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《Journal of Wuhan University of Technology》 2002-04
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Study on Peseudo-ternary System of FeSO_4 Solution/Surfactant/Oil

Su Liangbi Guan Jianguo Sun Tao Postgraduate, State Key Lab. of Advanced Technology for Materials Synthesis and Processing, WUT, Wuhan 430070,China.  
The conductivity ( σ ) of the pseudo ternary system FeSO 4 aqueous solution/SDS + isopentanol/xylene was tested as functions of such composition parameters as P (concentration of SDS), K m (cosurfactant surfactant mass ratio), R (water SDS molar ratio); and the inverse microemulsion phase diagrams were established in various conditions. The influencing factors such as K m, concentration and pH of FeSO 4 aqueous solution, the temperature of experiment, addition of methyl methacrylate on inverse microemulsion phase diagram for the pseudo ternary system were studied. The results indicated that during the process of forming an inverse microemulsion, σ of the pseudo ternary system increased with both decreasing Km and increasing P. σ showed obvious threshold effect with increasing R , while the critical value is 4, which is far less than 12 or 15 reported in the literature.
【Fund】: 国家自然科学基金项目 (2 990 4 0 0 5 )
【CateGory Index】: O648
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