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The Investigation on Preparation Technology of Polydichlorophosphazene

Zhang Wenlong1,3 Song Guixia1,3 Dai Yajie1,3 Wang Xuan2,3(1.College of Material Science & Engineering,Harbin University of Science and Technology,Harbin,150040;2.College of Electrical & Electronic Engineering,Harbin University of Science and Technology,Harbin,150040;3.Key Laboratory of Engineering Dielectrics and Its Application,Ministry of Education,Harbin,150080)  
Linear polydichlorophosphazene was straightly ring-opening polymerized at high temperature by hexachlorocyclotniphosphazene.By lots of repeated experiments,the most important factors of affecting the experimental result were discussed,the optimum synthesis technique was obtained,i.e.,reaction temperature 250 ℃,reaction time 10 h,the conditions of purification is firstly to dissolve raw polychlorophosphazene in benzene,than extract it from solution by n-heptane,the best yield is 64%,and the structure of the product was characterized by FT-IR.
【Fund】: 国家自然科学基金(50977019);; 黑龙江省自然科学基金资助项目(E200826)
【CateGory Index】: TQ316.3
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