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《Chinese Journal of Chromatography》 2006-01
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Analysis of Phthalates in Plastic Food-Packaging Bags by Thin Layer Chromatography

CHEN Hui,WANG Yuan,ZHU Ruohua(Department of Chemistry,Capital Normal University,Beijing 100037,China)  
The method for simultaneous determination of four phthalates,namely dimethyl phthalate(DMP),diethyl phthalate(DEP),di-n-butyl phthalate(DBP) and di (2-ethylhexyl) phthalate(DEHP) in plastic food-packaging bags by thin layer chromatography(TLC) was(developed).The plastic food-packaging bags were extracted with ethanol by ultrasonication,then the mixture was filtrated through membrane(0.45 μm).The mixture of ethyl acetate-(anhydrous)(ether-isooctane)(1∶4∶15,v/v) was used as developing agent on the TLC silica gel plate for development.The filtered liquid was spotted on the TLC plate dealt by acetone,and detected with scanning wavelength of 275 nm and reference wavelength of 340 nm.The qualitative(analysis) of the phthalates was performed using the R_f values of the chromatogram.The quantitative analysis was performed with external standard method.Good linearities were(obtained) for DMP,DEP,DBP and DEHP.The detection limits were 2.1 ng for DMP,2.4 ng for DEP,3.4 ng for DBP and 4.0 ng for DEHP.The relative standard deviations(RSDs) of the four phthalates were 2.8%-3.5%.The recoveries of the four phthalate standards in real sample were 78.58%-111.04%.The method presented has the advantages of high precision,high(sensitivity),small sample size,and simple pretreatment.The method was used to detect the four phthalates in the food-packaging bags.The contents in real samples were close to the(results) by gas chromatography.
【CateGory Index】: TS206
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【References】
Chinese Journal Full-text Database 4 Hits
1 YU Xiaonan LI Shuguang LI Xin ZHANG Jing Preclinical Medical College,Tongji University,Shanghai 200092,China;Investigation of phthalic acid ester dissolution and microparticle shedding and filtering off the disposable infusion apparatuses[J];Shanghai Medical Journal;2008-03
2 SHEN Haoyu,YING Liyan,CAO Yunfeng,PAN Gang,ZHOU Lu(Analysis and Testing Center,Ningbo Institute of Technology,Zhejiang University,Ningbo 315100,China);Simultaneous Determination of Phthalates and Parabens in Cosmetic Products by Gas Chromatography/Mass Spec-trometry Coupled with Solid Phase Extraction[J];Chinese Journal of Chromatography;2007-02
3 LIN Zhuguang1, SUN Ruonan1, ZHANG Lili1, ZOU Ximei1, CHEN Meiyu1, TU Fengzhang1,2, MA Yu1, JIANG Wenjing1 (1.Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, The Key Laboratory of Analytical Sciences of the Ministry of Education, Xiamen 361005, China; 2.Department of Chemistry and Material Engineering, Longyan College, Longyan 364000, China);Simultaneous determination of 14 phthalate ester residues in animal innards by gas chromatography-mass spectrometry with electron impact ionization[J];Chinese Journal of Chromatography;2008-03
4 LUO Caihong,GUO Zhishun,SUN Jing(Chongqing Environmental Monitoring Center,Chongqing 401147,China);Determination of phthalate esters in sediment by accelerated solvent extraction and gas chromatography-triple quadrupole mass spectrometry[J];Chinese Journal of Chromatography;2010-05
【Citations】
Chinese Journal Full-text Database 2 Hits
