)and (H2O-DMF)Mixtures at 298.15K[J];JOURNAL OF LIAOCHENG TEACHERS UNIVERSITY;1998-01
7 Li Linwei1) Du Maoxi1) Li Dacheng1) Chu Deging2) Liu Ruilin2) (1)Department of Chemistry,Liaocheng Teachers University,Liaocheng,Shandong,252059;2)College of Chemistry and Molecular Engineering,Beijing Uni;Using Ion Selective Electrode to Study Thermodynamics of SolutionDetermination of Activity Coefficients of RbCl in(H2O CH3OH) Mixtures at 298.15K[J];Journal of Liaocheng Teachers College(Natural Science Edition);1998-02
8 Li Linwei; Chu Deying; Liu Rmhn(College of Chemiastry and Moleculer Engineering. Peking University Beijing 100871: Departmentof Chemistry, Liaocheng Teache's College' Liaocheng 252O59);Determination of Activity Coefficients of RbCl in (H_2O-DMF) Mixed Solvents at 283.15 to 318.15K[J];ACTA PHYSICO-CHIMICA SINICA;1998-08
9 Li Linwei1 Chu Deying Liu Ruilin ( College of Chemistry and Molecular Engineering,Peking University, Beijing 100871; 1Department of Chemistry,Liaocheng Teachers College, Liaocheng City 252059);Determination of Standard Transfer Entropies of RbCl from H_2O to Mixtures of H_2O-DMF [J];ACTA PHYSICO-CHIMICA SINICA;1999-03
10 ZOU Li zhuang , WANG Xiao ling ,ZHU Shu quan (School of Chemical and Environmental Engineering, CUMT, Beijing 100083,China);Standard Gibbs Energies of Transfer for KBPh_4 from Water to Water+PrOH and Water+TBA Mixtures and the Primary Medium Effects[J];中国矿业大学学报(英文版);2002-02
【Co-references】
Chinese Journal Full-text Database 4 Hits
1 Lu Dian-Zhen;Men Dian-Yuan;Yiang Jia-Zhen; Liang Chun-Yu;Wang Yn;Fan Chui-Bin Department of Chemistry, Liaoning University, Shenyang;Study on Thermodynamic Properties of Mixed Electrolytes in Mixed Solvents——III. System of HCl-NaCl-i-PrOH-H_2O at 5 to 45℃[J];Acta Chimica Sinica;1989-01
2 Chu, De-Ying Han, Su-E Liu, Rui-Lin (Department of Chemistry, Peking University, Beijing, 100871);Using Ion-Selective Electrodes to Study the Thermodynamics of Solution Ⅴ. The Standard Glbbs Free Energies and Entropies of Transfer of KCl from H_2O to DMF-H_2O Mixture at Seven Temperatures from 283.15K to 318.15K[J];Acta Chimica Sinica;1993-08
3 Zhao Kaiyuan Lei Hongyi (Department of Chemistry,Peking Uiuversity);DETERMINATION OF ACTIVITY COEFFICIENTS IN CONCENTRATED HYDRO-CHLORIC ACID WITH Cl-ISE AND STUDY OF ADSORPTION OF Cl-ION[J];Acta Physico-Chimica Sinica;1987-04
4 Chu Deying Liu Li Liu Ruilin (Department of Chemistry,Peking University);THE STANDARD GIBBS ENERGIES OF TRANSFER AND THE ACTIVITY COEFFICIENTS OF NaF AND NaCl FROM WATER TO DIOXAN+WATER MIXTURES——USING IONSELECTIVE ELECTRODES TO STUDY THE THERMODYNAMICS OF SOLUTIONS[J];Acta Physico-Chimica Sinica;1987-05
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 CHEN Fang,WANG Wei-dong, HU Zhen-zhu (Dept. Chem. & Envn. Engn., Hubei Normal Univ., Huangshi 435002,Hubei,China);Determination of activity coefficient of Er(ClO_4)_3 in DMF with conductivity method[J];Journal of Baoji College of Arts and Science(Natural Science Edition);2005-01
2 WANG Wei-dong (Dept. Chem. & Envirn. Engin, Hubei Normal Univ., Huangshi 435002, Hubei,China);Study on the conductivity of rare earths salt NdCl_3 in DMF and H_2O at 298 K[J];Journal of Baoji College of Arts and Science(Natural Science Edition);2005-02
3 WANG Wei-dong, HU Zhen-zhu(Department of Chemistry and Environmental Engineering of Hubei Normal University,Hubei Huangshi 435002,China);Determination of The Molar Conductivity at Infinite dilution of DyCl_3 in DMF and H_2O at 298K[J];Journal of Changchun Teachers College;2004-10
4 WANG Wei-dong,WU Hui-juan,LIN Shu-xiong(College of Chemistry and Environmental Engineering,Hubei Normal University,Huangshi 435002,Hubei,China);Determination of the infinite dilution molar conductivity of DyCl_3 in isopropanol[J];Journal of Baoji University of Arts and Sciences(Natural Science Edition);2009-02
5 WANG Wei-dong (Department of Chemistry and Environmental Engineering, Hubei Normal University,Huangshi 435002,China);Determination of the Molar Conductivity at Infinite Dilution of YCl_3 in DMF and H_2O at 293K[J];;2005-03
6 WANG Wei-dong, HU Zhen-zhu (Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002,China);Study on activity coefficient of HCl in H_2O and 1.2-propanediol mixed solvent system with conductivity method[J];Journal of Hubei Normal University(Natural Science);2004-01
7 CHEN Fang , WANG Wei-dong , HU Zhen-zhu (Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002,China);Determination of activity coefficient of Er(NO_3)_3 in DMF[J];Journal of Hubei Normal University(Natural Science);2004-04
8 WANG Wei-dong (Department of Chemistry and Environmental Engineering , Hubei Normal University ,Huangshi 435002,China);Measurement method of activity coefficient of electrolyte solution[J];Journal of Hubei Normal University(Natural Science);2005-01
9 LU Jiang-lin,ZHENG Jing,WANG Wei-dong(College of Chemistry and Environmental Engineering,Hubei Normal University,Huangshi 435002,China);Studying the thermodynamics of ZnCl_2 in mixed solvent (ethanol and water)[J];Journal of Hubei Normal University(Natural Science);2009-01
10 Li ShuqinLin RuisenZong Hanxing (Department of Chemistry, Zhejiang Universtry, Hangzhou, 310027);Study on the Interaction between Preservative Sodium\=Benzoate and Biological Model Compound with Densimetry[J];HUAXUE SHIJIE (CHEMICAL WORLD);1999-07
China Proceedings of conference Full-text Database 4 Hits
1 Wang Weidong~*, Hu Zhenzhu, Chen fang (Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002);Study on the Activity Coefficient of ErCl_3 in H_2O with Conductivity Method[A];[C];2004
2 Wang Wei dong (Department of Chemistry and Environmental Engineering of Hubei Normal University, Hubei Huangshi 435002);Determination of The Molar Conductivity at Infinite dilution of YCl_3 in DMF and H_2O at 293K[A];[C];2005
3 WANG Wei-Dong (Department of Chemistry and Environmental Engineering of Hubei Normal University, Huangshi 435002);Use the Electric Conductivity to Assay the Activity Coefficient of LiCl in H_2O[A];[C];2005
4 WANG Wei-Dong (Department of Chemistry and Environmental Engineering of Hubei Normal University, Huangshi 435002);Study on The Conductivity of Rare Earths Salt Er(NO_3)_3 in DMF-H_2O Mixed Solvent[A];[C];2005
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved