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《Acta Parasitologica Et Medica Entomologica Sinica》 1994-01
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SYNTHESIS AND SPECIES SPECIFIC ATTRACTANCY OF AN OVIPOSITION ATTRACTANT PHEROMONE OF CULEX PIPIENS QUINQUEFASCIATUS

Zhang Jintong; Liu Xun; kong Jie;Zhang Zhongning; Bai Yunxiu The Project supported by National Natural Science Foundation of China. (Institute of Microbiology & Epidemiology,AMMS,Beijing 100071.) (Institute of Zoology,Academia Sinica. Beijing 100080.)  
The oviposition attractant pheromone of Culex pifoens quinque fasciatus was identified as erythro-6-acetoxy-5-hexadecanolide. A mixture of erythro-and threo-isomers of the lactone was synthesized by the aldol condensation from cyclopentanone and undecanol,producing 2-(1-hydroxyl undecyl-1-)cyclopentanone,then by the Baeyer-Villiger reaction and acetyoation. The synthetic product was consisted of equal protportions of four isomers including the active erythro-(5R,6S) and its enantiomer, and another two threo-enantiomers.Oviposition attractancy tests were made with the synthetic pheromone to four species/subspecies of mosquitoes.The synthetic pheromone showed an attractant effect to both Cx.p. pellens and Cx. p. quinque fasciatus,with a stronger effect to the former and keeping it for at least 10 days,and no effect to Cx. tritaeniorhynchus and Aedes aegypti,inferring that the pheromone is of species,but not genus,specificity.
【Fund】: 国家自然科学基金
【CateGory Index】: R384.1
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