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《Chemical Research and Application》 2008-04
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Catalytic kinetic spectrophotometric determice vanadium(V) by system of potassium peridate oxidation remazol brilliant blue R

CHEN Hua-ping1,WANG Zhao-li2,HUANG Qian-ming1,YIN Jia-jian1(1.College of Biology and Science,Sichuan Agricultural University,Yaan 625014,China;2.Chengdu Environment Protection Science Academy,Chengdu 610072,China)  
A catalytic kinetic spectrophotometric method for the determination of trace vanadium(V) based on the redox reaction between potassium bromate and remazol brilliant blue R in the presence of ascorbic acid as an activator in acetic acid medium has been proposed.The optimum conditions and kinetic parameters have been in vestigated.The calibration graph is linear for 0~6.4 μg·L-1 V(V).The detection limit for vanadium(V) is 3.4×10-11 g·mL-1.The catalytic and non-catalytic reactions are the first-order on vanadium(V).The apparent activation energy of the catalytic reaction is 69.84 KJ·mol-1.The Relative Standard Deviations(RSD) are 0.53% and the recoveries are 96.7 %-100.3 %.The method has been applied to the determination of trace vanadium(V) in water and flour samples with satisfactory results.
【Fund】: 国家863计划项目(2006AA10Z1F8和2006AA10Z179)资助;; 四川农业大学科技创新基金项目(007311)资助
【CateGory Index】: O657.3
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