Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Applied Chemical Industry》 2010-11
Add to Favorite Get Latest Update

Synthesis of cyclohexene on solid super acid catalyst S_2O_8~(2-)/Fe_2O_3/ZnO/ZrO_2

DU Jun,MENG Shuang-ming,GUO Yong,YANG Guo-chen(School of Chemistry and Chemical Engineering,Shanxi Datong University,Datong 037009,China)  
S2O2-8/Fe2O3/ZnO/ZrO2 Composite super-solid acid catalyst has been prepared by the methods of precipitation,preburning,impregnation,drying,baking and so on,and has done the related research for it.Cyclohexene was prepared by applying a novel solid acid catalyst S2O2-8/Fe2O3/ZnO/ZrO2 as dehydration catalyst.The effect of catalyst amount,temperature and reaction time on the dehydration reaction had been investigated.The results showed that S2O2-8/Fe2O3/ZnO/ZrO2 possessed many advantages such as shorter reaction time,higher yield,smaller catalyst amount,being disposable S2O2-8/Fe2O3/ZnO/ZrO2 and reusable.The optimized conditions for the reaction were as follows:catalyst was equal to 6.7% by the mass of the total reaction stocks,reaction temperature 150 ℃,reaction time 0.9 h.
【Fund】: 山西省高校科技开发项目(200811040);; 山西大同大学青年基金(2009Q15)
【CateGory Index】: TQ231.2
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 1 Hits
1 ZHANG Yan,SHU Hua,WU Si-zhan,TANG Bang-cheng,ZHOU Zeng-yan (Department of Biology & Chemistry Tongren College,Institute of Applied Chemistry,Guizhou Tongren 554300,China);The Research of Solid Super Acid Catalyst over the Alkylation Reaction of o-cresol and Tert-butyl Alcohol[J];Guangzhou Chemical Industry;2013-12
【Citations】
Chinese Journal Full-text Database 7 Hits
1 ZHANG Xia~(1,2),WU Feng-hua~1,HU Yi-min~1 (1.College of Chemistry and Materials Science,Anhui Normal University, Wuhu 241000,China;2.Department of Chemistry,Anqing Teacher's College,Anqing 246011,China);Preparation of Cyclohexene by Dehydration of Cyclohexanol on SO_4~(2-)-La_2O_3-TiO_2 Catalyst[J];Journal of Anhui Normal University(Natural Science);2006-01
2 FANG Zhi-li(Faculty of Basic Science,East China Jiaotong University,Nanchang 330013,China);Study on the Solid Superacid SO_4~(2-)/ZrO_2-La_2O_3 Catalyzed Synthesis of Cyclohexene[J];Journal of East China Jiaotong University;2007-01
3 Gu Xupeng,Yu Weiqin,Huang Yurong (Department of Application Chemistry Anhui University of Technology,Ma'anshan 243002);Application Study on Synthesis of Cyclohexene by Composite Fly Ash-Solid Acid as Catalyst[J];Chemical Industry and Engineering Progress;2004-02
4 WANG Yan1,LI Xian-cai1,CAO Xiao-hua1,2(1.Department of Chemistry,Nanchang University,Nanchang 330031,China;2.College of Chemistry and Chemical Engineering,Jiujiang University,Jiangxi Jiujiang 332005,China);Preparation of SO_4~(2-)/TiO_2-WO_3 Through Hydrothermal Modification and Its Application to Catalytic Dehydration of Cyclohexanol to Cyclohexene[J];Journal of Nanchang University(Natural Science);2007-04
5 ;稀土改性的固体超强酸SO_4~(2-)/TiO_2-La_2O_3催化合成丁酸丁酯[J];Science and Technology of Food Industry;2005-06
6 CHEN Ping (School of Petrochemical Technology,Liaoning University of Petroleum & Chemical Technology,Fushun 113001,China);Studing on prepration of cyclohexene by various catalysts[J];Shaanxi Chemical Industry;2004-03
7 Cao Xiaohua1 Li Xiancai1 Liao Xiaoning1,2( 1Department of Chemistry, Nanchang University., Nanchang Jiangxi 330047 China )(2Department of Chemistry, Jiangxi Agricultural University., Nanchang Jiangxi 330045 China )Cao Kai3 Hong Chengbo3( 3?Department of Chemistry,Jiangxi Normal University., Nanchang Jiangxi 330027 China );Green synthesis of Cyclohexene[J];Chemincal Intermediate;2005-07
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 WU Ying-hua,XIANG Kai-xiang,HOU Xiao-juan,WU Wei-lin (Huaihua Medical Courses in General,Huaihua 418000,China);Progress in the development of catalytic synthesis of butyl butyrate in China[J];China Surfactant Detergent & Cosmetics;2007-03
2 YU Shan-xin, GUAN Shi-bin, LIU Mei-yan(College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China);Preparation of Cyclohexene from Dehydration of Cyclohexanol Catalyzed by Solid Acid[J];Journal of Chenzhou Teachers College;2005-02
