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《Petrochemical Technology》 2004-04
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Determination and Study on Solubility of Methane in Cyclohexane-Ethanol and Benzene-Ethanol under High Pressure

Xia Shuqian , Ma Peisheng , Guo Yugao , Hua Chao (School of Chemical Engineering of Tianjin University, Tianj in 300072, China)  
Experimental investigation was conducted for determining solubility of methane in cyclohexane -ethanol and benzene -ethanol at temperatures of 15,30,45 ℃ under different pressures in a special self-established apparatus, for high pressure gas solubility determination. The measured solubility data of methane were calculated by PRSV equation of state with three different mixing rules. Diversified calculation accuracy rusulted from three mixing rules. Calculation accuracy can be improved by the improving mixing rules. Aalto -Keskinen model and Yen - Woods - Aalto - Keskinen model advanced in this paper were used to estimate experimental molar volume data of liquids under high pressure. Both estimation results were satisfactory.
【Fund】: 中国石化股份有限公司基金项目(X502009)。
【CateGory Index】: O645
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