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《Ion Exchange and Adsorption》 2003-01
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A THERMODYNAMIC STUDY ON ADSORPTION OF PHENOLS ONTO D301 RESIN

HUANG Jiangou1 XU Mancai1,2 LI Haitao1 SHI Zuoqing2 SHI Rongfu2 HE Binglin2 1 College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081 2 The State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Institute of Polymer Chemistry, Nankai University, Tianjin 300071  
Adsorption isotherms of phenol onto D301 resin from cyclohexane solution were measured. Isosteric adsorption enthalpy, adsorption free energy and adsorption entropy were calculated according to the relationship of thermodynamic function. Isosteric adsorption enthalpy was between 30kJ/mol and 35kJ/mol, which reveals a hydrogen-bonding adsorption mechanism. Difference of adsorption property of phenol onto D301 resin from aqueous solution and cyclohexane solution, and that of phenol and o-nitrophenol from cyclohexane solution were studied, and the results show the hydrogen-bonding based adsorption for phenols from non-aqueous solution furthermore.
【Fund】: 国家自然科学基金资助 (29974015)
【CateGory Index】: O647.3;O
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