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《Ion Exchange and Adsorption》 2006-04
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SYNTHESIS AND PROPERTIES OF MOLECULARLY IMPRINTED SPHERIC Β-CYCLODEXTRIN POLYMERS

WU Hao LI Haitao XU Mancai Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research of National Education Ministry,Chemistry and Chemical Engineering,Hunan Normal University,Changsha,410081,China  
Molecularly imprinted β-cyclodextrin polymers(MI-CDPs) were prepared using theophylline as a template,β-cyclodextrin as a functional monomer and toluene-2,4-diisocyanate as a crosslinker.Then,MI-CDPs powder was embedded with crosslinked polyvinyl alcohol by inverse suspension polymerization approach,and spheric MI-CDPs absorbent was prepared.The synthesis conditions of spheric MI-CDPs were optimized and their adsorption properties were investigated with static adsorption method.The results suggest that spheric MI-CDPs possess prominent molecule recognition performance for theophylline in aqueous solution and had maximum adsorption for theophylline at pH=9.0.
【Fund】: 湖南省教育厅科研项目
【CateGory Index】: O631.3
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