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《Applied Chemical Industry》 2010-11
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Synthesis of cyclohexene on solid super acid catalyst S_2O_8~(2-)/Fe_2O_3/ZnO/ZrO_2

DU Jun,MENG Shuang-ming,GUO Yong,YANG Guo-chen(School of Chemistry and Chemical Engineering,Shanxi Datong University,Datong 037009,China)  
S2O2-8/Fe2O3/ZnO/ZrO2 Composite super-solid acid catalyst has been prepared by the methods of precipitation,preburning,impregnation,drying,baking and so on,and has done the related research for it.Cyclohexene was prepared by applying a novel solid acid catalyst S2O2-8/Fe2O3/ZnO/ZrO2 as dehydration catalyst.The effect of catalyst amount,temperature and reaction time on the dehydration reaction had been investigated.The results showed that S2O2-8/Fe2O3/ZnO/ZrO2 possessed many advantages such as shorter reaction time,higher yield,smaller catalyst amount,being disposable S2O2-8/Fe2O3/ZnO/ZrO2 and reusable.The optimized conditions for the reaction were as follows:catalyst was equal to 6.7% by the mass of the total reaction stocks,reaction temperature 150 ℃,reaction time 0.9 h.
【Fund】: 山西省高校科技开发项目(200811040);; 山西大同大学青年基金(2009Q15)
【CateGory Index】: TQ231.2
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