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《Acta Physico-chimica Sinica》 2003-04
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Photocatalytic Production of Hydrogen with Degrading Pollutants and Characterization by in situ Infrared Spectroscopy

Li Yue Xiang1,2 Lu Gong Xuan1 Li Shu Ben1 Dong Lu Hu1(1State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences,Lanzhou 730000; 2Department of Chemistry, Nanchang University,Nanchang 330047)  
The photocatalytic generation of hydrogen from water using single and binary component pollutants as electron donors in aqueous Pt/TiO2 suspension has been investigated. The adsorption of these donors on TiO2 was also monitored by in situ attenuated total reflection infrared spectroscopy(ATR IR). In the single component system(formaldehyde, formic acid and oxalic acid), the efficiencies of electron donors follow the order:H2C2O4 HCOOH HCHO. The order is consistent with the adsorption strength of the electron donors on TiO2 determined by ATR IR, which suggests that the hydrogen evolution efficiency is dependent on the strength of surface interaction. In the binary mixture systems consisting of oxalic acid and formic acid, the overall kinetics of hydrogen evolution and decomposition of pollutants are dependent on their adsorption strengths on TiO2 and their concentration levels as well. The result can be explained by their competitive adsorption on TiO2. ATR IR characterization confirmed illustratively the above explanation.
【Fund】: 973项目(G20000264);; 江西省自然科学基金资助~~
【CateGory Index】: O643.3
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【References】
Chinese Journal Full-text Database 10 Hits
1 LI Huiquan, LI Yuexiang *, ZHOU Xinmu, PENG Shaoqin(Department of Chemistry, Nanchang University, Nanchang 330047, Jiangxi, China);Preparation and Properties of Sm_2O_3-Doped TiO_2 Photocatalyst[J];Chinese Journal of Catalysis;2004-10
2 LI Hui-quan~1, LI Yue-xiang~(1,2)), ZHOU Xin-mu~1, PENG Shao-qin~1, LU Gong-xuan~2, LI Shu-ben~2(1. Chemistry Department of Nanchang University, Nanchang 330047 China; ute of Chemical Physics, The Chinese Academy of Sciences, Lanzhou 730000, China);Preparation and Properties of La_2O_3 doping TiO_2 Photocatalyst[J];Journal of Molecular Catalysis;2004-04
3 YIN Zhong-huan1, LI Yue-xiang1, PENG Shao-qin1, LU Gong-xuan2, LI Shu-ben2 (1. Department of Chemistry, Nanchang University, Nanchang, 330047, China; 2. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, 730000, China);Photocatalytic Hydrogen Generation in the Presence of Ethanolamines over Pt/TiO_2[J];Journal of Molecular Catalysis;2007-02
4 LI Hui-quan~1,CHEN Wei-fan~2,MA Ji-long~1,CUI Yu-min~1(1.Chemistry Department of Fuyang Normal College,Fuyang 236041,Anhui,P.R.China;2.National Special Superfine Powder Engineering Research Center,Nanjing University of Science and Technology,Nanjing 210094,Jiangsu,P.R.China);Preparation and Properties of Yb Doped TiO_2 Photocatalysts[J];Photographic Science and Photochemistry;2005-06
5 LU Xin-ning,ZHANG Ning,SONG Wei-jun,QI Ping;Preparing and Photocatalysis Performance Study on La_2O_3-TiO_2 Nanotubes[J];Nonferrous Metals(Extractive Metallurgy);2007-01
6 Li Huiquan,Chen Weifan,Cui Yumin,Ma Jilong (Chemistry Department of Fuyang Normal College,Fuyang Anhui 236041,China;National Special Superfine Powder Engineering Research Center,Nanjing University of Science and Technology,Nanjing Jiangsu 210094,China);Preparation and Properties of La_2O_3/TiO_2/SO_4~(2-) Nano-Photocatalysts[J];Petrochemical Technology;2006-04
7 ZHANG Yao-Jun~1 ZHANG,Li~2 (1.School of Material Science and Engineering,Xi'an University of Architecture and Technology,Xi'an 710055,China;2.School of Chemistry and Chemical Engineering,Xi'an Shiyou University,Xi'an 710065,China);Synthesis of Composite Material CdS/Al-HMS and Hydrogen Production by Photocatalytic Pollutant Degradation under Visible Light Irradiation[J];Journal of Inorganic Materials;2008-01
