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《Acta Chimica Sinica》 1995-07
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Investigation on the Electrochemical Polymerization and Electrochemical Behavior of 3,4-Ethylenedioxy-thiophene in Aqueous Solution

FANG Hui-Qun HOU Shi-Feng CHEN Hong-Yuan(Department of Chemistry, Nanjing University, Nanjing, 210093)  
polymerization of 3,4-ethylenedioxy-thiophene (PEDT) was investigated in neutral aqueous solution by electrochemical method. The electrochemical behavior of the polymer, and the electropolymerization mechanism were studied by cyclic voltammetry, FTIR, XPS and UV-spectroscopy. The study of polymerization mechanism showed that the electropolymerization was a radical cation polymerization process, and the anion of some electrolytes which effected the character of the polymer was involved in the polymerization..
【Fund】: 国家自然科学基金资助项目
【CateGory Index】: O633
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【References】
Chinese Journal Full-text Database 7 Hits
1 Du Xusheng She Pingping Wang Zhenghao (Department of Chemistry, Beijing Normal University, 100875, Beijing, China);THE STUDY OF ELECTROCATALYTIC PROCESSES OF CATECHOL AND p -DIHYDROXYBENZENE ON THE PEDOT MODIFIED ELECTRODE[J];Journal of Beijing Normal University(Natural Science);2005-02
2 SUN Deng-Ming; GU Hai-Ying; YU Ai-Min; CHEN Hong-Yuan(Department of Chemistry, Nanjing University, Nanjing, 210093);Preparation of Poly(fuchsin basic) Modified Electrode and Its Application[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;1997-03
3 SUN Xiao-jie,XIAO Ying-hong(School of Chemical Engineering,Nanjing University ofScience and Technology,Nanjing 210094,China);Preparation of Conducting Poly(3,4-ethylenedioxythiophene) and Investigation on Its Properties[J];Polymer Materials Science & Engineering;2007-02
4 WANG Jiao,TANG Xian-zhong,LI Yuan-xun,LI Shao-shuai(Department of Applied Chemistry,School of Micro and Solid-state Electronics,University of Electronic Science and Technology of China,Chengdu 610054,China);The Synthesis and Application of PEDT[J];Chemistry & Bioengineering;2006-12
5 Qian Xianfeng Li Hanxu Ding Liming Jia Jiangxia(Department of Chemical Engineering,Anhui University of Science and Technology, Huainan 232001);A new synthetic method of 3,4-ethylenedioxythiophene(EDOT)[J];New Chemical Materials;2007-02
6 DU, Xu Sheng SHE, Ping Ping WANG, Zheng Hao  (Chemical Department, Beijing Normal University, Beijing 100875);A Study on Conductivity and in-situ ESR Response of PEDOT[J];Acta Chimica Sinica;2003-04
7 CHEN Li ZHANG Xiao-Gang YUAN Chang-Zhou CHEN Sheng-Yao (College of Material Science & Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China);Electrochemical Properties of Poly(3,4-ethylenedioxythiophene)/ Manganese Oxide Synthesized by Interfacial Polymerization[J];Acta Physico-Chimica Sinica;2009-02
【Citations】
Chinese Journal Full-text Database 4 Hits
1 Chen Yanzhen Huang Haitao and Tian Zhaowu (Chem Dept Xiamen University Xiamen);The Electrochemical Polymerization of Thiophene in Acid Aqueous Solution[J];Chemical Research In Chinese Universities;1986-10
2 Guo, Ke-Zhen Li, Yong-Fang~* Pan, Cheng-Huang Qian, Ren-Yuan (Institute of Chemistry, Academia Sinica, Beijing);XPS Study of Depth Distribution of Anion in Conducting Polypyrrole[J];Acta Chimica Sinica;1990-01
3 Ge, Hai-Lin (Department of Chemistry, Wollongong University, P. O. Box 1144, Wollongong, Australia);Studies on Stoichiometry of Electrochemical Polymerization of Conducting Polymers Materials Technology Division, Singapore Institute of Standards and Industrial Research, Science Park Drive, Singapore 0511[J];Acta Chimica Sinica;1992-07
4 Dong Shaojun;Zhang wenbin Laboratory of Electroanalytical Chemistry,Changchun Institute of Applied Chemistry,Changchun 130022;CHARACTERIZATION OF POLYTHIOPHENE ELECTROCHEMICALLY POLYMERIZED IN AQUEOUS MEDIUM[J];Chinese Journal of Applied Chemistry;1991-01
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 ZHAO Dongjun~(1)) LU Anhuai WANG Lijuan ZHENG Xishen LIU Rui GUO Yanjun(School of Earth and Space Sciences, Peking University, Beijing, 100871; ()~(1)));Mineralogical Characteristics Study of Natural Cryptomelane in the Xialei Manganese Deposit, Guangxi[J];Acta Scicentiarum Naturalum Universitis Pekinesis;2005-06
2 HU Gang 1,2 XU Chun-chun 1 ZHANG Xin-sheng 1 (1. College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China; 2. Department of Chemistry, Huanggang Normal University, Huanggang 438000, China);Composition and structure of the passive film of 304 stainless steel in an occluded solution[J];Journal of Beijing University of Chemical Technology;2003-01
3 (Beijing University of Chemical Technology, Beijing,100029) (Hong Kong Polytechnic University, Hong Kong);Effect of the martensite phase transition of austenitic stainless steel on the corrosion resistance[J];JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY;1998-02
4 HU Jun, ONG Jianhua, WANG Dianzuo, SHU YongpingResources and Environmental Engineering Department Heilongjiang Institute of Science and Technology, Jixi 158105, ChinaUniversity of Science and Technology Beijing, Beijing 100083, ChinaBeijing General;ESCA Analysis of Flotation Reagent BET Reaction on Coal and Pyrite Surface[J];Journal of University of Science and Technology Beijing;2002-05
5 ;XPS Study of the Glass Surface Modification[J];Surface Technology;1999-05
6 Oiu Zhaoming;Rang Mei;Qiu Longwei(Dep. of Applied Geochemistry);DISCOVERY OF GOLD WITH NEGATIVE OXIDATION NUMBER IN PYRITE AND ARSENOPYRITE[J];;1994-02
7 GUO Xikun*,LIN Shudong(Department of Chemistry,Shantou University,Shantou 515063,Guangdong,China);Preparation of Cu/La/CeO_2-Al_2O_3 and Its Catalytic Activity for Selective Reduction of NO with Propylene[J];Chinese Journal of Catalysis;2008-03
8 Liu,Zhao-tie; Lu,Da-xun and Guo,Zhi-ying(Shanxi Institute of Coal Chemistrg, Chinese Academy of Sciences,Taiguan 030001);DEHYDROGENATION OF METHANOL TO METHYL FORMATE ON COPPER CATALYSTS SUPPORTED ON TITANIA COATED ALUMINA AND SILICA[J];CHINESE JOURNAL OF CATAL YSIS;1994-01
9 Wei, Li-hui; Hu, Ze-shan and Dai, Li-zhen(Sbanxi Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, 030001 );SELECTIVE SYNTHESIS OF METHYLAMINE OVER SHAPE-SELECTIVE ZEOLITE CATALYSTS[J];CHINESE JOURNAL OF CATAL YSIS;1995-06
10 LU Yan-ping, QU Zu-yu, FANG Bai-you;An Investigation of Black Tarnished Film on CrO_(3-)SiO_2 Passivated Electrogalvanized Steel Sheet[J];Materiais Protection;2000-12
China Proceedings of conference Full-text Database 1 Hits
1 Guan Ming Gao Sijian Zhu Yongchang Liu jun (China Building Materials Academy,Beijing 100024,China);The XPS Structure Research of Sm Borosilicate Glass[A];[C];2005
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 HE Yan(Changchun Education College,Changchun 130061,China);The Catalytic Reaction Mechanism under the Influence of the Catalyst[J];Journal of Changchun Teachers College;2005-02
2 ;The Development of Electrochemical Biosensors[J];Sensor World;1997-04
3 ;The Satus Quo in the Development of Conjugated Polymer-Based Smart Window[J];Materials Review;1995-02
4 REN Li WANG Lixin ZHAO Jinling ZHANG Fuqiang LI Zuobang (Institute of Polymer Science and Engneering,Hebei University of Technology,Tianjin,300130);Progress in Research on Conductive Polymer and Conductive Polypyrrole[J];Materials Review;2002-02
5 SHEN Qingyue, LU Chunhua, XU Zhongzi(College of Materials Science and Technology, Nanjing University of Technology, Nanjing 210009);Color-changing Mechanism of Electrochromic Materials and Their Research Progress[J];Materials Review;2007-S1
6 HUANG Jun-sheng 1,REN Shan 2,XIE Cheng-wei 1 (1.Faculty of Material, Guangdong University of Technology, Guangzhou 510643,China; 2.Department of Physics, ZHongshan University, Guangzhou 510275,China);Nanocrystalline Powder Copper Prepared by Reduction in Acqueous Solution[J];Journal of Materials Science and Engineering;2003-01
7 DING Xin-geng, YANG Hui, WANG Ming (Research Center of Nanometer Science and Technology, State Key Laboratory of Silicon, Zhejiang University, Hangzhou 310027, China);Preparation and Properties of Antibacterial and Anticorrosive Film Made of Silane Coupling Agent Solution Adding Ag~+ on Stainless Steel Surface[J];Journal of Materials Science and Engineering;2004-05
8 LI Xin-gui,XIA Yu,HUANG Mei-rong (Tongji University, Shanghai 200092, China);Electrochromic Property of Conducting Polymers and Their Application on Smart Windows[J];Development and Application of Materials;2004-02
