Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Petrochemical Technology》 2004-05
Add to Favorite Get Latest Update

Determination of Reactivity Ratio of N-Maleoyl-L -Alanine and Styrene in Microemulsion Copolymarization

Wang Guoxiang, Liu Pengsheng (College of Chemistry,Xiangtan University,Xiangtan Hunan 411105,China; College of Chemistry of Hunan Institute of Technology, Yueyang Hunan 414000,China)  
N-maleoyl-L -alanine (AMI) and styrene(St) copolymerized in oil-water microemulsion at 60 ℃ ,using potassium persulfate(KPS) as initiator,sodium dodecyl sulfate(SDS) as anionic emulsifier and pentanol as consurf actant. The obtained polymer was optically active. Mayo-Lewis equation, Kelen-Tudos and Yezrielev -Brokhina-Roskin methods were used for calculating monomer reactivity ratios. From relevant feed monomer composition and copolymer composition,monomer reactivity mole ratios r1 = 0.050(AMI) and r2 - 0.113(St) were obtained, from which Alfrey-Price Q,e values were determined as follows: r1 =0.050 and r2 = 0.113,Q1 = 1.43 and e1 = 1.48,respectively,inferring an alternate copolymerization reaction.
【Fund】: 湖南省自然科学基金资助项目(01JJY3011)。
【CateGory Index】: O631
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
Chinese Journal Full-text Database 1 Hits
1 CHEN Ping,HUANG Yi-ping,RU Ling,CHEN Lei,ZHANG Yan(School of Chemistry and Chemical Engineering,Anhui University,Hefei 230039,China);Determination of Fluor-acrylate terpolymer system Reactivity-ratios[J];Journal of Anhui University(Natural Sciences);2008-03
Chinese Journal Full-text Database 1 Hits
1 PengYuxing;LiuJialin;DaiHansong and Cun Linfeng(Chengdu Institute of Organic Chemistry,Chengdu 610041);Determination of Reactivity Ratio of the Cationic Copolymerization of 1,3-Pentadiene-Styrene[J];PETROCHEMICAL TECHNOLOGY;1995-12
Chinese Journal Full-text Database 10 Hits
1 Ding Liguang (Guangxi Institute of Technology, Liuzhou 545006);RESEARCH OF COUNTERMEASURES AGAINST DIFFICULTY MACHINING ENGINEERING PLASTICS[J];Engineering Plastics Application;2002-04
2 Fang Jin, He Zikai (Faculty of Materials and Metallurgical Engineering, Kunming Universtiy of Science and Technology, Kunming 650093, China);MATERIAL CHOOSING AND MACHINING OF HIGH ACCURACY PLASTIC PARTS[J];Engineering Plastics Application;2006-01
3 Yang Xiaofeng,Li Qiaolin,Chen Zhiping,Han Hongli(Department of Chemistry,School of Science,North University of China,Taiyuan 030051,China);PREPARATION AND CHARACTERIZATION OF NOVEL HALOGEN-FREE FIRE RETARDANT COPOLYAMIDE 66[J];Engineering Plastics Application;2008-09
4 Liu Weitao1,Wang Lianshi1,Cai Tongmin2,Zhang Anqiang1,Zeng Xiangbin2(1.School of Polymer Materials Science and Engineering,South China University of Technology,Guangzhou 510640,China;2.Guangzhou Kingfa Science and Technology Co.Ltd.,Guangzhou 510520,China);STUDY ON SYNTHESIS OF EPDM-g-MAN AND IMPACT TOUGHNESS OF AEMS[J];Engineering Plastics Application;2009-03
5 LI Chen1,WANG Juan1,TIAN Zhao-yong2 (1.The Chemistry Department of Huainan Normal University,Huainan 232001,China; 2.Department of Chemistry,Shantou University,Shantou 515063,China);The Emulsion Polymerization of Methyl Methacrylate[J];Anhui Chemical Industry;2008-04
6 WANG Feng(School of materials and Chemical Engineering,Anhui Institute of Architectural and Industry,Hefei 230022);Synthesis of the phenol-formaldehyde copolymers containing cardo ring[J];Journal of Anhui Institute of Architecture & Industry(Natural Science);2010-06
7 PU Xia et al (College of Chemical and Chemical-Engineering,Zhongkai university of agriculture and engineering,Guangzhou,Guangdong 510225);Study on the Kinetics of the Soap-free Emulsion Copolymerization of the Tung Oil Derivant and Styrene[J];Journal of Anhui Agricultural Sciences;2010-23
8 WEI Zhi-zhen, HOU Min, LIAO Qing (Department of Materials Engineering, Beijing Institute of Clothing Technology, Beijing 100029, China);The Preparation and Property Test of Low-molecular Weight Chitosan[J];Journal of Beijing Institute of Clothing;2005-02
9 DONG Jun,GAN Xiao-xian(Xi′an Modern Chemistry Research Institute,Xi′an 710065,China);Synthesis and Characterization of 3-Bromonomethyl3-Methyloxetane Homopolymer[J];Chinese Journal of Explosives & Propellants;2008-02
10 ZHANG QingLei LUO LingLing LIU YaKang LI QiFang(College of Materials Science and Engineering,Beijing University of Chemical Technology,Beijing 100029,China);Effect of the amount of pentane on the properties of expanded polystyrene[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2010-05
China Proceedings of conference Full-text Database 9 Hits
1 LIANG Zhi-jie National Key Laboratory for Remanufacturing,Beijing 100072; FENG Bin HUANG Qi Faculty of Materials Science and Engineering,Academy of Armored Force Engineering,Beijing 100072;Advance of the research on the anti-aging coat for military rubber equipment[A];[C];2008
2 ;Synthesis and Construction Application for Passenger Dedicated Line of the Polycarboxylate Superplasticizer[A];[C];2009
3 Xu Bin Xiu Huimin Zhong Yiling Lou Zheng (Hangzhou Zhengguang Resin CO.,LTD,Hangzhou 311106,China);Studies on the Second Suspention Polymerization and Application of Ion Exchange Resins[A];[C];2007
4 Xuri Li, Liqun Zhao, Feng Yang, Zhi Yu ShenYang Institute of Chemical Technology, Shenyang 110042;The necessity and practice of Polymer professional experimental teaching reform[A];[C];2008
5 LIANG Chao,LU Jian-pin,SHAO Li-bin (HangZhou Research Institute of Chemical Technology HangZhou 310014,China);Praparation and Application of Surface Sizing Agent PAS and PMS[A];[C];2001
6 Tan Yang Qiu Huayu (Shandong Key Laboratory of Pulp and Paper Engineering, Shandong Institute of Light Industry,Jinan,250100);THE STABILITY OF THE CATIONIC GELATIN INVERSE EMULSION[A];[C];2005
7 TAN Yang~1 QIU Hua-yu~(1,2) (1.Shandong Key Laboratory of Pulp and Paper Engineering,Shandong Institute of Light Industry, Jinan 250100;2.Key Laboratory of Organosilicon Chemistry and Material Technology,Hangzhou Teachers College,Hangzhou 310012.);Graft Copolymerization onto Gelatin with AM-DMC in Inverse Emulsion[A];[C];2005
8 Zhang Xiu - qing~1 Qiu Hua - yu~(1,2) (1.Shandong Key Lab of Pulp and Paper Engineering,Shandong Institute of Light Industry, Ji'nan250100,China.2.Key Lab of OrganosiliconChemistry and Material Technology of Ministry of Education,Hangzhou Teachers College,Hangzhou 310012,China);The Properties and Applications of Cationic Polymer Emulsion[A];[C];2007
9 Yan Ji-peng Wu Yu-ying Yang Jing-wen (College of Material Sciences and Technology,Beijing Forestry University,Beijing,100083);Study on characterization and application of Graft Acrylamide onto Chitosan[A];[C];2007
Chinese Journal Full-text Database 4 Hits
1 Li Lifeng , Dai Lixing , Wang Chaosheng (Collage of Material Science and Engineering, China Textile University,Shanghai,200051);Method to Measure the Reactivity Radio(RR) of AN/VAC/SMAS[J];;1999-05
2 Huang Yue-wen et al / Guangzhou Chemistry Co. Ltd., Chinese Academy of Sciences;Study of Acrylate Coatings Modified by Organic Fluorinated Compounds[J];Chemical Materials For Construction;2005-02
3 CHEN Yan-jun,WANG Yi-feng,CHEN Pei-zhi;Study on Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate[J];Paint & Coatings Industry;2005-09
4 LI Xiao-rui, XIN Hua (Chemistry and Chemical Engineering College, Shaanxi University of Science & Technology, Xianyang,712081 China);Preparation and Application of Fluoroacrylate Copolymer Emulsion as Surface Sizing Agent[J];Paper and Paper Making;2005-04
【Secondary References】
Chinese Journal Full-text Database 1 Hits
1 LIU Jin-hong,CHEN Ping,HUANG Yi-ping*(College of Chemistry and Chemical Engineering,the Key Laboratory of Environment-friendlyPolymer of Anhui Province,Anhui University,Hefei 230039,China);The synthesis and characterization of fluorinated acrylate copolymer latex with core-shell structure[J];Journal of Anhui University(Natural Sciences Edition);2010-03
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved