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《Journal of Mineralogy and Petrology》 2001-04
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PREPARATION OF A KAOLINITE- POLYACRYLONITRILE INTERCALATION COMPOUND

XIA Hua TONG Jian HOU Chang-e Institute of Material Science and Chemical Engineering,China University of Geoscience,Wuhan 430074  
The intercalation complex involving the layer silicate kaolinite and organic compound is studied through the application of infrared absorption spectroscopy and X-ray powder diffraction.The acrylonitrile can be intercalated between the layers of kaolinite by displacing intercalated ammonium acetate from kaolinite/ammonium acetate complex.The XRD pattern showed that the layer interval of kaolinite increased.The IR spectra provide evidence that the inner-surface hydroxyl groups of kaolinite are hydrogen bonded to intercalated DMSO molecules.When there is a initiator,the acrylonitrile monomer can be polymerized between the layers.
【CateGory Index】: TB33
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