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《Fine Chemicals》 2004-S1
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Preparation and Properties of Fluoroacrylate Copolymer

ZHOU Xiao-dong,GU Guo-hua,LI Wei-hua,FU Xun,HU Zheng-shui~*(Institute of Chemistry & Molecule Engineering,Qingdao University of Science and Technology,Qingdao 266042,Shandong,China)  
Self-made fluoroacrylate monomer was treated with other acrylate monomers to give fluoroacrylate solution copolymer(Ⅰ) and emulsion copolymer(Ⅱ),and their properties were compared with acrylate copolymer without fluorine(Ⅲ).Soaking in water for 96 h,the film of Ⅰ was intact,but that of Ⅲ was peeled.Soaking in water for 24 h,the water absorption of Ⅱ was 12.01%~13.65%,and that of Ⅲ was 24.87%.Soaking in acetone and 5% NaOH for 24 h,the films of Ⅰ and Ⅱ were intact,while that of Ⅲ was peeled,broken or solved.When w(fluoroacrylate monomer)=5%,Ⅰ was modified by KH-570 and its properties were tested as stated above.The film of modified Ⅰ was intact,and its hardness changed from HB to H.Average contact angle with water was 62.1°~68.4° for Ⅰ,53.9°~61.0° for Ⅱ,29.1°~30.5° for Ⅲ and 63.4°~67.3° for Ⅰ modified by KH-570.These results show that the water resistance,alkali resistance,solvent resistance,and self-cleaning properties of the fluoroacrylate copolymers are more excellent than those of the acrylate copolymer without fluorine,and the fluorine-containing monomer has good synergistic effect with KH-570.
【CateGory Index】: TQ630
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Chinese Journal Full-text Database 1 Hits
1 GAO Juan,ZHOU Yu-ming(College of Chemistry & Chemical Engineering,Southeast University,Nanjing 210096,China);Study on the preparation and surface properties of fluoroacrylate copolymer anti-adherent[J];Chemical Research and Application;2007-03
Chinese Journal Full-text Database 2 Hits
1 LI Wei hua,ZHOU Xiao dong,HU Zheng shui,LI Cang,GU Guo hua,WANG Feng ying,FU Xun (Institute of Chemistry and Molecular Engineering,Qingdao University of Science and Technology,Qingdao 266042,China);Preparation of Perfluoro Acrylate Monomer[J];Fine Chemicals;2002-11
2 Shen Yiding,Li Xiaorui (Northwest Institute of Light Industry,Xianyang,Postcode 712081);The Preparation and Application of N Hydroxyethyl Perfluorooctamide Acrylate Copolymers for Leather Soilproofing[J];FINE CHEMICALS;1997-05
Chinese Journal Full-text Database 10 Hits
1 WANG Jiang-jie,CHEN Jian-bing,WU Guang-hui & WANG Rui-xia(Department of Chemistry,Chizhou College,Chizhou 247000,China);Study on the Films of Aqueous Fluorine-Containing Polyurethane Prepared by Seed Emulsion Polymerization[J];Journal of Anqing Teachers College(Natural Science Edition);2006-02
2 CHEN Lan-ping(Shanghai Dacromet Surface Treatment Co.,Ltd.,Shanghai 200072,China);Synthesis and Structure Characterization of Waterborne Fluoropolymer Emulsion[J];Materials Protection;2008-01
3 JIANG Yuan LIU Yuqing (Nanjing Fiberglass Research and Design Institute,Nanjing 210012);Characteristics of Fluororesin Used in Polymer Optical Fiber[J];Materials Review;2005-01
4 SU Jielong WU Guozhong ZENG Hongyan (School of Chemical Engineering, Xiangtan University, Xiangtan 411105) (Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800);Preparation of fluorocarbon finishing agents by γ-ray induced emulsion polymerization[J];Journal of Radiation Research and Radiation Processing;2006-02
5 ZHAO Xing-shun, DING Xiao-bin, ZHANG Jun-hua,ZHENG Zhao-hui, PAN Yi, ZHU Zhu, PENG Yu-xing(Chengdu Institute of Organic Chemistry, Chinese Academyof Sciences, Chengdu 610041, China);THE KINETIC INVESTIGATION OF EMULSION COPOLYMERIZATION OF PERFLUOROALKYLETHYL METHACRYLATE WITH BUTYL METHACRYLATE[J];Polymeric Materials Science & Engineering;2004-06
6 LI Jun, CHEN Qing-min(Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093);RESEARCH PROGRESS IN FLUORINE-CONTAINING ACRYLATE POLYMER[J];Polymeric Materials Science & Engineering;2005-05
7 YANG Ting ting, WANG Shi min, XU Zu shun, CHENG Shi yuan\+* (School of Chemistry and Material Science, Hubei University, Wuhan 430062, China);Progress in Studies of Perfluoroacrylates Polymer Emulsions[J];Polymer Bulletin;2003-06
8 YANG Bao-ping~(1,2),CUI Jin-feng~1,ZHANG Ying-peng~1ZHOU Ying-ping~1,CHEN Jian-min~2 (1.College of Petrochemical Technology.,Lanzhou Univ.of Tech.,Lanzhou 730050,China;2.State Key Laboratory of Solid Lubrication,Lanzhou Institute of Chemical Physics,CAS,Lanzhou 730000,China);Development of epoxy-modified fluorocarbon nano-scale compound for marine coatings[J];;2005-05
