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《Journal of Petrochemical Universities》 2007-02
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Adsorption of Nickel From Aqueous Solution by Humin

LIU Zhi-rong1,2,ZHOU Li-min1,WEI Peng1,PETER Warwick2,NICK Evans2(1.Department of Applied Chemistry,East China Institute of Technology,Fuzhou Jiangxi 344000,P.R.China;2.Department of Chemistry,Loughborough University,Leicestershire LE11 3TU,UK)Received 6 December 2006;revised 19 March 2007;accepted 1 April 2007  
The experiment tested that humin can enrich Ni2+ by means of liquid scintillation counting.The procedures were effected by pH value,amount of humin and initial aqueous concentration of nickel.There may be exist reversible transitions among humic acid,fulvic acid and humin for variation of ultra-violet of peat or humin into nickel solution.Freundlich equation can describe the adsorption reaction of Ni2+ onto humin excellently.Nickel-humin-dual-complexation mode play an primary part in the adsorption owing to Freundlich adsorption exponent 0.684 4.Freundlich adsorption exponent(0.638 2,0.684 4)and common logarithm of adsorption index(1.693 2,1.711 5)for peat and humin are almost equal.They indicate that humin may control the binding ability of Ni2+ onto peat.The results show that humin can act as a potential material for permeable reactive barrier.
【Fund】: 国家留学基金委资助(22307S05);; 东华理工学院博士基金(DHB0504);; 东华理工学院核资源与环境工程技术中心开放测试基金(051104)
【CateGory Index】: TQ028.15
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