Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Chinese Journal of Biotechnology》 2003-01
Add to Favorite Get Latest Update

Studies of Enzymatic Synthesis of Biodiesel

DENG Li TAN Tian Wei * WANG Fang (Beijing Bioprocess Key Lab, Beijing University of Chemical Technology, Department of Bioengineering,Beijing\ 100029,China)  
Biodiesel, an alternative diesel fuel, fatty acid alkyl ester, is made from renewable biological sources such as vegetable oils and animal fats. Two processes for biodiesel synthesis, enzymatic lipase catalytic esterification from fatty acid and transesterification from oils and fats, was investigated. The effects of various lipases, enzyme amount and purity, solvent, water absorbent, inhibition of short chains alcohol, specificity of substrate, molar ratio of substrate on esterification were studied in detail. The esterification degree with the optimal parameter and process can reach up to 92%. The purity of biodiesel obtained by separation and purification is up to 98%, and the half-life of the immobilized lipase for the esterification process can be up to 360hr, Moreover, the preliminary studies of the transesterification including the amount of methanol and mode of adding methanol into reaction system were made. The transesterification degree with adding methanol stepwise can reach 83%.
【Fund】: 国家自然科学基金资助 (No .2 0 1760 0 2 ) ;; 十五攻关“酯化用脂肪酶及应用”项目资助~~
【CateGory Index】: TE665
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 10 Hits
1 WEI Wei et al(School of Chemical Engineering,Zhengzhou University,Zhengzhou,Henan 450001);Progress on the Biomass Fuels Transformed by Cellulose[J];Journal of Anhui Agricultural Sciences;2009-18
2 WANG Yan et al(Shaanxi Province Institute of Microbiology,Xi'an,Shaanxi 710043);Study on Screening and Culture Condition of Strain Producing Chinese Prickly Ash Seed Oil Favorite Lipase[J];Journal of Anhui Agricultural Sciences;2011-21
3 WANG Yu1 SUN HaiYang1 WANG Fang2 TAN TianWei2(1.College of Life Science and Technology;2.Beijing Key Laboratory of Bioprocess Beijing University of Chemical Technology,Beijing 100029,China);Performance of biodiesel made from ditch oil[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2007-S2
4 LI JunKui WANG Fang TAN TianWei DENG Li(Beijing Key Laboratory of Bioprocess,Beijing University of Chemical Technology,Beijing 100029,China);Synthesis of biodiesel from crude jatropha oil using immobilized lipase[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2010-02
5 Zhang Zhihong(Department of Chemical Engineering , Beijing Institute of Petrochemical Technology , Beijing 102617);Progress of Biosynthesis through Lipase-Catalyzed Reaction[J];Journal of Beijing Institufe of Petrochemical Technology;2004-04
6 XI Li-min~(1,2),REN Qi-long~2(1.Taizhou Technical College,Departement of Biological and Chemical Engineering,Taizhou 318000,China;2.Zhejiang University,National Laboratory of Secondary Resources Chemical Engineering,Hangzhou 310027,China);Preparation of fatty acid methyl ester catalyzed by solid acid from by-products of plam oil[J];China Surfactant Detergent & Cosmetics;2006-06
7 LUO Xi,WANG Ming-yong(Guiyang No.1 High School,Guiyang,Guizhou 550081,China);Study of Optimized Production Technology for Biodiesel Produced from Chinese Tallow Sulfated Oil[J];Guizhou Agricultural Sciences;2010-10
8 DAI Da-Zhang*,XIA Li-Ming(Institute of Bioengineering,College of Material Science and Chemical Engineering,Hangzhou 310027,China);Enzymatic Resolution of (R,S)-2-Octanol by Ultrastable-Y Molecular Sieve Immobilized-lipase in Microaqueous Media[J];Chemical Journal of Chinese Universities;2007-12
9 ZHAO Tan,ZHANG Quan-guo,SUN Sheng-bo(Daqing Research Center of Chemical Engineering,PetroChina Research Institute of Petroleum and Petrochemicals, Daqing 163714,China);Research Advances in Biodiesel[J];Technology & Development of Chemical Industry;2011-04