3 LIN Qian,CHEN Xiu-yu (Department of Biology and Chemistry Engineering,Fuqing Branch of Fujian Normal University,Fuqing,Fujian 350300,China);Synthesis of Tri(n-amy1) citrate catalyzed by rare-earth solid excess strong acid[J];Journal of Minjiang University;2012-02
4 LENG Ling-bo,GU Xu-peng (Department of Applied Chemistry,Anhui University of Technology,Ma'anshan 243002,Anhui China);Developments in modification of SO_4~(2-)/M_xO_y solid acid catalysts[J];Industrial Catalysis;2006-04
5 WANG Lan-zhi1,YANG Li-jing2,ZHAO Xiao-hong3,HE Xuan1 (1.College of Chemistry and Material Science,Hebei Normal University,Hebei Shijiazhuang 050016,China;2.The Cadre College of Chinese Environmental Management,Hebei Qinhuangdao 066004,China;3.Qinhuangdao Branch,North China Coal Medical College,Hebei Qinhuangdao 066004,China);Synthesis of Cyclohexene under Green Chemistry Philosophy[J];Journal of Hebei Normal University(Natural Science Edition);2009-02
6 FANG Zhi-li(Faculty of Basic Science,East China Jiaotong University,Nanchang 330013,China);Study on the Solid Superacid SO_4~(2-)/ZrO_2-La_2O_3 Catalyzed Synthesis of Cyclohexene[J];Journal of East China Jiaotong University;2007-01
7 Liu Xianxiang,Mao Liqiu,Yin Dulin(The Key Lab of Resources Fine-Processing and Advanced Materials of Hunan Province,Institute of Fine Catalysis and Synthesis,Hunan Normal University,Changsha Hunan 410081,China);Research Progresses on Value-added Utilization of Fly Ash[J];Environmental Protection of Chemical Industry;2009-01
8 Wu Yinghua Hou Xiaojuan Ji Huaiping(Huaihua Medical College,Hunam Huaihua 418000);Catalytic System for Synthesis of Butyl Butyrate[J];Chemical Industry Times;2007-03
9 Liu Meiyan Yu Shanxin Guan Shibin (College of Chemistry and Chemical Engineering,Hunan Normal University,Changsha,410081);Research Progress on Synthesis of n-butyl Butyrate by Catalytic Esterification[J];China Chemicals;2007-03
10 GU Xu-peng,LENG Ling-bo(School of Chemistry and Chemical Engineering,Anhui University of Technology,Ma'anshan 243002,China);Synthesis of Butyl Lactate with Fly Ash Composite Solid Acid as Catalyst[J];Fine Chemical Intermediates;2006-03
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 PAN Jiang-Qing(Institute of Chemistry, Chinese Academy of Sciences, Beijing\ 100080,China);Study and Application of Antioxidant in Polymer Area[J];Polymer Bulletin;2002-01
2 WU Wen-li,WAN Hui,GUAN Guo-feng(College of Chemistry and Chemical Engineering,Nanjing University of Technology,Nanjing 210009,China);Characterization and Evaluation of Solid Superacid Catalyst SO_4~(2-)/SnO_2-Al_2O_3 Prepared by Aging at Low Temperature[J];Journal of Chemical Engineering of Chinese Universities;2011-02
3 WANG Qing,ZHONG Si-zhi,YANG Yu-nong,WENG Qi-yang,WANG Bin(Guangzhou Research Institute of Synthetic Materials,Guangzhou 510665,Guangdong,China);Synthesis of 2-Methyl-6-t-Butylphenol[J];Synthetic Materials Aging and Application;2006-04
4 L Jiu-zhuo~1,FENG Lei~2,XU Ya-xian~1,CHAI Jin-rong~1,SHEN Jing~1 (1.Department of Chemical Engineering,Beijing Institute of Petrochemical Technology,Beijng 102617,China;2.Department of Chemical Engeering,Beijing University of Chemical Technology,Beijing 100029,China);Synthesis of 3-Methyl-6-t-butylphenol[J];Fine Chemicals;2003-11
5 XU Haiyun,LIU Ying(Department of Chemistry,Shangqiu Teachers College,Shangqiu 476000,China);Study on synthesis of p-tert-butylphenol from methyl tert-butyl ether with phenol catalyzed by solid superacid SO_4~(2-)/Fe_2O_3[J];Journal of Shangqiu Teachers College;2010-03
6 CHENG Zhan-sheng,XING Chun-li,TIAN Jing-cheng,YANG Lin (Department of Biological and Chemical and Environmental Engineering, Jiaozuo University, Jiaozuo 454003, China);Recent development on the solid superacid catalysts[J];Shaanxi Chemical Industry;2004-06
7 SU Yi~1,2,ZHU Shu-quan~1,WANG Jian-li~1(1.School of Chemical and Environmental Engineering,China University of Mining Technology,Beijing 100083,China;2.Chemistry Department,Huanghuai College,Zhumadian 436000,China);CATALYTIC SYNTHESIS OF LONG CHAIN ALKYLPHENOL BY Fe_2O_3·SO_4~(2-)[J];Acta Petrolei Sinica(Petroleum Processing Section);2006-05
