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《Journal of Jinan University(Natural Science & Medicine Edition)》 2009-03
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Removal of HABs algae using clay modified by quaternary ammounium

HUANG Juan1,LIU Jie-sheng1,2,TAN Shao-zao1,YANG Wei-dong1,2,ZENG Xiao-hong1,LI Hong-ye1(1.Department of Biotechnology,Jinan University;2.Guangdong Province's High Education Key Lab of Eutrophication and Red tid Control;3.Department of Chemistry,Jinan University,Guangzhou 510632,China)  
The removal of the modified clay with tetradecyldimethylbenzyl ammonium cations on the harmful algal blooms(HABs) algae,Chattonella marina and Alexandrium tamarense were explored.The results indicated that the modified clay had an excellent ability to extinguish the two HABs algae in dose-effect manner and time-dependent relation.When the modified clay was 0.012 g·L-1,85 % C.marina cells were removed in 24 h,and 95% in 72 h.Meanwhile,less than 50% A.tamarense cells were removed under the concentration of 0.016 g·L-1 in 24 h.However,the removal efficiency increased with time.77% of A.tamarense cells were removed in 48 h,and 85% in 72 h.Compared with the high removal efficiency,natural clay had less effect on the two algae.When the natural clay was 0.03 g·L-1,the removal efficiency was less than 70% in 72 h even for C.marina.Besides,the modified clay was shown to have a strong coagulation on the two algae.These suggested that the introduction of tetradecyldimethylbenzyl ammonium cations could strengthen the removal ability of clay,which played an important role in the removal.The modified clay might be a potential algaecide with high effectiveness and long acting time.
【Fund】: 国家重点基础研究发展规划973项目(2001CB409710);; 国家自然科学基金项目(20676049 20871058);; 广东省科技计划项目(2004B20501007);; 广州市环保局项目
【CateGory Index】: X55
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