10 ZHAN Xian,LIU Shao-Gang (State Key Laboratory of Pollution Control and Resource Reuse,College of Environmental Science and Engineering,Tongji University,Shanghai 200092,China);Research Progress of the Manufacture Technology of Biodiesel Fuel[J];Journal of Guangxi University for Nationalities(Natural Science Edition);2008-02
China Proceedings of conference Full-text Database 2 Hits
1 WANG Xue-wei~(1,2), CHANG Jie~1, LV Peng-mei~1,TAN Tian-wei~2, ,ZHANG Xi-tong~(1,2)(1. Guangzhou Institute of Energy, CAS, Guangzhou 510640, China 2. Department of Biochemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China);Study On Biodiesel Production[A];[C];2005
2 YING Ming and CHEN Guanyi,(Section of Bioenergy and Wastes Treatment, Faculty of Environmental Science and Engineering/State Key Lab for Internal Combustion Engine, Tianjin University, 300072, Tianjin China);A Study on Whole-Cell Biocatalyst for the Production of Bio-diesel[A];[C];2005
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Zhang Zhihong(Department of Chemical Engineering , Beijing Institute of Petrochemical Technology , Beijing 102617);Progress of Biosynthesis through Lipase-Catalyzed Reaction[J];Journal of Beijing Institufe of Petrochemical Technology;2004-04
2 WANG Yingxiong,WANG Guofu,HOU Xianglin,DU Junmin,QIAO Xingang,QIN Zhangfeng,WANG Jianguo(Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan030001,China);Lipase catalyzed hydrolysis of linseed oil in a solvent-free medium[J];China Surfactant Detergent & Cosmetics;2003-04
3 XI Li-min~(1,2),REN Qi-long~2(1.Taizhou Technical College,Departement of Biological and Chemical Engineering,Taizhou 318000,China;2.Zhejiang University,National Laboratory of Secondary Resources Chemical Engineering,Hangzhou 310027,China);Preparation of fatty acid methyl ester catalyzed by solid acid from by-products of plam oil[J];China Surfactant Detergent & Cosmetics;2006-06
4 HE Qin, XU Yan, TENG Yun, WANG Dong(Key Laboratory of Industrial Biotechnology of the Ministry of Education, Jiangnan University, Wuxi 214122, Jiangsu, China);Biodiesel Production Catalyzed by Whole-Cell Lipase from Rhizopus chinensis[J];Chinese Journal of Catalysis;2008-01
5 Zhao Guixing (Harbin Business University Starbin 150076;Soybean Research Institute, Heilongjiang Academy of Agricultural Sciences, Harbin 150086);STUDY ON SOYBEAN BIODIESEL PRODUCTION-GREEN LIQUID FUEL[J];Soybean Science;2005-03
6 WANG Xin-lei,SUN Yu-mei,WANG Yue,CAO FangSchool of Biological & Food Engineering,Dalian Polytechnic University,Dalian 116034,China;Effects of adsorbing glycerol with silica gel on enzymatic transesterification of soybean oil[J];Journal of Dalian Polytechnic University;2009-05
7 Zhang Huaiyuan,Song Yuanda(Department of Biochemistry,School of Biological Science and Technology,Central South University,Changsha 410078,China);Application of transesterification for the production of biodiesel[J];Engineering Sciences;2010-01
8 Zhang Jun(Daqing Lianyi Group,Daqing 163852,China);Research Advances in Manufacture Technologies of Biodiesel[J];Guangdong Chemical Industry;2012-04
9 CHEN Zheng-zhong (Green New Energy Co.,Ltd.,Shanghai 200335,China);Study on Production Process of Biodiesel from Olive Oil[J];Technology & Development of Chemical Industry;2009-04
10 ZHAO Tan,ZHANG Quan-guo,SUN Sheng-bo(Daqing Research Center of Chemical Engineering,PetroChina Research Institute of Petroleum and Petrochemicals, Daqing 163714,China);Research Advances in Biodiesel[J];Technology & Development of Chemical Industry;2011-04
China Proceedings of conference Full-text Database 2 Hits
1 Li Liping,Chen Guanyi,Huang Yeqian (School of Environmental Science and Technology/State Key Laboratory of Engines,Tianjin University,Tianjin 300072,China);Biodiesel production in a magnetically stabilized fluidized bed reactor by whole-cell bio-catalyst[A];Chinese Society of Agricultural Engineering[C];2011