8 GAO Lei1,2,LIU Min1,NIE Xiaowa1,GAO Jian1,3,GUO Xinwen1(1.State Key Laboratory of Fine Chemicals,Department of Catalysis Chemistry and Engineering,Shool of Chemical Enigineering,Dalian University of Technology,Dalian 116012,China;2.Zhengzhou Branch,China Nuclear Power Engineering Co.Ltd.,Zhengzhou 450052,China;3.School of Chemical Engineering and Energy,Zhengzhou University,Zhengzhou 450002,China);SO_3H-Functionalized Ionic Liquids for Selective Alkylation of o-Cresol With tert-Butanol[J];Acta Petrolei Sinica(Petroleum Processing Section);2011-02
9 Wang Zhicai,Sun Zhengjun (School of Chemistry & Chemical Engineering,Anhui University of Technology,Maanshan Anhui 243002,China);SO_4~(2-)/ZrO_2 Solid Super Acid Catalyst for Benzylation of Toluene with Benzyl Chloride[J];Petrochemical Technology;2005-10
10 Pan Lurang and Zhang Alping(Department of Chemistry, Nankai University, Tianjin 300071);Study of New Catalysts for Alkylation of Phenol to p-Tert-Butylphenol and 2, 4-Ditert-Butylphenol[J];PETROCHEMICAL TECHNOLOGY;1996-11
【Secondary References】
Chinese Journal Full-text Database 1 Hits
1 ZHANG Weixin;LIAO Liewen;HU Wenbin;GONG Hongsheng;College of Chemistry and Chemical Engineering,Zhongkai University of Agriculture and Engineering;;Research development on supported solid super acid catalyst[J];Journal of Zhongkai University of Agriculture and Engineering;2014-01
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 $ Gao Genzhi (Chemistry Department, Qufu Normal University, Qufu 273165) Yu Shitao, Yang Jinzong (Department of Fine Chemicals, Dalian University of Technology, Dalian 116012);PREPARATION OF SO 2- 4/TiO 2 Al 2O 3 SnO 2 AND ITS CATALYTIC PROPERTIES FOR THE SYNTHESIS OF DIOCTYL ADIPATE[J];CHINESE JOURNAL OF CATAL YSIS;1996-01
2 Chen Kaidong, Yan Qijie (Department of Chemistry, Nanjing University, Nanjing 210093);INFLUENCE OF LANTHANUM ON THE STRUCTURE AND CATALYTIC PERFORMANCE OF Fe/ZrO 2 CATALYSTS FOR CO HYDROGENATION[J];CHINESE JOURNAL OF CATALYSIS;1997-03
3 Xu Limin Lin Shen Yan Guiyang Chen Shouzheng (Department of Chemistry ,Fujian Teachers University ,Fuzhou 350007);Studies on the Catalytic Activity of Modified Bentonite in the Dehydration of Cyclohexanol[J];JOURNAL OF FUJIAN TEACHERS UNIVERSITY(NATURAL SCIENCE);1999-02
4 YANG Shui\|jin, YU Xie\|qing, LIANG Yong\|guang (Department of Chemistry, Hubei Normal University, Huangshi 435002, China);Synthesis of Benzoates Using TiSiW_(12)O_(40)/TiO_2 Catalyst[J];Journal of Molecular Catalysis (China);2001-06
5 YANG Shuijin1, 2, YU Xieqing2, LIANG Yongguang1, SUN Jutang1(1. College of Chemistry and Molecular Sciences, Wuhan University, Hubei Wuhan 430072, China 2. Department of Chemistry and Environmental Engineering, Hubei Normal University, Hubei Huangshi 435002, China;);Synthesis of Ethyl Acetoacetate Ethylene Ketal Catalyzed by using TiSiW_(12)O_(40)/TiO_2[J];Journal of Molecular Catalysis (China);2003-01
6 Gao Zi,Chen Jian-min,Tang Yi (Department of Chemistry,Fudan University,Shanghai,200433);Studies on the Formation of ZrO_2/SO_4~(2-)Superacid System[J];Chemical Research In Chinese Universities;1992-12
7 LI Ji-zhong (The Shanxi Province Key Laboratory of Chemical Reaction Engneering, Department of Chemistry and Chemical Engineering, Yanan University, Yanan 616000, China);The Synthesis of Cyclohexene Catalyzed by Sodium Hydrogen Sulfate[J];Chinese Journal of Synthetic Chemistry;2004-03
8 Gu Xupeng,Yu Weiqin,Huang Yurong (Department of Application Chemistry Anhui University of Technology,Ma'anshan 243002);Application Study on Synthesis of Cyclohexene by Composite Fly Ash-Solid Acid as Catalyst[J];Chemical Industry and Engineering Progress;2004-02
9 Guo Junsheng (Department of Chemistry,Xinxiang Teacher′s College,Xinxiang 453000);Preparation of cyclohexene by catalyzed dehydration of cyclohexanol[J];Chemical Reagents;2001-03
10 Yuan Xian you ,Zhang Min,Liu Yuanyuan (Department of Chemistry,Lingling Teacher′s College,Yongzhou 425000);Synthesis of cyclohexene catalyzed by SnCl_4[J];Chemical Reagents;2001-03
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved