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《Chemical Research and Application》 2002-04
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Studies on the adsorption of D201×4 resin for Cr(Ⅵ)

SHEN Qiou xian,SU Zen nian,WANG Yong jiang,XIONG Chun hua(Department of Chemistry,Lishui,Teathers College,Lishui Zhejiang 323000,China)  
Cr(Ⅵ) was quantitatively adsorbed by D201×4 resin with pH=2.63~3.66 in the medium of HAc NaAc.The statically saturated sorption capacity is 156.8mg/g·resin.The sorption rate constant is k 298 =1.80×10 -4 s -1 .The apparent sorption activation energy of APAR for Cr(Ⅵ) is 7.21kJ·mol -1 .The themodynamic parameters of sorption:enthalpy change ΔH,free energy change ΔG and entropy change ΔS of sorption (D201×4) for Cr(Ⅵ) are 33.12kJ·mol -1 ,-28.36kJ·mol -1 ,206.3J·mol -1 ·K -1 ,respectively.Coordination molar ratio of the functional group of D201×4 to Cr(Ⅵ) is 1∶1.Cr(Ⅵ) adsorbed on D201×4 can be reductively eluated by 5% NH 4Cl-10% NH 3·H 2O.The sorption rate of D201×4 for Cr(Ⅵ) is fast.The equilibrium time of adsorption is five hours.
【Fund】: 浙江省高校中青年学科带头人基金;; 浙江省教育厅资助项目 (2 0 0 10 667);; 丽水市科技局计划项目 (2 0 0 10 12 )
【CateGory Index】: O647.3
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