Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《FINE CHEMICALS》 2000-05
Add to Favorite Get Latest Update

Preparation of Cyclohexene by Dehydration of Cyclohexanol on Dealuminated USY

ZHANG Min,YUAN Xian you (Department of Chemistry,Lingling Teachers′ College,Yongzhou 425000,China)  
Preparation of cyclohexene by dehydration of cyclohexanol on dealuminated USY was studied.The influences of silica/alumina in the catalyst,catalyst amount,reaction temperature and time on the reaction were investigated.The most suitable conditions for the reaction were as follows:molar ratio of SiO 2/Al 2O 3 in catalyst 10.99,mass ratio of catalyst to cyclohexanol 7 5%,reaction temperature(oil bath) 180-190 ℃,reaction time 1 h.The yield was up to 87 8%,and the catalyst was reusable.
【Fund】: 湖南省自然科学基金!资助项目 ( 94 -2 0 9-1 5)
【CateGory Index】: TQ23
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 10 Hits
1 ZHANG Xia~(1,2),WU Feng-hua~1,HU Yi-min~1 (1.College of Chemistry and Materials Science,Anhui Normal University, Wuhu 241000,China;2.Department of Chemistry,Anqing Teacher's College,Anqing 246011,China);Preparation of Cyclohexene by Dehydration of Cyclohexanol on SO_4~(2-)-La_2O_3-TiO_2 Catalyst[J];Journal of Anhui Normal University(Natural Science);2006-01
2 YU Shan-xin, GUAN Shi-bin, LIU Mei-yan(College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China);Preparation of Cyclohexene from Dehydration of Cyclohexanol Catalyzed by Solid Acid[J];Journal of Chenzhou Teachers College;2005-02
3 WU Yurong,DING Jielian,LIN Ling,ZENG Chongyu*(College of Chemistry and Chemical Engineering,Nanjing University of Technology,Nanjing 210009,Jiangsu,China);Study on WO_3/M_xO_y catalyst for dehydration of cyclohexanol to cyclohexene[J];Industrial Catalysis;2008-07
4 WANG Lan-zhi1,YANG Li-jing2,ZHAO Xiao-hong3,HE Xuan1 (1.College of Chemistry and Material Science,Hebei Normal University,Hebei Shijiazhuang 050016,China;2.The Cadre College of Chinese Environmental Management,Hebei Qinhuangdao 066004,China;3.Qinhuangdao Branch,North China Coal Medical College,Hebei Qinhuangdao 066004,China);Synthesis of Cyclohexene under Green Chemistry Philosophy[J];Journal of Hebei Normal University(Natural Science Edition);2009-02
5 LI Ji-zhong (The Shanxi Province Key Laboratory of Chemical Reaction Engneering, Department of Chemistry and Chemical Engineering, Yanan University, Yanan 616000, China);The Synthesis of Cyclohexene Catalyzed by Sodium Hydrogen Sulfate[J];Chinese Journal of Synthetic Chemistry;2004-03
6 TANG Man-sheng,LIU Xing-ming,YUAN Xian-you,ZHANG min (Department of Chemistry and Bioengineering,Hunan University of Science and Engineering,Yongzhog 425100,China);Preparation of Cyclohexene from Cyclohexanol by Dehydration Using I_2/C as a Catalyst[J];Chinese Journal of Synthetic Chemistry;2009-03
7 Guo Junsheng (Department of Chemistry,Xinxiang Teacher′s College,Xinxiang 453000);Preparation of cyclohexene by catalyzed dehydration of cyclohexanol[J];Chemical Reagents;2001-03
8 Yuan Xian you ,Zhang Min,Liu Yuanyuan (Department of Chemistry,Lingling Teacher′s College,Yongzhou 425000);Synthesis of cyclohexene catalyzed by SnCl_4[J];Chemical Reagents;2001-03
9 CHEN Ping (Liaoning University of Petrochemical & Technology,Fushun 113001);Preparation of cyclohexene by dehydration of cyclohexanol on Hβ zeolite[J];Chemical Reagents;2004-05