2 NIE Kaili TAN Tianwei WANG Fang(Department of Biochemical Engineering, College of Life and Science Technology,Beijing University of Chemical Technology, Beijing 100029, People's Republic of China);SYNTHESIS OF BIODIESEL USING IMMOBILIZED LIPASE[A];[C];2005
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 XUE Yong,YU Long-jiang, ZHU Men, JI Jai-yong(School of Life Science & Technology,Huazhong University of Science & Technology,Wuhan 430074,China);Study on the utilization of plant oil to produce biodiesel as new degradable energy[J];Shandong Agricultural Sciences;2004-05
2 BAO Jia-lan, LI Neng-shu (School of Life Science of Anhui University, Hefei 230039,China);Studies on Ferment Condition of Lipase from Fungi[J];Journal of Anhui University(Natural Sciences);2001-01
3 LU Sa-yin~1, HU Lei~2 (1.Center of Modern Experiment Technology,Anhui University, Hefei230039,China; 2.Xiuning Brewhouse of Anhui Province, Xiuning245400,China);Studies on alkaline lipase producing conditions by bacillus coagulans[J];Journal of Anhui University(Natural Sciences);2004-01
4 DAI Quan (Anhui National Technology and Engineering Centre of Pesticide Formulation,Hefei 230041,China);Domestic Present Situation of Pesticide Formulation Processing[J];Anhui Chemical Industry;2008-02
5 SU Min-guang1,YU Shao-ming1,WU Ke2,YU Zhi-min2,YANG Yan-hong1(1.School of Chemical Engineering,Hefei University of Technology,Hefei 230009,China;2.The Engineering Technology Research Center for Municipal Solid Waste and Resource Application of Anhui province,Hefei University,Hefei 230022,China);Study on the Conditions of Swill Oil Produced Biodiesel by Enzymatic[J];Anhui Chemical Industry;2009-06
6 WANG Yan et al(Kunming Institute of Botany,Chinese Academy of Sciences,Kunming,Yunnan 650204);Utilization of Jatropha Cuscas L.,an "Energy Plant" for Biodiesel[J];Journal of Anhui Agricultural Sciences;2007-02
7 HOU Xin-cun et al(Department of Horticulture,Tianjin Agricultural College,Tianjin 300384);Research Progress in Woody Energy Plant Pistacia chinensis[J];Journal of Anhui Agricultural Sciences;2007-12
8 FANG Ying-ming et al (Xuchang Vocational and Technical College, Xuchang, Henan 461000);Study on Development Status of Biodiesel[J];Journal of Anhui Agricultural Sciences;2007-26
9 MENG Chun-xiao et al(College of Life Science,Shandong University of Technology,Zibo,Shandong 255049);Study on Developing Biomass Energy by Microalgae[J];Journal of Anhui Agricultural Sciences;2007-31
10 LIU Hong-bo et al(College of Science,Northwestern A&F University,Yangling,Shaanxi 712100);Comparison Among Several Methods of Experimental Design[J];Journal of Anhui Agricultural Sciences;2007-36
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 HE Hong-bo,YAO Ri-sheng,JIANG Lai-en(School of Chemical Engineering,Hefei University of Technology,Hefei 230009,China);Research Progress of Biodiesel Preparation[J];Anhui Chemical Industry;2008-06
2 WANG Po,WANG Xiang-yang(Anhui Design Institute of Chemical Industry,Hefei 230009,China);Preparation of Biodiesel from Waste Cooking Oil and Ethanol[J];Anhui Chemical Industry;2011-02
3 Zhang Shimin,Zha Guo-jun,Zhang Wu-di,Yin Fang(Provincial Key Laboratory of Rural Energy Engineering,Yunnan Normal University,Kunming 650092,PRC);One kind of green environmental protection energy source——Biodiesel[J];Anhui Agricultural Science Bulletin;2007-18
4 LI Xia(Institute of Food Crop,Jiangsu Academy of Agricultural Sciences,Jiangsu High Quality Rice Research and Development center,Nanjing,Jiangsu 210014);Research on Bio-diesel and its Developing Potential in Jiangsu Province[J];Journal of Anhui Agricultural Sciences;2008-03
