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《Acta Chimica Sinica》 2012-10
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Fabrication of Ordered One-dimensional P3HT/CdS/TiO_2/ZnO Core-Shell Nanorod Array and Their Application to Hybrid Solar Cell

Hao,Yanzhong*,a Cao,Yinhua Sun,Baoa Zhang,Yanhuia Li,Yingpina Xu,Dongshengb Li,Xianglingc(aCollege of Sciences,Hebei University of Science and Technology,Shijiazhuang 050018)(bCollege of Chemistry and Molecular Engineering,Peking University,Beijing 100871)(cTianjin Motimo Membrane Tech.Co.,Ltd.,Tianjin 300457)  
In this paper,ordered one-dimensional poly(3-hexylthiophene)(P3HT)/CdS/TiO2/ZnO core-shell nanorod arrays were fabricated.Highly ordered and vertically oriented one-dimensional ZnO nanorod arrays were electrodeposited on the indium-tin oxide(ITO) glass substrates.TiO2 sol was deposited on ZnO nanorod array by dip-coating to obtain TiO2/ZnO core-shell nanorod array.CdS nanocrystals were electrodeposited on the TiO2/ZnO core-shell nanorods to fabricate CdS/TiO2/ZnO core-shell nanorod arrays.Then a thin P3HT layer was electrodeposited on the CdS/TiO2/ZnO core-shell nanorod arrays to prepare the photoanode of the nanostructured hybrid solar cell.The photovoltaic performance of the hybrid solar cell was tested,and the mechanism of the solar cell was investigated.
【Fund】: 国家自然科学基金(Nos.21173065 20573031);; 河北省自然科学基金(No.B2010000856)资助项目~~
【CateGory Index】: TM914.4;TB383.1
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