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《Acta Chimica Sinica》 2002-04
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Electroless Ag Plating on Self-assembly Monolayer

LIU, Zheng-Chun a HE, Quan-Guo a XIAO, Peng-Feng a LIANG, Bo b HE, Nong-Yue ,a LU, Zu-Hong ,a ( a Key Laboratory for Molecular and Bio-molecular Electronics of Ministry of Education, Nanjing 210096) ( b College of Chemistr  
Mercaptopropyltrimethoxysilane(MPTS) was used to form self-assembly monolayers (SAMs) on glass substrates by solution extraction, which was checked with XPS and AES. These prepared glass slides were used as substrates for electroless Ag plating. XPS study showed that Ag colloids formed in the solution were successfully and firmly anchored on SAMs through Ag─S bonds. By the Ag-Ag interaction, Ag was then deposited to produce a silver-coated glass. SEM and XRD analysis illustrated that the Ag film on the SAMs-modified glass was superior in durability over that of the Ag film on the conventionally modified glass and the crystallinity of Ag film on the SAMs-modified glass was identical to that of the Ag film on the conventionally modified glass and pure Ag.
【Fund】: 国家 8 6 3计划 (No .10 3 13 0 5 0 1 10 1 0 1 0 1);; 973计划 (No .G19980 5 12 0 4);; 国家自然科学基金 (No.6 0 0 710 0 1);; 教育部“高等学校骨干教师资助计划”项目
【CateGory Index】: TQ153
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