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《Acta Petrolei Sinica (Petroleum Processing Section)》 2005-01
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STUDIES ON THE FORMATION OF INVERSE MICROEMULSION FROM Span80-Tween60/WHITE OIL/ACRYLAMIDE/SODIUM ACRYLATE/H_(2)O SYSTEM

ZHAO Huai-zhen~(1), WU Zhao-liang~(1), ZHENG Xiao-yu~(2), LIN Mei-qin~(1), LI Ming-yuan~(1)(1. Enhanced Oil Recovery Research Center, University of Petroleum, Beijing 102249, China;2. School of Chemical Engineering, University of Petroleum, Beijing 102249, China)  
The process of inverse microemulsion formed from Span80-Tween60/white oil/ acrylamide/sodium acrylate/H_2O system was investigated by the conductivity method, phase volume method, phase diagrams, viscosity, and optical microscope. The results showed the inverse microemulsion area boundaries determined separately with conductivity method or with phase volume method were consistent with each other when the mass fraction of surfactant in system was lower than 20%,the microemulsion boundaries determined with the conductivity method were observed far apart from the microemulsion boundaries.This indicated that the boundaries are to be determined by the combination of conductivity method and phase volume method rather than to use the conductivity method only. Under m(Span80)∶m(Tween60) of 13∶7, θ of 25-30℃ and w(Sodium acetate) of 2%, the system formed relatively larger inverse microemulsion area which was suitable for microemulsion polymerization.
【CateGory Index】: O648
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