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《Petrochemical Technology》 2003-04
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Atom Transfer Radical Polymerization of Octadecyl Acrylate

GU Yu-rong, ZHU Xiu-lin, CHENG Zhen-ping, CHEN Jian-ying, LU Jian-mei(Department of Chemistry and Chemical Engineering, Suzhou University, Suzhou Jiangsu 215006,China)  
?Atom Transfer Radical Polymerization (ATRP) of octadecyl acrylate (ODA) had been conducted successfully using iron dichloride tetrahydrate/triphenylphosphine (FeCl2·4H2O/ PPh3)as catalyst,ethyl-2-bromo propionate(EBP) as initiator,and toluene as solvent.Effect of polymerization temperature and amount of catalyst on rate of ODA ATRP was investigated.Relative molecular mass distribution of PODA was also discussed.Chain-extended reaction and analysis of polymer end group proved that ODA ATRP had the characteristics of "living"/ controllable radical polymerization.When n(ODA)/n(EBP)/n(FeCl2·4H2O)/n(PPh3) was 100/1/1/2,the apparent propogation rate constant (kappp) was 402×10-5 s-1 at 120 ℃,328×10-5 s-1 at 100 ℃,and 165×10-5 s-1 at 80 ℃,respectively.Equilibrium enthalpy of ODA ATRP was calculated.
【Fund】: 国家自然科学基金(20176033);; 江苏省自然科学基金(BK2001141)资助项目。
【CateGory Index】: TQ316.3
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Chinese Journal Full-text Database 4 Hits
1 LIU Chang-chun~(1,2),LI Deng-hao~3(1.Nanjing University of Technology,Nanjing 210009,China;2.Jiangsu Food Science College,Huai'an 223003,China;3.Huaiyin College of Technology,Huai'an 223001,China);SYNTHESIS AND DISPERSION OF HYPERDISPERSANT PS-b-PAA BY RAFT[J];Journal of Beijing Technology and Business University(Natural Science Edition);2006-01
2 WANG Kejun, LIU Fang, HU Shanling ( College of Chemistry and Life Science, Gannan Normal University, Ganzhou 341000; College of Materials Science and Engineering,South China University of Technology, Guangzhou 510640);Microwave-assisted Synthesis of Octadecyl Acrylate Polyester[J];Materials Review;2007-S2
3 YANG Bin-bin1,QING Feng-ling1,2,MENG Wei-dong1,21 Key Laboratory of Science & Technology of Eco-Textile,Ministry of Education,Donghua University,Shanghai 201620,China2 Key Laboratory of Organofluorine Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China;Synthesis of Novel Fluorinated Acrylate Co-polymers and Their Application on Cotton Fabrics[J];东华大学学报(英文版);2010-01
4 LIU Chang-chun1,2(1、Nanjing University of Technology,Nanjing 210009,China;2、Jiangsu Food Science College,Huai'an 223003,China);Synthesis and Dispersion of Hyperdispersant Poly(styrene-b-acrylic acid) by RAFT[J];Zhejiang Chemical Industry;2005-12
Chinese Journal Full-text Database 10 Hits
1 ZHAO Yong-bin 1 SHI Yan 1 WEI Jie 2 FU Zhifeng 1* YANG Wan-tai 1 (1. The Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry of Education; 2. College of Information Science and Technology, Beijing University of Chemical Technology, Beijing 100029, China);Synthesis of highly branched polystyrene via atom transfer radical polymerization with p-styrenesulfonyl chloride as an initiator[J];Journal of Beijing University of Chemical Technology;2003-04
2 (College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029);Atom transfer radical polymerization of styrene and synthesis of its block copolymer[J];JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY;1998-02
3 Shi YanFu ZhifengLi BingyiJiao Shuke (College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029);Effect of temperature on the atom transfer radicalpolymerization of styrene[J];JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY;1999-02
4 WANG Ke-jun~(1,2),LIU Fang~1,JIA De-min~1(1.College of Materials Science and Engineering,South China University of Technology,Guangzhou 510641,China;2.Dept.of Chemistry and Life Science,Gannan Teacher's College,Ganzhou of Jiangxi Prov.341000,China);SYNTHESIS OF 191~# UNSATURATED POLYESTER BY MICROWAVE IRRADIATION[J];Fiber Reinforced Plastics/Composites;2007-01
5 SHEN Yinghua,XIE Long,WANG Zhizhong(College of Chemical Engineering and Technology,Taiyuan University of Technology,Taiyuan030024,China);Recent development on kinetics of inverse microemulsion polymerization[J];China Surfactant Detergent & Cosmetics;2003-05
6 ZHU Wei~1,WANG Shao-jun~1,ZHAO Yu-jun~2,YANG Wan~1,QU Feng-zuo~1(1.Dalian Institute of Light Industry Chemistry Department,Dalian 116034,China;2.Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,China);Preparation of nanoparticles in W/O reverse microemulsion and its application[J];China Surfactant Detergent & Cosmetics;2005-06
7 YANG Huaming HUANG Chenghuan SONG Xiaolan JIN Shengming QIU Guanzhou (Department of Inorganic Materials,School of Resources Processing and Bioengineering, Central South University,Changsha 410083,China);Research Progress in Microwave Synthesis of Inorganic Nanophase Materials[J];Materials Review;2003-11
8 ZHONG Fachun, HE Jiangping, WANG Xiaochuan, ZHAO Xiaodong, ZHANG Xiaohua(Insitute of Chemical Materials, Chinese Academy of Engineering and Physics, Mianyang 621900);Structure and Properties of Epoxy Foams Prepared by Microwave Irradiation[J];Materials Review;2006-08
9 ZHONG Shengliang1, ZHANG Maisheng2, HUANG Yixiang1(1 College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022;2 School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou 510275);Semiwork Synthesis of Zeolite 4A by Microwave[J];Materials Review;2007-01
10 Ding Wei(Dept of Petrochemical Engineering, Daqing Petroleum Institute, Anda, Heilongjiang, China, 151400);Synthysis of Octadecyl Acrylate[J];JOURNAL OF DAQING PETROLEUM INSTITUTE;1998-02
【Secondary References】
Chinese Journal Full-text Database 5 Hits
1 Li Zhen1,2*,Li Wenxiu1,2(1.School of Materials Science and Chemical Engineering,Anhui University of Architecture,Hefei 230022;2.Anhui Key Laboratory of Advanced Building Materials,Anhui University of Architecture,Hefei 230022,China);Synthesis and Properties of Fluorinated Acrylate Co-polymers[J];Guangdong Chemical Industry;2012-09
2 YANG Li-peng1,CUI Jian-wei1,LI Jin-hua2,CAO Ming-rang1(1.College of Mechanical Engineering,Taiyuan University of Technologe,Taiyuan 030024,China;2.Sima Coal Industry Co.,Ltd,Lu'an Group,Changzhi 047105,China);Experiment Research on Process of Deep Hole Drilling by EDM with Tape Water Dielectric Fluid and Dispersant Dielectric Fluid[J];Mechanical Engineering & Automation;2010-04
3 ;Polymeric Dispersants for Waterborne Coatings[J];Coatings Technology & Abstracts;2009-07
4 ;Application of Controlled-living Polymerizations in the Preparation of Wetting and Dispersing Agents for Coatings[J];Coatings Technology & Abstracts;2011-01
5 Chen Jian-lian,Li Zhong-hua(College of Chemistry,Huazhong Normal University,Wuhan 430079);Research Progress on Emulsions of Acrylic Resin and Nanometer SiO_2[J];Silicone Material;2009-06
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