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《Agrochemicals》 2008-02
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Function of Anionic/Nonionic Complex Surfactant in Forming Pesticide Microemulsion

LI Li-fang1,2a, WANG Kai-yun2b, SONG Dong-sheng1, SUN Xu-bing1, WANG Feng-zhi1 (1.Shandong Huayang Pesticide Chemical Industry Group Co., Ltd., Taian 271411, Shandong, China; 2.Shandong Agriculture University a.College of Chemistry and Material Science; b.College of Plant Protection, Taian 271018, Shandong, China)  
Pseudo-ternary phase diagram and electrical conductivity of complex surfactant(calcium dodecylbenzene sulfonate + ethoxylated tristyrylphenol)/chlorpyrifos solution/water system was investigated. It was found that emulsifying effect was increased comparing complex surfactant with calcium dodecylbenzene sulfonate and ethoxylated tristyrylphenol, respectively. The system could be infinite diluted by water at their optimum ratio, and the micro-structure was varitied from W/O to liquid crystal, bicontinuous structure and O/W. Compared to the pure ethoxylated tristyrylphenol, the γcmc was decreased distinctly with improving content of calcium dodecylbenzene sulfonate in the complex surfactant.
【Fund】: 山东省博士后科研项目专项经费资助(200603112)
【CateGory Index】: TQ450.1
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