9 LUO Ju DING Xingzhao CHENG Lifang MA Xueming DONG Yuanda (Institute of Solid State Physics,Academia Sinica);STUDY ON THE STRUCTURE OF NANOMETER-SIZED TITANIA POWDERS PREPARED BY A SOL-GEL METHOD[J];;1993-01
10 CHEN Qidao;LU Jianping;HONG Xiaoyin (Tsinghua University);PROGRESS OF CONDUCTIVE POLYMER[J];CHINESE JOURNAL OF MATERIAL RESEARCH;1997-06
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 Du Xusheng She Pingping Wang Zhenghao (Department of Chemistry, Beijing Normal University, 100875, Beijing, China);THE STUDY OF ELECTROCATALYTIC PROCESSES OF CATECHOL AND p -DIHYDROXYBENZENE ON THE PEDOT MODIFIED ELECTRODE[J];Journal of Beijing Normal University(Natural Science);2005-02
2 Sun yuanxi (Hunan Changde Teatchers College,Changde, 415000);Conducting Polymer Film Modified Electrodes and Its Analytical Application[J];;1997-03
3 SUN Yuan-xi 1 ZHOU Gu-zhen 1 ZHOU Sheng-wu 2 YANG You-mou 3 (1.Department of Chemistry,Changde Teacher's University,Changde Hunan 415000; 2.No.1 Middle School of Taojiang,Hunan 414200; 3.Dingcheng No.8 Middle School of Dingcheng,Changde Hunan 415008);STUDY ON THE ELECTROCHEMICAL CHARACTERISTICS OF POLY(NEUTRAL RED) FILM MODIFIED ELECTRODE[J];Journal of Changde Teachers University;2002-04
4 ZHOU Gu-zhen YANG You-mo TIAN ZHeng - ping SUN Yuan - xi (Chemistry Department of Hunan University cf Arts and Science ,Changde, Hunan, 415000);Preparation of Poly(fluorescein) Film Modified Electrodes[J];;2004-03
5 Chen Ying(Detection center of Fuzhou University,Fuzhou,350002,China);Application Advances of Molecule Self-assembled Films in Electroanalytical Chemistry[J];Fujian Analysis & Testing;2006-01
6 MA Wei,SUN Deng-ming(Department of Chemistry,Huaibei Coal Industry Teachers College,235000,Huaibei,Anhui,China);The Preparation and Application of the Polymer Modified Electrode[J];Journal of Huaibei Industry Teachers College (Natural Sciences Edition);2005-04
7 Sun Yuanxi (Changde Normal college, Changde 415000) Ye Baoxian, Zhou Xingyao (Department of Chemistry, Wuhan University 430072);Electrochemical Behavior of Neurotransmitter at Poly(neutral red) Modified Electrode and Application[J];Chinese Journal of Analytieal Chemistry;1998-05
8 Wang Zhenhui; Jia Jianbo; Li Gongan; Zhou Shuping (College of Chemistry and Environmental Science, He'nan Normal University, Xinxiang 453002);Electrochemical Behaviour of Dopamine on the Polytheophylline/Nafion Dual-layer Modified Glassy Carbon Electrode[J];CHINESE JOURNAL OF ANALYTIEAL CHEMISTRY;2000-05
9 Yang Qiuxia, Ma Yurong, He Wei, Wang Xuelin (Department of Applied Chemistry, Jinan University, Jinan 250022);Electrochemistry and Electrocatalysis of Electropolymerized Vitamin B_1 Film Electrode[J];Chinese Journal of Analytieal Chemistry;2001-06
10 Yuan Zhuobin *, Zhang Yuzhong, Zhao Hong (Department of Chemistry, Graduate School, University of Science and Technolody of China, Beijing 100039);Electrocatalysis of Poly-azure I Modified Glassy Carbon Electrode for Reduction of Hemoglobin[J];Chinese Journal of Analytieal Chemistry;2001-11
China Proceedings of conference Full-text Database 4 Hits
1 Pingping She, Zhenghao Wang Department of Chemistry, Beijing Normal University, Beijing 100875,PR China;Redox kinetics of PEDOT[A];[C];2005
2 Pingping She, Zhenghao Wang Department of Chemistry, Beijing Normal University, Beijing 100875,PR China;Effects of pH on the properties of electrosynthesized PEDOT films[A];[C];2005
3 Pingping She, Zhenghao Wang Department of Chemistry, Beijing Normal University, Beijing 100875,PR China;The behavior of PEDOT in dedoped potential range[A];[C];2005
4 Pingping She, Zhenghao Wang Department of Chemistry, Beijing Normal University, Beijing 100875,PR China;A study on overoxidation mechanism of PEDOT at an anode[A];[C];2005
【Secondary Citations】
Chinese Journal Full-text Database 2 Hits
1 Chen Yanzhen Huang Haitao and Tian Zhaowu (Chem Dept Xiamen University Xiamen);The Electrochemical Polymerization of Thiophene in Acid Aqueous Solution[J];Chemical Research In Chinese Universities;1986-10
2 Cao Yong Guo Ding Ye Cheng Pang Mei(Institute of Chemistry,Academia Sinica,Beijing);Characterization of α, α'-Linked Thiophene Oligomers[J];Acta Chimica Sinica;1987-11
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