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《Petrochemical Technology》 2004-09
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Synthesis and Characterization of Poly(Arylene Acetylene) Containing Dimethylsilylene

Yan Hao , Qi Huimin , Huang Farong (Key Laboratory for Ultrafme Materials of Ministry of Education,School of Materials Science and Engineering,East China University of Science and Technology,Shanghai 200237,China)  
A novel kind of resins, phenyl acetylene terminated poly(dimethy silylene ethynylene phenylene ethynylene)s, were prepared by condensation of dimethyldichlorosilane and organic magnesium Grignard reagents. Relative molecular mass and viscosity of these resins correlated to amount of phenyl acetylene used as anending reagent. A variety of resins with different relative molecular mass were obtained by the addition of different phenyl acetylene(PA)/diethynylbenzene(DEB) mole ratio. The obtained resins were soluble in most common solvents.The resins were characterized by means of FTIR,1H NMR,GPC,DSC,and TGA.The resins were cured with low exothermal heat. The cured resins decomposed at temperature of higher than 460 ℃and the decomposition of residue was higher than 80 % at 800 ℃ , which indicated that the resins were high in heat resistance.
【Fund】: 国家863项目(2002AA305205) 上海市重点学科建设资助项目
【CateGory Index】: TQ320
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