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Synthesis of Diethyl Sebacate Using Tungstophosphoric Acid as Catalyst

LIN Jin,ZHANG Yan feng (Department of Chemistry, Hebei Normal University, Shijiazhuang 050016, China)  
It was found that tungstophosphoric acid was superior to H 2SO 4 when used as catalyst for esterification of ethyl alcohol with sebacic acid.The optimum conditions of the reaction were determined:the molar ratio of ethyl alcohol to sebacic acid was 4 0∶1,the amount of tungstophosphoric acid was about 4% of the mass of sebacic acid charged in the reaction and the reaction time was 4h.Conversion of sebacic acid was 96 85%,the selectivity was 99 8%,and the purity of the product was over 98%.This catalyst could be used repeatedly for many times.
【CateGory Index】: O623.624
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