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《Ion Exchange and Adsorption》 2008-06
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SYNTHESIS AND CHARACTERIZATION OF MOLECULARLY IMPRINTED NOVEL FUNCTIONAL ABSORBENT OF ENDOCRINE-DISRUPTING COMPOUNDS ESTRONE

XU Zhixiang1,2 WANG Shuo1 FANG Guozhen1 1. Key Laboratory of Food Nutrition and Safety, Ministry of Education of China, Faculty of Food Engineering and Biotechnology, Tianjin University of Science and Technology, Tianjin 300457, China 2. College of Food Science and Engineering, Shandong Agricultural University, Tai'an 271018, China  
In this thesis, a highly selective imprinted polymer was synthesized by the bulk polymerization method, using estrone as template and acrylamide as functional monomers. The imprinted polymer was evaluated by the kinetic and selective adsorption experiments. The results showed that the imprinted functional sorbent exhibited good recognition and selective ability, offered a faster kinetics for the adsorption of estrone than the non-imprinted sorbent. Results also indicated that polymerizing conditions had important effect on the selectivity of the imprinted polymer, and the 1:3:6 ratio of template to functional monomer and cross-linker was suitable for preparation an imprinted polymer having high adsorption capacity and selective ability.
【Key Words】： Molecular imprinting Estrone Functional material Kinetic adsorption Selective recognition.
【Fund】： 国家自然科学基金(30571532)
【CateGory Index】： R318.08
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