1 WANG Hai-yan,JIANG Zhan-peng,YU Gang,ZHANG Peng-yi,RAO Min-hua (Department of Environmental Science and Engineering, Tsinghua University, Beijing 100084, China);Study of Photoelectrocatalytic Oxidation of Benzoic Acid[J];Environmental Science;2004-01
2 Lin Xingtao, Wang Xiaoyi, Ren Ren. College of Environmental and Energy Engineering , Beijing Polytechnic University, Beijing 100022;Environmental endocrine disruptors——a study of phthalate esters[J];Environmental Pollution & Control;2003-05
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 TONG Bao-feng 1,2, LIU Ling-hua2, LIU Xiao-ru2, GAO Ji-jun2, ZHOU Huai-dong2, ZHU Duan-wei1(1 College of Resources and Environment, Huazhong Agricultural University, Wuhan 430070, China;2 Department of Water Environment Research, China Institute of Water Resources and Hydropower Research, Beijing 100038, China);Determination of phthalate and adipate esters in the source water by solid-phase extraction and gas chromatography-mass detector[J];Journal of Safety and Environment;2006-02
2 Sun Wenxian,Yang Haizhen,Wang Shaoping(School of Environmental Science and Engineering,Tongji University,Shanghai 200092,China);A Review of Degradation of Phthalate Esters[J];Environmental Science and Management;2008-03
3 CHEN Hui,WANG Yuan~* and ZHU Ruo-hua(Department of Chemistry,Capital Normal University,Beijing 100037);Analysis of phthalates in food-packaging bags by two kinds of chromatography[J];Chinese Journal of Analysis Laboratory;2006-04
4 QI Wen-wei,ZHU Pei-yu,WU Wei(Wuxi Environmental Monitoring Center,Wuxi Jiangsu 214023,China);Determination of Phthalate Esters in Water by Using Liquid-liquid Extraction/gas Chromatography[J];Arid Environmental Monitoring;2006-04
5 ZHANG Qing-fang,SUN Yuan-han,ZHOU Zhi-fang(College of Petrochemical Technology,Lanzhou Univ.of Tech.,Lanzhou 730050,China);Experimental investigation of influence of electrolyte on processing efficiency of photoelectrical coupling[J];Journal of Lanzhou University of Technology;2006-03
6 WANG Lei1,ZHANG Rui1,CHENG Ai-hua1,2,SHI Xin-bin1,ZHANG Li1,WANG Zhi-ying1(1.School of Environmental and Municipal Engineering,Xi'an University of Architecture and Technology,Xi'an 710055,China;2.Department of Environmental and Geological Engineering,Xi'an University of Science and Technology,Xi'an 710054,China);Determination of Phthalate Esters in Water by Solid-phase Extraction and GC-MS[J];China Water & Wastewater;2007-14
7 Chen Peiyi,Li Yanxu,Sun Yinghuang,Li Lijuan(Faculty of Environmental Science and Engineering,Guangdong University of Technology,Guangzhou 510090,China);Progress in the research on wastewater treatment by photoelectrocatalytic technology[J];Industrial Water Treatment;2005-12
8 ZHENG Wen-zhi, QIN Shi-jian, CHEN Yin (Department of Chemistry & Chemical Engineering, Guangzhou University, Guangzhou 51006, China);Research Progress of Environmental Hormone Phathalic Acid Esters[J];Guangzhou Chemical Industry;2006-05
9 Li W eizhong He Yuxin Huang Xiaoping Sheng Guoying;Investigation of Semivolatile and Nonvolatile Organic Compounds in the Drinking Water Sources and Watercourse Water of a City in Pearl River Delta[J];Guangzhou Environmental Sciences;2005-02
10 ZHANG Sheng-han,BIAN Na,HAN Li-yan;Research and application of electrochemical water treatment technology[J];Electric Power Environmental Protection;2009-05
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 ZENG Ming~1,LU Zhe~2,XIE Shu-yan~2(1.School of Life and Environment,Central Unviersity for Nationalities,Beijing 100081,China;2.School of Environment and Resource,Renmin Unviersity of China,Beijing 100872,China);Pollution characteristics and resources of phthalic esters in atmosphere in summer[J];Journal of Anhui University(Natural Sciences);2006-04