10 LING Shao ming, LONG Jin qiao (Department of Chemistry, Guangxi YouJiang Teachers College, Guangxi Baise 533000, China);Synthesis of Cyclohexene on Nafion/SiO_2 Catalyst[J];Huaxue Shijie (Chemical World);2002-10
【Citations】
Chinese Journal Full-text Database 1 Hits
1 Yuan Xianyou; Zhang Min(Department of Chemistry, Lingling Teachers' College, Yongzhou, 425006,China);STUDIES ON THE CATALYSIS OF FAUJUSITE IN FINE ORGANIC SYNTHESIS-XV ESTERIFICATION OF CARBOXYLIC ACID WITH ALCOHOL CATALYZED BY DEALUMINATED USY[J];NATURAL SCIENCE JOURNAL OF XIANGTAN UNIVERSITY;1997-03
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 YU Shan-xin, GUAN Shi-bin, LIU Mei-yan(College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China);Preparation of Cyclohexene from Dehydration of Cyclohexanol Catalyzed by Solid Acid[J];Journal of Chenzhou Teachers College;2005-02
2 WANG Lan-zhi1,YANG Li-jing2,ZHAO Xiao-hong3,HE Xuan1 (1.College of Chemistry and Material Science,Hebei Normal University,Hebei Shijiazhuang 050016,China;2.The Cadre College of Chinese Environmental Management,Hebei Qinhuangdao 066004,China;3.Qinhuangdao Branch,North China Coal Medical College,Hebei Qinhuangdao 066004,China);Synthesis of Cyclohexene under Green Chemistry Philosophy[J];Journal of Hebei Normal University(Natural Science Edition);2009-02
3 LI Ji-zhong (The Shanxi Province Key Laboratory of Chemical Reaction Engneering, Department of Chemistry and Chemical Engineering, Yanan University, Yanan 616000, China);The Synthesis of Cyclohexene Catalyzed by Sodium Hydrogen Sulfate[J];Chinese Journal of Synthetic Chemistry;2004-03
4 Yuan Xian you ,Zhang Min,Liu Yuanyuan (Department of Chemistry,Lingling Teacher′s College,Yongzhou 425000);Synthesis of cyclohexene catalyzed by SnCl_4[J];Chemical Reagents;2001-03
5 CHEN Ping (Liaoning University of Petrochemical & Technology,Fushun 113001);Preparation of cyclohexene by dehydration of cyclohexanol on Hβ zeolite[J];Chemical Reagents;2004-05
6 LING Shao ming, LONG Jin qiao (Department of Chemistry, Guangxi YouJiang Teachers College, Guangxi Baise 533000, China);Synthesis of Cyclohexene on Nafion/SiO_2 Catalyst[J];Huaxue Shijie (Chemical World);2002-10
7 YUAN Xian-you(Hunan University of Science and Engineering;Hunan Yongzhog,425006,China);Preparation of cyclohexene by catalyzed dehydration of cyclohexanol by SnCl_4·5H_2O under microwave irradiation[J];Journal of Lingling University;2004-11
8 CHEN Ping (School of Petrochemical Technology,Liaoning University of Petroleum & Chemical Technology,Fushun 113001,China);Studing on prepration of cyclohexene by various catalysts[J];Shaanxi Chemical Industry;2004-03
9 ZHANG Min~1,WANG Xiao-yong~1,CHEN Ai-min~2 (1.Department of Chemistry,Lingling Teachers’ College,Yongzhou,Hunan 425000,China; 2.Department of Chemistry,Shaoyang Teachers’ College,Shaoyang,Hunan 422000,China);Catalytic Synthesis of Cyclohexanone Ethylene Glycol Ketal by Dealuminated USY[J];PETROCHEMICAL TECHNOLOGY;2000-11
10 Li Xiaofeng1,Lu Zhiping2,Li Yuping2(1.Interchange Center of Science and Technology, Taiyuan 030001,China; 2.Institute of Special Chemistry of TUT, Taiyuan 030024,China);The Present Situations and Prospects of Study of MOR in Application Areas[J];Taiyuan Science and Technology;2004-03
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 Tan Zhidou(Department of Chemistry and Environment Engineering,Hubei Institute for Nationalities,En Shi 445000,China);Benzyl Propionate Catalyzed by Phosphoungstic Acid Under Microwave Irradiation[J];Anhui Chemical Industry;2003-03
2 Zheng Jingying Liu Ronghua Ji Weihong Dai Qianhuan(Department of Chemistry and Evironmental Engineering);Preparation of Anthraquinone from Anthracene with Catalyst of Mixed Light Rare-Earth Ore Nitrates[J];Journal of Beijing Polytechnic University;1990-03
3 LI Ying CHEN XiaoChun SUN Wei LIU ShiWei HOU Wei (College of Chemical Engineering,Beijing University of Chemical Technology,Beijing 100029,China);Experimental study of the catalytic dehydration of ethanol to ethylene on a γ-Al_2O_3 catalyst[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2007-05
4 Huang Chao Guo Zhiwu Jin Haibo Yang Suohe(Department of Chemical Engineering,Beijing Institute of Petro-chemical Technology,Beijing 102617);Study on the Synthesis of Butyl Lactate Catalyzed by Modified Bentonite[J];Journal of Beijing Institute of Petro-Chemical Technology;2007-04
5 YU Shan-xin WEN Rui-ming LUO Xin-xiang (Department of Chemistry,Yiyang Teacher's College, Yiyang Hunan,413049);CATALYTIC SYNTHESIS OF 1,4-DIOXANE USING ETHANEDIOL AS RAW MATERIAL AND SODIUM BISULFATE AS CATALYST[J];Journal of Changde Teachers University;2001-02
6 DING Bin,XUE Lian-hai,MIAO Nai-fen(Department of Chemical Engineering,Jilin Institute of Chemical Technology,Jilin 132022,China);Preparation of dibutyl succinate using acid activated bentonite as catalyst[J];China Surfactant Detergent & Cosmetics;2006-05
7 Ma,Jian-Wei;Ye, Xing-kai and Wu, Yue (Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022);STUDY ON THE CATALYTIC PROPERTY OF HETEROPQLY COMPOUND:SYNTHESIS,CHARACTERIZATION AND CATALYTIC ACTION ON H_2O_2 DECOMPOSITION OF HETEROPOLY TUNGSTO-PHOSPHORIC COMPOUND SUBSTITUTED BY TRANSITION METAL ION[J];Chinese Journal of Catalysis;1991-06
8 WEN Langyou 1, SHEN Shikong 1, MIN Enze 2 (1 School of Chemical Engineering, University of Petroleum (Beijing), Beijing 102200, China; 2 Research Institute of Petrochemical Processing, SINOPEC, Beijing 100083, China);Physicochemical and Catalytic Properties of 12-Phosphotungstic Acid Supported on Different Silica[J];Chinese Journal of Catalysis;2000-06
9 HUANG Shiyu 1, DING Yunjie 1* , ZHANG Lianzhong 2, LI Xuemin 2, LIN Peizi 1, LUO Hongyuan 1 (1 Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, China; 2 Carbide Factory of Jilin Chemical Industrial Corporati;Investigation on Direct Oxidation of Ethylene to Acetic AcidⅠ. Catalytic Performance of Pd-Ru/HPA/SiO_2 Catalyst[J];Chinese Journal of Catalysis;2001-06
10 CAI Tiejun *, CHEN Yazhong, PENG Zhenshan, LONG Yunfei, JIANG Shaoliang, DENG Qian (Chemistry Department of Xiangtan Normal University, Xiangtan 411201, Hunan, China);Catalytic Performance of M-Na-P-Mo-V/SiO_2 Series Catalysts for Isobutylene Oxidation[J];Chinese Journal of Catalysis;2002-03
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 ZHANG Xia~(1,2),WU Feng-hua~1,HU Yi-min~1 (1.College of Chemistry and Materials Science,Anhui Normal University, Wuhu 241000,China;2.Department of Chemistry,Anqing Teacher's College,Anqing 246011,China);Preparation of Cyclohexene by Dehydration of Cyclohexanol on SO_4~(2-)-La_2O_3-TiO_2 Catalyst[J];Journal of Anhui Normal University(Natural Science);2006-01
2 YU Shan-xin1,WEN Rui-ming 2,YOU Pei-qing 3 (1.College of chemistry and chemical engineering,Hunan normal university,Hunan,Changsha,410081;2.Department of chemistry and environmentally engineering,Hunan city university,Hunan,Yiyang,413049;3.Department of science and technology,Hunan city university,Hunan,Yiyang,413000);Application of sodium bisulfate monohydrate in organic synthesis[J];Journal of Hunan University of Arts and Science(Science and Technology);2008-01
3 YU Shan-xin, GUAN Shi-bin, LIU Mei-yan(College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China);Preparation of Cyclohexene from Dehydration of Cyclohexanol Catalyzed by Solid Acid[J];Journal of Chenzhou Teachers College;2005-02
4 HUANG Zhu-liang, LI Hong-lei, HU Liu, CUI Xue(Department of Chemistry, Youjiang Medical College for Nationalities, Baise 53300, China);Synthesis of Cinnamonitrile Catalyzed by Nafion/SiO_2[J];Guangxi & Development of Chemical Industry;2003-03
5 HUANG Qing,GU Jingquan,NING Dan,YU Hongyuan,LIU Chunshan (Institute of Industrial Catalysis,East China University of Science & Technology,Shanghai 200237,China);Vapor phase synthesis of 2-octene via dehydration of 2-octanol[J];Industrial Catalysis;2007-03
6 WANG Lan-zhi1,YANG Li-jing2,ZHAO Xiao-hong3,HE Xuan1 (1.College of Chemistry and Material Science,Hebei Normal University,Hebei Shijiazhuang 050016,China;2.The Cadre College of Chinese Environmental Management,Hebei Qinhuangdao 066004,China;3.Qinhuangdao Branch,North China Coal Medical College,Hebei Qinhuangdao 066004,China);Synthesis of Cyclohexene under Green Chemistry Philosophy[J];Journal of Hebei Normal University(Natural Science Edition);2009-02
7 LI Ji-zhong (The Shanxi Province Key Laboratory of Chemical Reaction Engneering, Department of Chemistry and Chemical Engineering, Yanan University, Yanan 616000, China);The Synthesis of Cyclohexene Catalyzed by Sodium Hydrogen Sulfate[J];Chinese Journal of Synthetic Chemistry;2004-03
8 TANG Man-sheng,LIU Xing-ming,YUAN Xian-you,ZHANG min (Department of Chemistry and Bioengineering,Hunan University of Science and Engineering,Yongzhog 425100,China);Preparation of Cyclohexene from Cyclohexanol by Dehydration Using I_2/C as a Catalyst[J];Chinese Journal of Synthetic Chemistry;2009-03
9 YOU Pei-qing1,WEN Rui-ming1,YU Shan-xin2(1.Department of Chemistry and Environmental Engineering,Hunan City University,Yiyang,Hunan 413049,China;2.College of Chemistry and Chemical Engineering,Hunan Normal University,Changsha,Hunan 410081,China);Study on Synthesis of Cyclohexene[J];;2005-03
10 ZHANG Shou-cai,LIANG Yue,LI Pei-fang,LI Li-na(College of Chemistry,Jilin Normal University,Siping 136000,China);Synthesis of cyclohexene by Ti~(4+ )-cation exchange resin as catalysted[J];Chemical Engineer;2004-11
【Secondary Citations】
Chinese Journal Full-text Database 2 Hits
1 Yuan Xianyou, Yin Dulin, Li Qianhe, Fu Zaihui, Mao Liqiu (Institute of Fine Catalysis and Synthesis, Hunan Normal University, Changsha 410081);Studies on the Catalysis of Faujusite in Fine Organic Synthesis Ⅸ. Isomerization of α Pinene Catalyzed by Dealuminated USY[J];JOURNAL OF MOLECULAR CATALYSIS (CHINA);1996-06
2 Yuan Xianyou;Yin Dulin;Li Qianhe;Fu Zaihui(Institute of Fine Catalysis and Synthesis, Hunan Normal University, Changsha 410081);On the esterification of acetic acid with β-phenylethyl alcohol catalyzed by dealuminated USY[J];MODERN CHEMICAL INDUSTRY;1996-07
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved