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《PAINT & COATINGS INDUSTRY》 1997-05
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FACTORS INFLUENCING THE EMULSION RESIN PARTICLE SIZE AND ITS DISTRIBUTION OF MMA-BA-DMAEMA COPOLYMER

Yu Zhangqing; Li Bogeng; Pan Zuren  
A MMA -BA-DMAEMA copolymer emulsion has been prepared with batch or semi-continuous emulsion polymerization process. Influence of compound emulsifier's ratio and amount, reaction temperature, polymerization types and functional monomer amount on the emulsion resin particle size and its distribution were studied. It has been shown that increasing of the percentage of anion in emulsifier and the amount of emulsifier, and reducing of the amount of functional monomers and reaction temperature will lead to a finer resin particle size and wider distribution. Non-seeding semi-continuous emulsion polymerization will lead to a larger particle size and wider distribution than batch reaction and seeding semi -conitinuous polymerization at the same monomer droping rate. The droping rate in a proper range have no influence on the emulsion resin particle size and its distribution. Only if the droping rate is lower than that lead to a" hungry status" of the system, the particle size will become larger.
【CateGory Index】: TQ630.1
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