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《Chemical Research and Application》 2008-07
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Synthesis of derivatives of bornel containing chiral amines

ZHU Hong1,YANG Jin-hui2,3,4,LI Xue-qiang2,3,4(1.Assets Administrative Office of Ningxia University,Yin Chuan 750021,China; 2.Key Laboratory of Energy Sources and Chemical Engineering of Ningxia,Yin Chuan 750021,China; 3.Developmental Center of Natural Products and Medication,Yin Chuan 750021,China; 4.College of Chemistry and Chemical Engineering,Ningxia University,Yinchuan 750021,China)  
The asymmetric Michael addition-elimination reaction of chiral 5-(1S)-bornyloxy-3,4-dibromo-2(5H)furanones and some amines are investigated.Four new chiral bornyl amine derivatives 6a~6d are obtained.they are identified by IR,1H NMR,13C NMR,HRMS and so on.It offer a new way to synthetize more chiral bornyl amine derivatives.
【Fund】: 国家自然科学基金资助项目(20562010);; 国家重点基础研究发展计划资助项目(2007CB2160);; 教育部科技研究重点资助项目(203143)
【CateGory Index】: O621.25
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【Citations】
Chinese Journal Full-text Database 2 Hits
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【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 ZHONG Guo-chen,LI Jia-ming (Dept. of Pharmaceutical Chemistry,Anhui College of Traditional Chinese Medicine,Hefei 230038,China);Synthesis of Pazufloxacin Mesilate[J];Anhui Chemical Industry;2006-04
2 Huang Min Chen Qinghua (Department of Chemistry, Beijing Normal University, 100875, Beijing, China);STUDIES ON TANDEM ASYMMETRIC DOUBLE MICHAEL ADDTION AND INTERNAL NUCLEOPHILIC SUBSTITUTION[J];JOURNAL OF BEIJING NORMAL UNIVERSITY(NATURAL SCIENCE);2000-01
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9 LING Xia1,DENG Da-wei2,ZHONG Wen-ying1,YU Jun-sheng21.Department of Analytical Chemistry,China Pharmaceutical University,Nanjing 210009,China2.School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210093,China;Quantitative Determination of Pazufloxacin Using Water-Soluble Quantum Dots as Fluorescent Probes[J];Spectroscopy and Spectral Analysis;2008-06
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