5 SONG Hua-min et al(Key Laboratory of Renewable Energy,Ministry of Agriculture of the People's Republic of China,College of Mechanical and Electrical Engineering,Henan Agricultural University,Zhengzhou,Henan 450002);Research Progress on the Preparation of Biodiesel Production by Solid Base Catalyst[J];Journal of Anhui Agricultural Sciences;2008-05
6 GAO Li-fei et al (College of Food Engineering and Biotechnology,Tianjin University of Science and Technology,Tianjin Key Laboratory of Food Nutrition and Safety,Tianjin 300457);Primary Study on Producing Biodiesel with Castor Oil by Enzymatic Catalysis[J];Journal of Anhui Agricultural Sciences;2008-16
7 XU Gui-zhuan et al (Mechanical and Electrical Engineering College of Henan Agricultural University,Zhengzhou,Henan 450002);Study on Analysis of Fatty Acid Methyl Ester Content in Biodiesel by GC[J];Journal of Anhui Agricultural Sciences;2008-28
8 LIU Xing-Huo et al(Department of Chemical Engineering,Jiangsu Polytechnic University,Changzhou,Jiangsu 213164);Study on Esterification of Waste Oils Catalyzed by Sodium Bisulfate[J];Journal of Anhui Agricultural Sciences;2008-29
9 ZHANG Yu-xing et al(College of Agronomy,Hainan University,Danzhou,Hainan 571737);Prokaryotic Expression of Pseudomonas aeruginosa Lipase Gene[J];Journal of Anhui Agricultural Sciences;2008-35
10 JIANG Meng et al(College of Chemistry and Chemical Engineering,Jiangsu Polytechnic University,Changzhou,Jiangsu 213164);Research and Discussion on the Biodiesel[J];Journal of Anhui Agricultural Sciences;2008-35
China Proceedings of conference Full-text Database 7 Hits
1 Jianhua FANG,Boshui CHEN,Jiu WANG,Jiang WU Dept.of Military Oil Application and Administration Engineering,Logistical Engineering University,Chongqing,China;Study on Bio-Diesel Preparation from Scraped Creatural and Vegetable Oil by SO_4~(2-)/Al_2O_3-ZrO_2 Solid Acid Catalyzing[A];[C];2011
2 LIU Wei-Wei~(1,3)MA Huan~(2,3)WANG Ji-xian~1 XIA Ping~1 ZHANG Wu-Di~3 LIU Shi-Qing~3 1.Technology School of Anhui Agricultural University Hefei 230036 P.R.China 2.Key Laboratory of Ion Beam Bioengineering Institute of Plasma Physics Chinese Academy of Sciences Hefei 230031 PR China 3.Provincial Key Laboratory of Rural Energy Engineering Yannan Normal University Kunming 650092;A study about preparation of biodiesel through transesterification reaction catalyzed by Barium hydroxide[A];[C];2007
3 Ren Qinggong Yah Jie Qiu Taiqiu~* (College of Light Industry and Food Sciences,South China University of Technology,Guangzhou 510641,China);Advances in Biodiesel production by means of ultrasonically enhanced transesterification[A];[C];2007
4 Wang Yong-neng Ma Jian-zhong Hu Jing (College of Resource and Environment,Shannxi University of Science & Technology,Shaanxi,Xi'an 710021);Present situation and prospect of bioenergy for car[A];[C];2007
5 Tang Bing Guo Donghui Li Congfa College of Science and Engineering,South China University of Tropical Agriculture,Danzhou,571737;Research Progress of Bio-diesel Preparation Technology from Vegetable Oils[A];[C];2005
6 Han Lijuan~1,~*Li Lin~(1,2),Liu Guoqin~(1,2) (1.College of Grain Oil and Food Science,He'nan University of Technology,Zhengzhou,He'nan 450052,China; 2.College of Light Industry and Food Science,South China University of Technology,Guangzhou,Guangdong 510640,China);Study on Influences of Improving the Conversion Degree of Fatty Acid Methyl Ester by Using Chemical and Ultrasonic Methods in the NaOCH_3 Catalyzed System[A];Chinese Society of Agricultural Engineering[C];2009
7 WANG Xue-wei~(1,2), CHANG Jie~1, LV Peng-mei~1,TAN Tian-wei~2, ,ZHANG Xi-tong~(1,2)(1. Guangzhou Institute of Energy, CAS, Guangzhou 510640, China 2. Department of Biochemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China);Study On Biodiesel Production[A];[C];2005
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved