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《Petrochemical Technology》 2002-05
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Catalytic Synthesis of Acetals or Ketals with Vitamin C

WEN Rui-ming, YOU Pei-qing, LUO Xin-xiang, YU Shan-xin (Department of Chemistry, Yiyang Teachers College, Yiyang Hunan 413049, China)  
The catalyst of vitamin C was first used in the synthesis of acetals and ketals. Glycol or 1,2-propanediol reacted with the carbonyl group of aldehydes or ketones in the presence of vitamin C to yield acetals or ketals. Thus a mixture of 0 2 mol aldehydes or ketone, 0 3 mol alcohols and 0 3 g vitamin C using cyclohexane as solvent was heated for 60 min under reflux and water separation, the yield was 70%~84%.
【Fund】: 湖南省教育厅科研基金资助课题 (0 1C0 2 2 )
【CateGory Index】: O623.541
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【References】
Chinese Journal Full-text Database 10 Hits
1 YANG Shui jin DU Xin xian LV Bao lan(Department of Chemistry and Environmental Engineering, Hubei Normal University, Hubei Huangshi 435002,China);Synthesis of acetals and ketals catalyzed by phosphotungstic acid supported on active carbon[J];Journal of Beijing University of Chemical Technology;2005-01
2 YANG Shuijin, YU Xieqing, SUN Jutang Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002, China; College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China;Synthesis of Butyraldehyde Glycol Acetal by using TiSiW_(12)O_(40)/TiO_2 as Catalyst[J];Journal of University of Science and Technology Beijing;2003-06
3 YOU Pei-qing~1 LUO Xin-xiang~2 WEN Rui-ming~2 YU SHan-xin~3 (1.Department of Science and Technology,Hunan City University,Yiyang Hunan,413000;2.Department of Chemistry and Environmental,Hunan City University,Yiyang Hunan,413049;3.College of Chemistry and Chemical Engineering,Hunan Normal University,CHangsha Hunan,410081);Study Synthses of Cyclohexanone Ethylene Ketal[J];Journal of Hunan University of Arts and Science(Natural Science Edition);2006-02
4 YU SHan-xin1, LIU Mei-yan1, GUAN Shi-bin1, WEN Rui-ming2 (1. College of Chemistry and Chemical Engineering, Hunan Normal University, CHangsha Hunan 410081; 2. Department of Chemistry and Environmentally Engineering, Hunan City University, Yiyang Hunan 413000);Progress on Synthesis of Cyclohexanone 1,2-propylene Ketal Catalyzed by Solid Acid[J];Journal of Hunan University of Arts and Science(Natural Science Edition);2006-03
5 Yang Shuijin Tong Wenlong (Hubei Key Laboratory of Bioanalytical Technique,Hubei Normal University,Huangshi 435002,China);Catalytic Synthesis of Acetals and Ketals with H_3PW_6Mo_6O(40)/TiO_2[J];Rare Metal Materials and Engineering;2007-S3
6 WANG Jing-yun,ZHANG Shu-jiang(Vocational and Technical College,Liaoning University of Petroleum & Chemical Technology,Fushun Liaoning 113001,P.R.China);Application of Solid Superacid Catalyst SO_4~(2-)/ZrO_2 in Acetalization[J];Journal of Liaoning University of Petroleum & Chemical Technology;2006-01
7 HE Jie-yu, LIAO De-zhong , MAO Li-xin, CHEN Xian-tao(Department of Chemical Engineering, Hunan Institute of Science and Technology, Yueyang Hunan 414000 , China);The Acid Property of Titanium Sulfate Doped Lanthanum Oxide and its Catalytic Activity in Ketal Synthesis[J];Journal of Molecular Catalysis;2005-02
8 CHEN Fang,CHEN Di-hai,Lü Bao-lan,YANG Shui-jin ( Department of Chemistry and Environmental Engineering,Hubei Normal University, Huangshi 435002,Hubei China );Synthesis of cyclohexanone 1,2-propanediol ketal catalyzed by H_3PW_(12)O_(40)/PAn[J];Industrial Catalysis;2004-12
9 TAN Zhi-wei~(1,2),LI Bi-na~2,CHEN Zhen-hua~2 (1.Faculty of Chemical and Environmental Engineering,Hubei Institute for Nationalities, Enshi 445000,China;2.Faculty of Chemical Engineering and Light Industry,Guangdong University of Technology,Guangzhou 510090,China);Catalytic Synthesis of Cyclohexanone Ethylene Ketal with Solid Superacid SO_4~(2-)/TiO_2-Y(Ⅲ)[J];;2004-05
10 BAI Ai min,YU Jian yong,YANG Shui jin, HAN De yan ( Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002,China);Catalytic synthesis of benzaldehyde glycol acetal with SO_4~(2-)/TiO_2-MoO_3[J];Journal of Hubei Normal University(Natural Science);2004-02
【Citations】
Chinese Journal Full-text Database 2 Hits
1 Yu Shanxin Lei Cunxi Long Liping(Department of Chemistry, Hunan Yiyang Teacher's College, Yiyang 413049);Research on Catalytic Synthesis of Cyclohexanone Ethylene Ketal[J];Advances in Fine Fetrochemicals;2001-01
2 Yu Shanxin Chen ChunlinDepartment of Chemistry, Hunan Normal University, Changsha, 410081;Catalytic Synthesis of Acetals or Ketals with Polymer Protected Catalyst polyvinyl chloride-Ferric chloride[J];Ion Exchange and Adsorption;1992-05
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 GUO He-min (Teaching and Research Section of Chemistry, Anhui Medical University,Hefei 230032,China);Synthesis of (S)-(+)-Naproxen via asymmetric cross-coupling reaction[J];Journal of Anhui University(Natural Sciences);2002-02
2 Zhang Zhongping(Chemistry Department of Chaohu College,Anhui 238000);Lauroyl Aarcosine Synthesis and Its Corrosion Inhibition Evaluation[J];Anhui Chemical Industry;2003-03
3 ZHANG Fu-juan,SHENG Shu-ling,ZHANG Xiang-yu(Department of Chemistry,Xuchang University,Xuchang 461000,China);Synthesis of Cyclohexanone 1,2-Propanediol Ketal Catalyzed by Sulfamic Acid[J];Anhui Chemical Industry;2006-01
4 Liu Xingrong et al(Dept. of Pharmacy, Shangdong Medical University);Study on the Synthsis, Characterization and Antibacterial Activity of Zn(Ⅱ)Complex with Schiff Base of L-Leucine[J];;1994-02
5 Liao Xiaoyuan(Dongshen Fine Cheinical Research Institute, Shenzen 518057);Some Basic Physical Properties of L-, D-, DL-Theronine and Allothreonine[J];AMINO ACIDS & BIOTIC RESOURCES;1995-01
6 Liu GuoXing; Zhang Zinwei; Hu Derong(Department of Chemistry, Capital Normal University, BeiJing 100037)Hu Wenzing Academy of Military medical Sciences, Beijing 100850);Esterification of Amino Acids and Their Infrared Spectroscopy[J];AMINO ACIDS & BIOTIC RESOURCES;1995-03
7 Din Zhongyu;Li Wenzhong Department Of Foundamental Sciences;STUDY ON FLUCYTHRINATE[J];Journal of Anhui Agricultural University;1991-03
8 SUN Qi-xiang~1,PENG Zhen-hua~1,ZHANG Qi-sheng~2 (1.Research Institute of Forestry,Chinese Academy of Forestry,Beijing 100091; 2.Nanjing Forestry University,Nanjing 210037);Volatiles of Wood of Chinese Fir in Nature and Its Effect on Human Health[J];Journal of Anhui Agricultural University;2004-02
9 YAO Peng-li,CHEN Jian,XIAO Ren-hai (Huaibei Coal Teachers' College,Huaibei 235000,China);The Best Condition for the Precipitation of Lead Chromate[J];Journal of Anqing Teachers College(Natural Science Edition);2002-01
10 HUANG RongYi1, LIU JuXiang2 (1 Chemistry Department of Anqing Teachers College, Anqing 246011, China 2 Heli Middle School of Ninguo, Ninguo 235000, China);A Basic Solutions Method of Calculating Wave Function of Degenerate Energy Level for Conjugated Molecule[J];Journal of Anqing Teachers College(Natural Science Edition);2003-04
China Proceedings of conference Full-text Database 4 Hits
1 GUO Jun-ming WANG Bao-sen LIU Gui-yang ZHAI Feng-rui LIU Jie HE Ying (College of Science,Honghe University,Mengzi 661100,China);Solution combustion synthesis of LiMn_2O_4 powder by using acetic acid as fuel in nitrate system[A];[C];2008
2 CHEN Jing-Jing~(1,2) SUN Zhi-gao~(2*) (1.College of Food Science,Southwest University,Chongqing 400715,China; 2.Citrus Research Institute,Chinese Academy of Agricultural Sciences,Chongqing 400712,China);Research advances on limonene[A];[C];2007
3 Xue-zheng Liang ;Shan Gao ; Yue-chang Zhao; Lin Liu;Jian-guo Yang Shanghai Key Laboratory of Green Chemistry and Chemical Process, East China Normal University, North Zhongshan Rd.3663, Shanghai200062;Synthesis of Novel Seven-member-ring Acetals and Ketals Catalyzed by HY[A];[C];2006
4 DOU Sen ZHANG Jin-Jing LI Kai YU Shui-Qiang WANG Li-Li PING LI-Feng Guan Song ZHOU Su-Yan LIN Xue-Wei GAO-Xian College of Resources and Environmental Sciences,Jilin Agricultural University Changehun 130118 China. Yves Tardy ENSAT,Montgeard,31560 Nailloux,Toulouse,France;A Preliminary Study on Thermodynamic Stability of Humic Acid and Fulvic Acid in Soil[A];[C];2008
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 ZHANG Fu-juan,SHENG Shu-ling,ZHANG Xiang-yu(Department of Chemistry,Xuchang University,Xuchang 461000,China);Synthesis of Cyclohexanone 1,2-Propanediol Ketal Catalyzed by Sulfamic Acid[J];Anhui Chemical Industry;2006-01
2 GUO Jun cheng 1,ZHANG You jin 1,SHU Jun sheng 2,LIU Qiang 3,CHENG Xiao lei 1 (1.College of Economics and Technology,University of Science and Technology of China,Hefei 230052; 2.Technical Center of Wuhu Cigarette Factory;3.Technical Center of Y;Study on Maillard Reaction Flavor of Tobacco[J];JOURNAL OF ANHUI AGRICULTURAL UNIVERSITY;2002-01
3 YANG Shui jin DU Xin xian LV Bao lan(Department of Chemistry and Environmental Engineering, Hubei Normal University, Hubei Huangshi 435002,China);Synthesis of acetals and ketals catalyzed by phosphotungstic acid supported on active carbon[J];Journal of Beijing University of Chemical Technology;2005-01
4 YANG Shuijin, LIANG Yongguang, DONG Jiinghua, SUN Jutang, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002, China;Synthesis of Propionates by using TiSiW12O40/TiO2 as Catalyst[J];Journal of University of Science and Technology Beijing;2003-04
5 YANG Shuijin, YU Xieqing, SUN Jutang Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002, China; College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China;Synthesis of Butyraldehyde Glycol Acetal by using TiSiW_(12)O_(40)/TiO_2 as Catalyst[J];Journal of University of Science and Technology Beijing;2003-06
6 YANG Shuijin TONG Wenlong YIN Guojun Department of Chemistry and Environmental Engineering,Hubei Normal University,Huangshi 435002,China;Catalytic synthesis of acetals and ketals with I_2/PAn[J];Journal of University of Science and Technology Beijing;2006-03
7 Lin Shijing1 Sun Yangzhao2 (1 Department of Chemical Engineering, Beijing Institute of Petro-chemical Technology, Beijing 102617; 2 Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085);Catalytic Synthesis of Ethyl Propionate with P-Toluene Sulfonic Acid[J];Journal of Beijing Institufe of Petrochemical Technology;2005-01
8 ZHAO Li fang,HE Zhu sheng,WANG Feng (Dept. Chem.& Chem.Eng., Baoji Coll. Arts & Sci., Baoji 721007, Shaanxi, China);The application of the solid superacids in acid catalytic reactions[J];JOURNAL OF BAOJI COLLEGE OF ARTS AND SCIENCE(NATURAL SCIENCE EDITION);1999-03
9 NIE Guo-chao (Scientific Research Department, Xiangfan Vocational and Technical College, Xiangfan 441021, China);SYNTHESIS OF BENZALDEHYDE DIHEXYL MERCAPTAL CATALYZED BY PHOSPHOTUNGSTIC ACID IMMOBILIZED ON ION EXCHANGE RESIN[J];Journal of Beijing Technology and Business University (Natural Science Edition);2004-01
10 XU Jing-shi, CHEN Hui-zong (Institute of Chemistry and Biological Science,Jiangxi Normal Universit y,Nanchang 330027,China);The Study of Rare Earth Solid Superacids for Catalytic Synthesis of Hydroxybenzoic Ethers[J];JOURNAL OF JIANGXI NORMAL UNIVERSITY (NATURAL SCIENCES EDITION);2000-02
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 ZHANG Fu-juan,SHENG Shu-ling,ZHANG Xiang-yu(Department of Chemistry,Xuchang University,Xuchang 461000,China);Synthesis of Cyclohexanone 1,2-Propanediol Ketal Catalyzed by Sulfamic Acid[J];Anhui Chemical Industry;2006-01
2 YANG Shui-jin~1 WANG Min~2(1.Department of Chemistry and Environmental Engineering,Hubei Normal University,Hubei Huangshi 435002,China;2.College of Chemistry,Central China Normal University,Hubei Wuhan 430079,China);Catalytic synthesis of butanone 1,2-propanediol ketal over H_4SiW_6Mo_6O_(40)/PAn[J];Journal of Beijing University of Chemical Technology;2005-05
3 YANG Shuijin TONG Wenlong YIN Guojun Department of Chemistry and Environmental Engineering,Hubei Normal University,Huangshi 435002,China;Catalytic synthesis of acetals and ketals with I_2/PAn[J];Journal of University of Science and Technology Beijing;2006-03
4 YANG Shui-jin,GAO Fei,TONG Wen-long(Department of Chemistry and Environmental Engineering,Hubei Normal University,Huangshi 435002,China);CATALYTIC SYNTHESIS OF ACETALS AND KETALS WITH H_3PW_6Mo_6O_(40)/PAn[J];Journal of Beijing Technology and Business University(Natural Science Edition);2008-01
5 XU Zhao-hui~a,LIU Xian-liang~b,ZHANG Shi-jin~a,LIAO Wei-lin~a (a.Institute of Chemistry and Chemical Engineering Sciences;b.Periodical Office of Journal,Jiangxi Normal University,Nanchang 330027,China);Synthesis of Benzaldehyde Glycol Acetal Catalyzed by CePW_(12)O_(40)[J];Journal of Jiangxi Normal University(Natural Sciences Edition);2006-05
6 YU SHan-xin1, LIU Mei-yan1, GUAN Shi-bin1, WEN Rui-ming2 (1. College of Chemistry and Chemical Engineering, Hunan Normal University, CHangsha Hunan 410081; 2. Department of Chemistry and Environmentally Engineering, Hunan City University, Yiyang Hunan 413000);Progress on Synthesis of Cyclohexanone 1,2-propylene Ketal Catalyzed by Solid Acid[J];Journal of Hunan University of Arts and Science(Natural Science Edition);2006-03
7 YU Shan-xin1,WEN Rui-ming 2,YOU Pei-qing 3 (1.College of chemistry and chemical engineering,Hunan normal university,Hunan,Changsha,410081;2.Department of chemistry and environmentally engineering,Hunan city university,Hunan,Yiyang,413049;3.Department of science and technology,Hunan city university,Hunan,Yiyang,413000);Application of sodium bisulfate monohydrate in organic synthesis[J];Journal of Hunan University of Arts and Science(Science and Technology);2008-01
8 YANG Shui-jin~(1,2),DU Xin-xian~1,SUN Ju-tang~2 (1.Department of Chemistry and Environmental Engineering,Hubei Normal University,Huangshi435002,China; 2.College of Chemistry and Molecular Sciences,Wuhan University,Wuhan430072,China);Catalytic synthesis of n-butyraldehyde glycol acetal with SO_4~(2-)/TiO_2-La_2O_3[J];China Surfactant Detergent & Cosmetics;2004-05
9 XU Zhao-hui,LIAO Wei-lin,WANG Sheng(Chemistry and Chemical Engineering of Jiangxi Normal University,Nanchang 330027,China);Synthesis of benzaldehyde 1,2-propanediol acetal by H_3PW_(12)O_(40)/TiO_2[J];China Surfactant Detergent & Cosmetics;2005-06
10 WANG Qing-ning,ZHANG Lei,FANG Ming-feng,JIANG Rui-yu(School of Petrochemical Engineering,Lanzhou University of Technology,Lanzhou 730050,China);Synthesis technology of fructone[J];China Surfactant Detergent & Cosmetics;2008-06
China Proceedings of conference Full-text Database 1 Hits
1 Xue-zheng Liang ;Shan Gao ; Yue-chang Zhao; Lin Liu;Jian-guo Yang Shanghai Key Laboratory of Green Chemistry and Chemical Process, East China Normal University, North Zhongshan Rd.3663, Shanghai200062;Synthesis of Novel Seven-member-ring Acetals and Ketals Catalyzed by HY[A];[C];2006
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 Ran Rui-cheng, Huang Jin, Jia Xin-ru and Shen Ji (Department of Chemistry,Beijing University);A POLYMER-SUPPORTED LEWIS ACID CATALYST: COPOLY(STYRENE-N-VINYLCARBAZOLE)-TITANIUM TETRACHLORIDE COMPLEX[J];Chinese Journal of Catalysis;1987-04
2 Ran Rui-cheng and Mao Guo-ping (Department of Chemistry, Peking University);POLYMER-SUPPORTED STANNIC CHLORIDE COMPLEX CATALYSTS Ⅵ. COPOLY (STYRENE-4-VINYLPYRIDINE) -STANNIC CHLORIDE COMPLEX[J];Chinese Journal of Catalysis;1989-01
3 Liu Fu-an, Zhao Jun-xiu and Huang Hua-min(Department of Chemistry, Jilin University, Changchun 130023);SYNTHESIS OF ION EXCHANGE RESIN-SUPPORTED TITANIUM TETRACHLORIDE AND ITS APPLICATIONS[J];Chinese Journal of Catalysis;1991-05
4 Ran Ruicheng, Pei Weiwei, Jia Xinru, Shen Ji ( Department of Chemistry, Peking University, Beijing );A POLYMER-SUPPORTED LEWIS ACID CATALYST, POLYSTYRENE-ZIRCONIUM TETRACHLORIDE COMPLEX[J];Journal of Molecular Catalysis;1988-02
5 Ran Ruicheng and Jiang Shuojian (Dep. of Chem., Peking University, Beijing)Shen Ji (Dep. of Chem., Beijing Chemical Fiber College, Beijing);A Lewis Acid Catalyst Supported by Polymer:Polystyrene-Stannic Chloride Complex——Preparation and Application in Organic Synthesis[J];Chemical Research In Chinese Universities;1986-03
6 Ran Ruicheng, Pei Weiwei, Jia Xinru, Shen Ji and Jiang Shuojian (Department of Chemistry, Peking University, Beijing);A Lewis Acid Catalyst Supported by Polymer. Polystyrene AlCl_3/TiCl_4 Complex[J];Chemical Research In Chinese Universities;1986-07
7 Fan Ruicheng, Jia Xinru, Wu Xianghong, Pei Weiwei and Jiang Shuojian (Department of Chemistry, Peking University, Beijing);A Lewis Acid Catalyst Supported by Polymer——Polystyrene-AICI_3/SnCI_4 Dibasic Metal Chloride Complex[J];Chemical Research In Chinese Universities;1987-12
8 LIU Fu-An , TIAN Ming-Yuan, LI YAO-Xian, HUANG Hua-Min (Department of Chemistry, Jilin University, Changchun, 130023);A Polymer Lewis Acid Catalyst——Cation Exchange Resin SnCl_4 Complex[J];Chemical Research In Chinese Universities;1993-08
9 RAN Ruicheng and JIANG Shuojian (Department of Chemistry, Peking University, Beijing);A NEW POLYMER SUPPORTED CATALYST——A Complex of Polystyrene-Titanium Tetrachloride[J];;1985-05
10 RAN Ruicheng, PEI Weiwei, JIA Xinru, SHEN Ji and JIANG Shuojian(Department of Chemistry, Peking University, Beijing);POLYMER-SUPPORTED LEWIS ACID CATALYST ——POLYSTYRENE-ANTIMONY PENTACHLORIDE COMPLEX[J];;1986-05
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