9 Jiang Guozhong (Changzhou Lingda Chemicals Co.Ltd.,Changzhou Jiangsu 213177,China);Research and development on Fluoride-Carbon finishing agent[J];Synthetic Technology & Application;2008-04
10 Zhou Xiaodong, Sun Daoxing (Institute of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042);Synthesis and organosilicon modification of fluorocarbon resin[J];China Synthetic Resin and Plastics;2004-03
Chinese Journal Full-text Database 10 Hits
1 FU Ya-bo, CHEN Qiang, GE Yuan-jing (Dept. of Plasma Physics and Materials, Beijing Institute of Graphic Communication, Beijing 102600, China);The Characterizations of Low Surface Energy Film Polymerized in Continuous and Pulsed Plasmas[J];Journal of Beijing Institute of Technology;2005-S1
2 Fu Lianshe Zhang Hongjie Shao Hua Meng Qingguo Ni Jiazuan Key Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences Changchun 130022;Progress on Inorganic/Organic Hybrid Prepared by the Sol Gel Process[J];MATERIALS SCIENCE AND ENGINEERING;1999-01
4 Bai Xiue Chen Guoqiang(College of Material Engineering,Soochow University,Suzhou 215021);The Effect of Initiationless Graft Copolymerization on Silk Fibre Properties[J];Acta Sericologica Sinica;2002-04
5 YU Jian-Lei1 LIU Jin-Qiang1 LI Yong-Qiang1 WANG Ming-Liang1 GE Hua-Yun1 FAN Qin-Guo2(1The Key Laboratory of Advanced Textile Materials and Manufacturing Technology,Ministry of Education,Zhejiang Sci-Tech University,Hangzhou 310018,China;2Department of Textile Sciences,University of Massachusetts,Dartmouth MA02747,USA);Preparation Technology of Grafting HEMA on Silk and Performance Estimation of Weighted Silk[J];Science of Sericulture;2007-04
6 Du Wenqin , Di Jianfeng (Department of Textile, Wuyi University, Jiangmen, 529020);Technology of Producing Water - repellent Fabric for Architecture and Study on the Stability of Hydrophobic Solution[J];;2000-03
7 Hu Weiling Wu Lingling * Zhou Jing Li Jingxin Luo Jin Lin Zhonghua (State Key Lab. for Phys. Chem. of the Solid Surf., Dept. of Chem., Ins. of Phys. Chem., Xiamen Univ., Xiamen 361005);Direct Electrolysis of Seawater on Conducting Film for Microbial Anticorrosion 1. Simulation and Measurement Technique[J];ELECTROCHEMISTRY;1999-03
8 SUN Ping, SUN Yong-hong, WANG Yan-yun (Beijing Institute of Technology, Beijing 100081, China) (Dept. of Transportation Engineering, Dalian Railway Institute. Dalian 116028, China);A Study on Prevention and Elimination for Marine Fouling Organism[J];Journal of Dalian Railway Institute;2000-04
9 Gao xiaohui; Jiang shufen; Li jie; Wang hao(Central-south University of Technology 410083 Changsha;IE CHEMISTRY KINETIC QUANTITATIVE STUDY OF F-DOPED Bi-BASED SUPERCONDUCTING PHASE[J];CHINESE JOURNAL OF LOW TEMPERATURE PHYSICS;1994-04
10 Liu Jianhong;Yu Tongyin(Department of Macromolecular Science);Graft copolymerization of silk fibers(Ⅱ)──Grafting vinyl monomers onto silk fibers in absence of initiator[J];;1994-04
【Secondary References】
Chinese Journal Full-text Database 1 Hits
1 Yang Shifang, Zhu Yuanyuan, Xu Weimin, Chen Peizhi(College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062);Thermosetting Fluoroacrylic Resin Preparation[J];Chemical Production and Technology;2009-01
【Secondary Citations】
Chinese Journal Full-text Database 5 Hits
1 XU Long-gui, LIU Ya-li (Inst. of Chemistry and Chemical Engineering, Hunan Univ., Changsha 410082, China);Development of fluororesin coatings[J];Electroplating & Finishing;2001-04
2 Tian Jun;XuJinfen;Peng Guangming;ZhouZhaofu;XueQunji(Laboratory of Solid Lubrication, Lanzhou Institute of ChemicalPhysics,Chinese Academy of Sciences, Lanzhou 730000);Polymer Containing Fluorine and Its Potential Uses[J];JOURNAL OF FUNCTIONAL POLYMERS;1995-04
3 LU HENG-YAO GUO CAI-YUN WANG SHAN-DI CHEN QING-YUN~* (Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai);THE SYNTHESIS OF ACRYLATES OF FLUORINATED ALCOHOLS[J];Acta Chimica Sinica;1985-10
4 Lu Guohong,Chen Zhengguo,Cheng Shiyuan,Chen Yanjun (Facuty of Chemisty and Material Science, Hubei Unversity, Wuhan, 430062);SYNTHESIS AND APPLICATUON OF PERFLUOROALKYL ACRYLATE POLYMER[J];CHINESE JOURNAL OF COLLOID AND POLYNIER;2000-02
5 Shen Yiding,Li Xiaorui (Northwest Institute of Light Industry,Xianyang,Postcode 712081);The Preparation and Application of N Hydroxyethyl Perfluorooctamide Acrylate Copolymers for Leather Soilproofing[J];FINE CHEMICALS;1997-05
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