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《Acta Chimica Sinica》 1998-09
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Studies on Polymerization of Styrene in Microemulsions

SHI Yuan - Chang HAO Jing - Cheng TAO Cheng HUJi-Ye LI Gan-Zuo(Laboratory of Surface and Interface, Shandong Normal University, Jinan, 250014) (Institute of Colloid and Interface Chemistry,Shandong University,Jinan,250100)  
The isothermal phase diagram for the system sodium dodecyle sulfonate/n - butanol/20% styrene/water has been determined at 40℃ . The polymerization of styrene in O/W, W/O, and BC microemulsions was investigated by using the water - soluble potassium persulfate and oil - soluble azo - bis - isobutyronitrile(AIBN) as initiators. The relationship between the conversion rate of styrene, the molecular weight of polystyrene and the water content of the system was obtained, and the effect of microemulsion structures on the polymerization of styrene was alsodiscussed. With the microscope,the feature of polystyrene particles was observed and the diameter was 20 ~ 60 nm. At the same time, in order to analyze the polymerization of styrene, the solubilization site of styrene in microemulsion drops was studied by 1H NMR spectra.
【Fund】: 国家自然科学基金(28970136);; 山东省自然科学基金资助项目
【CateGory Index】: TQ316.3
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