2 GAO Feng,YU Hong shan,JIN Feng xie (Dept. of Food Sic. and Biotechnol., Dalian Inst. of Light Ind., Dalian 116034,China);Application of column chromatography to ginseng saponins separation[J];Journal of Dalian Institute of Light Inoustry;2000-04
3 GUO Gen-he, PAN Wei, SU De-sen, LAO Qiu-hua, HE Zhi-gang, CHEN Han-zhen ( Central Laboratory, Fujian Academy of Agricultural Sciences, Fuzhou, Fujian 350003, China; Institute of Pomology, Fujian Academy of Agricultural Sciences, Fuzhou, Fujian 350013, China);Determination of some organic acids in the fruits of loquat by RP -HPLC[J];Fujian Journal of Agricultural Sciences;2005-03
4 YU Shi-dan(Fu Jian Province Environmental Monitoring Centre,Fuzhou 350003,China);Determination of Polycyclic Aromatic Hydrocarbons,PCBs,and Phthalats by SPE Disk Extraction-GC/MS with Selected Ion Monitoring Mode[J];Analysis and Testing Technology and Instruments;2006-03
5 Wang Xikui, Guo Weilin, Xu Guangtong, Wang Xiaomei, Meng Pingrui (Department of Applied Chemistry, Shandong Institute of Building Materials, Jinan 250022);Separation and Determination of Trace Phthalate Esters in Environmental Samples[J];Chinese Journal of Analytieal Chemistry;1995-12
6 Song Fengrui, Liu Shuying (National Analytical Research Center of Electrochemistry and Spectroscopy, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022);Analysis of Sedative Drugs in Human Urine by Electron Impact/Tandem Mass Spectrometry[J];Chinese Journal of Analytieal Chemistry;1998-11
7 Liu Li 1, Mou Jun *2 , Yang Zuojun 1, Li Ying 1, Zhang Weiya 1 1(Shenzhen Entry Exit Inspection and Quarantine Bureau, Shenzhen 518045) 2(Jilin Entry Exit Inspection and Quarantine Bureau, Changchun 130062);Analysis of Plasticizer in Polyvinyl Chloride Plastics by Gas Chromatography/Mass Spectrometry[J];Chinese Journal of Analytieal Chemistry;2002-03
8 Ma Lingling, Lao Wenjian, Wang Xuetong, Liu Hui, Chu Shaogang, Xu Xiaobai  (Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085);Analytical Method for Trace Semi-Volatile Organic Compounds in the Soil of Beijing Suburbs[J];Chinese Journal of Analytical Chemistry;2003-09
9 Zhao Rusong, Xu Xiaobai *, Liu Xiufen (Reseach Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085);The Advancement and Application of Liquid-Phase Microextraction[J];Chinese Journal of Analytical Chemistry;2004-09
10 Jin Xiaoying, Yuan Dongxing* (State Key Laboratory of Marine Environmental Science, Environmental Science Research Center, Xiamen University, Xiamen 361005);Determination of Organophosphorous Pesticides in Water Samples Using Dynamic Liquid-phase Microextraction and Gas Chromatography[J];Chinese Journal of Analytical Chemistry;2005-03
【Secondary References】
Chinese Journal Full-text Database 9 Hits
1 FU Ruo-nong (Chemistry Department, Beijing Institute of technology, Beijing 100081);Advances and trend of capillary GC chromatographic columns in recent two years[J];Chinese Journal of Analysis Laboratory;2009-03
2 XIONG Ye-dan,WAN Shu-qing(College of Resources and Environment,South China Agricultural University,Guangdong Guangzhou 510642,China);The Species and the Detriment of Environmental Hormones in the Aquatic System[J];Guangzhou Chemical Industry;2010-01
3 ZHOU Xiang-juan,ZHAO Yu-qi,LI Wei,XIE Jing-jing(Haidian District Institute of Products Quality Supervision and Inspection,Beijing 100094,China);Determination of sixteen kinds of phthalic ester in cosmetics by gas chromatography-mass spectrometry[J];China Surfactant Detergent & Cosmetics;2010-02
