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《Fine Chemicals》 2004-S1
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Preparation and Properties of Fluoroacrylate Copolymer

ZHOU Xiao-dong,GU Guo-hua,LI Wei-hua,FU Xun,HU Zheng-shui~*(Institute of Chemistry & Molecule Engineering,Qingdao University of Science and Technology,Qingdao 266042,Shandong,China)  
Self-made fluoroacrylate monomer was treated with other acrylate monomers to give fluoroacrylate solution copolymer(Ⅰ) and emulsion copolymer(Ⅱ),and their properties were compared with acrylate copolymer without fluorine(Ⅲ).Soaking in water for 96 h,the film of Ⅰ was intact,but that of Ⅲ was peeled.Soaking in water for 24 h,the water absorption of Ⅱ was 12.01%~13.65%,and that of Ⅲ was 24.87%.Soaking in acetone and 5% NaOH for 24 h,the films of Ⅰ and Ⅱ were intact,while that of Ⅲ was peeled,broken or solved.When w(fluoroacrylate monomer)=5%,Ⅰ was modified by KH-570 and its properties were tested as stated above.The film of modified Ⅰ was intact,and its hardness changed from HB to H.Average contact angle with water was 62.1°~68.4° for Ⅰ,53.9°~61.0° for Ⅱ,29.1°~30.5° for Ⅲ and 63.4°~67.3° for Ⅰ modified by KH-570.These results show that the water resistance,alkali resistance,solvent resistance,and self-cleaning properties of the fluoroacrylate copolymers are more excellent than those of the acrylate copolymer without fluorine,and the fluorine-containing monomer has good synergistic effect with KH-570.
【CateGory Index】: TQ630
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