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《Acta Chimica Sinica》 2002-07
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Electrochemical Behavior of Hemoglobin at a Lipid-Lauric Acid Modified GC Electrode and Its Application to the Determination of Proteins

JIN, Song-Zi WANG, Tao ZHANG, Chun-Xu SHEN, Han-Xi (Chemical School, Nankai University, Tianjin 300071)  
The electrochemical behavior of hemoglobin at a lipid-lauric acid modified glassy carbon electrode (GC) is reported. In the potential range of +0.8~-0.7 V (vs. Ag/AgCl), an irreversible cathodic peak was observed at -0.4 V at the scan rate of 20 mV/s. In the medium of 0.01 mol/L KH 2PO 4-Na 2HPO 4(pH 6.0), the cathodic peak current shows linear relationship with the concentration of hemoglobin in the range of 1.25×10 -8~4.31×10 -7 mol/L. The electrode can be used as an approach for determining hemoglobin with high sensitivity.
【Fund】: 国家自然科学基金 (No .2 9875 0 11)资助项目
【CateGory Index】: O646
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