4 LAI Ying,WANG Hong-hui,HUANG Chang-chun,DONG Qing-mu,HUANG Zong-ping,CAI Yan-ping(Xiamen Entry-Exit Inspection and Quarantine Bureau,Xiamen 361012,China);HPLC Determination of Benzene Homologues and Phthalic Esters as Plastifiers in Architectural Adhesives[J];Physical Testing and Chemical Analysis(Part B:Chemical Analysis);2010-05
5 YE Xi-wen1,WANG Hui-hui1,2,NIU Zeng-yuan1,QIAN Yi2(1.Shandong Entry-Exit Inspection and Quarantine Bureau,Qingdao 266002,China;2.School of Environment and Safety Engineering,Qingdao University of Science and Technology,Qingdao 266042,China);Simultaneous Determination of Eleven Phthalic Acid Esters in Waterborne Coatings by High Performance Liquid Chromatography[J];Journal of Instrumental Analysis;2009-05
6 FANG Cheng,WANG Yang,CAO Yu-hua(School of Chemical and Material Engineering,Jiangnan University,Wuxi 214122,China);Preparation of Electrochemical Sensor for Parabens Based on Molecularly Imprinted Polymers[J];Journal of Instrumental Analysis;2009-07
7 LUO Caihong,GUO Zhishun,SUN Jing(Chongqing Environmental Monitoring Center,Chongqing 401147,China);Determination of phthalate esters in sediment by accelerated solvent extraction and gas chromatography-triple quadrupole mass spectrometry[J];Chinese Journal of Chromatography;2010-05
8 CHEN Ai1,HE Qiaosang2,WANG Pingya1,ZHOU Yong1,HUANG Li1,XU Zhenjian1,ZHAO Hua1,ZHANG Weiying1(1.National Marine Food Quality Supervision and Testing Center,Zhoushan 316021,China;2.Zhejiang Province Food Quality and Safety Test Center,Hangzhou 310013,China);Determination of six p-hydroxybenzoates in fruits and jams using solid-phase extraction-high performance liquid chromatography[J];Chinese Journal of Chromatography;2009-06
9 WANG Feng1,2 ZHANG Xiaoqiang1 LU Jian1 ZHANG Chunpeng1(1. National Supervising&Testing Center for Cosmetics Quality,Nanjing 210029,China;2. College of Forest Resources and Environment of Nanjing Foresty University,Nanjing 210037,China);Determination of 15 Phthalates in Cosmetic by Chromatography/Mass Spectrometry[J];Flavour Fragrance Cosmetics;2009-05
【Secondary Citations】
Chinese Journal Full-text Database 4 Hits
1 Dai Qing, Guo Yan, Yuan Chunwei (National Laboratory of Molecular and Biomolecular Electronics, Southeast University, Nanjing 210096) Xi Rongbiao, Lin Baoping (Department of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096);ELECTROCHEMICALLY ASSISTED PHOTOCATALYTIC DEGRADATION OF CHLOROPHENOLS USING TiO 2 MICROPOROUS FILM[J];CHINESE JOURNAL OF CATALYSIS;1999-03
2 LIU Hong 1, LENG Wenhua 2, WU Hejin 1, CHENG Shaoan 2, WU Ming 1, ZHANG Jianqing 2, LI Wenzhao 1, CAO Chunan 2 (1 Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, China; 2 Department of Chemistry, Zhejiang U;Study of Photoelectrocatalytic Degradation of Sulfosalicylic Acid[J];CHINESE JOURNAL OF CATALYSIS;2000-03
3 WU He jin, WU Ming, XIE Mao song, LIU Hong, YANG Min, SUN Fu xia, DU Hong zhang (Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023);Primary Study of the Enhanced Electro-assisted Photocatalytic Degradation of Organic Contaminants in Water[J];JOURNAL OF MOLECULAR CATALYSIS (CHINA);2000-04
4 LENG Wenhua, CHENG Shao'an, ZHANG Jianqing, CAO Chunan\ (Department of Chemistry, Zhejiang University, Yuquan district, Hangzhou 310027);Combination degradation of aniline via photoelectrocatalysis and photogenerating hydrogen peroxide[J];Acta Scientiae Circumstantiae;2001-05
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