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《Chemical Research and Application》 2009-02
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Preparation and recognition properties of GA_3-imprinted polymers/membranes

WANG Guo-song,YANG Xue-qiong,FANG Yun-shan,ZHU Xiu-fang,ZHANG Hong-bin,DING Zhong-tao(School of Chemical Science and Technology,Key Laboratory of Medicinal Chemistry forNature Resource,Ministry of Education,Yunnan University,Kunming 650091,China)  
Four gibberellic acid(GA3)-imprinted polymers(MIP1-4)and two GA3-imprinted membranes(MIM1-2)had been prepared in chloroform or in methanol using different functional monomers(MAA or AM),respectively.The interaction between template and functional monomers was studied by UV spectrophotometry,which showed a formation of GA3-monomer complexes with 1:2.The polymeric particles were tested in the equilibrium binding experiment to analyze its adsorption ability to GA3.The recognition properties of MIP and MIM were compared with and prior to those of the NIP and NIM.The permeation experiment showed that MIM1 prepared in chloroform using AM as functional monomer,exhibited higher permeation selectivity to gibberellic acid.
【Fund】: 国家自然科学基金(30260014)资助;; 云南省自然科学基金(2006B002Q)资助
【CateGory Index】: O631.3
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