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《Acta Chimica Sinica》 2000-03
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Effect of Functional Monomer on Chiral Separation Ability of Molecular Imprinted Chiral Stationary Phase

WANG Jin-Fang ZHOU Liang - Mo LIU Xue - Liang WANG Qing-Hai ZHU Dao-Qian( Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian, 116012)  
The effect of functional monomer on chiral separation ability of the non - covalent molecular imprinted chiral stationary phase was investigated systematically. It was found that there was compatibleness between the functional monomer and the template molecules. Strong hydrogen bond and ionic interaction could be formed between the amide group and carboxyl group in the amino acid derivatives and acrylamide and 2 -vinylpyridine, which made the imprinting effect of the combined functional monomers AM + 2 - VP more evident. The competing solvent acetic acid showed great influence on the non - covalent interaction between the analyte and the functional groups of molecular imprinted polymer (MIP). Ionic interaction and hydrogen bonding between amide group and carboxyl group in the analyte and the functional groups of MIP were weakened by increasing the concentration of the competing solvent acetic acid, therefore both the capacity factor, chiral selectivity factor and resolution decreased.
【Fund】: 国家自然科学基金(29575212)资助项目
【CateGory Index】: O658
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7 Li Ping Rong Fei Xie Yibing Zhu Xinle Yuan Chunwei ( 1Department of Biomedical Science and Medical Engineering, Southeast University, Nanjing 210096, China) ( 2Department of Bioengineering, Beijing University of Aeronautics and Astronautics, Beijng 100083, China);Study on binding characteristics of (S)-naproxen imprinted polymer and performance of its complexes during preparation[J];Journal of Southeast University (Natural Science Edition);2003-04
8 LIU Hui1, LIU Hong-xia2, WANG Zun-yao2, WANG Lian-sheng3(1.Department of Material and Chemical Engineering,Guilin Institute of Technology,Guilin 541004,China;2.School of Biological and Chemical Engineering,Jiaxing College,Jiaxing 314001,China;3.Department of Environment,Nanjing University,Nanjing 210093,China);Quantitative Structure-Property Relationship for Fluorine-contained Aromatics[J];Environmental Science & Technology;2009-01
9 Zhou Zhiqiang\ Zhang Hongyan\ Yu Zhaowen\ Hou Jingguo\ Chen Liren(Lanzhou Institute of Chemical Physics, the Chinese Academy of Sciences Lanzhou 730000);Enantiomeric Resolution of Chiral Drugs by HPLC[J];ANALYSIS AND TESTING TECHNOLOGY AND INSTRUMENTS;1998-01
10 Meng Zihui, Wang Qinghai, Zhu Daoqian, Zhou Liangmo (Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012);Application of Molecular Imprinting in Chira1 Separation[J];Chinese Journal of Analytieal Chemistry;1997-03
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 ZHANG Qiaozhen SHI Jinsheng DENG Qiliang JING Zuoliang (Institute of Science,Tianjin University of Science and Technology,Tianjin 300222);Molecular Imprinting Polymer[J];Materials Review;2003-S1
2 XUE Xiu-heng,PAN Jian,XIE Hui-ming,ZHANG Shuang(Engineering Research Center of Bio-Process,Ministry of Education,He fei University of Technology,Hefei Anhui 230009,China);Effect of different preparation condition on SpA-molecularly imprinted polymer microspheres[J];Journal of Chinese Electron Microscopy Society;2008-05
3 CHANG Jing1,ZHU Jun1,DI Yumin2,ZHANG LeiPing1,HAO Hongxia3,HE Yi1,YU Zhongshan1 1.Institute of Forensic Science,Ministry of Public Security,Beijing 100038,China;2.Chinese People's Public Security University,Beijing 100038,China;3.China University of Political Science and Law,Beijing 100088,China;The development of molecularly imprinted technology research in forensic science toxicology[J];Chinese Journal of Forensic Medicine;2010-06
4 LIU Fan,XIONG Zhi-chao,ZHANG Ling-yi,ZHANG Wei-bing (East China University of Science and Technology,Shanghai 200237,China);Methods for Cleaning and Regeneration of High Performance Liquid Chromatographic Columns[J];Analysis and Testing Technology and Instruments;2010-02
5 Liu Ying, Liu Xueliang, Wang Junde  (Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012);The Adsorption Property of Nicotine-Imprinted Polymer[J];Chinese Journal of Analytical Chemistry;2003-10
6 Zhang Jing, He Langchong *, Fu Qiang (College of Medicine, Xi′an Jiaotong University, Xi′an 710061);Preparation of Strychnine Molecularly Imprinted Monolithic Column[J];Chinese Journal of Analytical Chemistry;2005-01
7 HUANG Jian-xiang,HU Yu-ling,LI Gong-ke*(School of Chemistry and Chemical Engineering,Sun Yat-sen University,Guangzhou 510275);The Development of Selective Coating for Solid Phase Microextraction[J];Journal of Analytical Science;2008-01
8 FU Ruo nong (Department of Chemistry, Beijing Institute of Technology, Beijing 100088),Fenxi Shiyanshi,2003,22(2):94~107;Advances on gas chromatography in China[J];Analytical Laboratory;2003-02
9 LIU Zheng,WEN Yu-qing,HUANG Mei-chun(Department of Materials and Chemistry Engineering,Guilin University of Technology,Guilin 541004,China);Preparation and Adsorbability of Copper Ion Imprinted Polymer[J];Journal of Guilin University of Technology;2007-01
10 YANG Zuo-guo1,GU Xiao-yan2,XU Zhen-liang1,HUI Shao-liang2,BING Nai-ci1(1.Insititute of Chemical Engineering,East China Univ.of Sci.and Tech.,Shanghai 200237,China;2.Insititute of Shanghai Chemical Reagent,Shanghai 200241,China);Study on the Preparation of Dibenzoyl-L-tartaric Acid(L-DBTA) Imprinted Composite Membranes and its Properties[J];Journal of Chemical Engineering of Chinese Universities;2007-05
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