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《Acta Chimica Sinica》 2002-05
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Synthesis of Novel Metalloporphyrins and Their Action on the Growth Metabolism of E. coli

LI, Zao-Ying ZHANG, Yue-Ning XIE, Zheng ZHU, Xun-Jin GAO, Zhen-Ting LIU, Yi (Department of Chemistry, Wuhan University, Wuhan 430072)  
Based on 5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrin (2), a series of water insoluble and water-soluble metalloporphyrins has been synthesized. An LKB-2277 thermal activity monitor was used to monitor the cell metabolic activity in vitro to produce thermogenesis curves. The growth rate constants k, maximum heat production rates p max and peak time of growth thermogenic curves t of E. coli in different metalloporphyrins at different concentrations were deduced from these thermogenesis curves. Metalloporphyrins 4a~4f and 7a~7f show inhibiting action on the growth metabolism of E. coli with water-soluble metalloporphyrins 7a~7f being the better ones.
【Fund】: 国家自然科学基金 (No .2 9972 0 35 );; 武汉大学自强科学基金 2 0 0 0年资助项目
【CateGory Index】: R914
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