8 Li Yue Xiang1,2 Wang Tian Hui1 Peng Shao Qin1 LüGong Xuan2 Li Shu Ben2 (1Department of Chemistry, Nanchang University, Nanchang 330047; 2State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000);Synergistic Effect of Eu~(3+)and Si~(4+)Co doping on Photocatalytic Activity of Titanium Dioxide[J];Acta Physico-chimica Sinica;2004-12
9 LIU Fu-Sheng1,2 JI Ren2 WU Min1 SUN Yue-Ming1,(1School of Chemistry and Chemical Engineering,Southeast University,Nanjing 210096,P.R.China;2Department of Chemistry and Materials Science,Nanjing Forestry University,Nanjing 210037,P.R.China);Hydrogen Production from Water Splitting Using Perylene Dye-Sensitized Pt/TiO_2 Photocatalyst[J];Acta Physico-Chimica Sinica;2007-12
10 ZHENG Xian-jun,JIANG Qiao-juan,WEI Li-fang,FU Yong,WEI Ming-bao(Henan Provincial Key Lab.of Surface and Interface Sci.,Zhengzhou Univ.of Light Ind.,Zhengzhou 450002,China);Progress of photocatalytic hydrogen evolution from water by modified nano-TiO_2[J];Journal of Zhengzhou University of Light Industry(Natural Science);2008-04
China Proceedings of conference Full-text Database 1 Hits
1 Guan Xiurong~(1,2) Shao Zhongca~(2*) Tian Yanwen~1 (1.School of Materials and Metallurgy,Northeast University,Shenyang 110004,China;2.School of Environmental and Chemical Engineering,Shenyang Ligong University,Shenyang 110168,China);Preparing TiO_2 with Doping Rare Earth and Study of Their Photocatalysed Performance[A];[C];2008
【Citations】
Chinese Journal Full-text Database 2 Hits
1 LI Yuexiang, L Gongxuan, LI Shuben (State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, The Chinese Academy of Sciences, Lanzhou 730000, China);Photocatalytic Hydrogen Generation over Pt-TiO_2 with Oxalic Acid as Electron Donor[J];Chinese Journal of Catalysis;2001-02
2 LI Yue\|xiang, LU Gong\|xuan\+\{1)\}, LI Shu\|ben, YU Fei (State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, The Chinese Academy of Sciences, Lanzhou 730000, China);Photocatalytic Hydrogen Generation by Pollutant Formaldehyde as Electron Donor over Pt/TiO_2[J];Journal of Molecular Catalysis (China);2002-04
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Wang Baolu Ma Yuhua (A Graduate in our College) (Research Office on Higher Education);Determination of Micro Lead in Calcium Stearate[J];Journal of Beijing Institufe of Petrochemical Technology;1993-02
2 Yang Shuijin(Dept. Chem.,Hubei Normal Univ.,Huangshi,Huibei 435002);PHOTOCATALYTIC DEGRADATION OF WASTE WATER FROM ACTIVE CHLORINE DYE[J];JOURNAL OF BAOJI COLLEGE OF ARTS AND SCIENCE(NATURAL SCIENCE EDITION);1997-01
3 SHI Yueping, YANG Zhuhong, FENG Xin, ZHENG Zhong, LU Xiaohua *(College of Chemical Engineering, Nanjing University of Technology, Nanjing 210009, Jiangsu, China);Study on Photocatalytic Degradation of CHCl_3 over Pt/TiO_2 Fiber Catalyst[J];Chinese Journal of Catalysis;2003-09
4 SANG Lixia~(1*),LI Qunwei~1,MA Chongfang~1,XU Lixian~1,SUN Jihong~2,DAI Hongxing~2,HE Hong~2(1 Key Laboratory of Enhanced Heat Transfer and Energy Conservation,Ministry of Education,and Key Laboratory of Heat Transfer and Energy Conversion,Beijing Education Commission,Beijing University of Technology,Beijing 100022,China;2 Department of Chemistry and Chemical Engineering,College of Energy and Environmental Engineering,Beijing University of Technology,Beijing 100022,China);Photocatalytic Hydrogen Evolution from Water over Layered K-Fe-Ti Metal Oxides[J];Chinese Journal of Catalysis;2006-10
5 YANG Yahui CHEN Qiyuan YIN Zhoulan LI Jie (College of Chemistry and Chemical Engineering,Central South University,Changsha 410083);Study on the Photocatalytic Activity of K_4Nb_6O_(17) Doped with Ni~(2+),Co~(3+),Mn~(4+) and Cu~(2+)[J];Materials Review;2005-05
6 XI Lihe,ZHU Zhongqi,ZHANG Jin,JIANG Haijun,LIU Qingju(Department of Material Science and Engineering,Yunnan University, Kunming 650091);The Purification of Formaldehyde in the Indoor Air[J];Materials Review;2007-04
7 Zhang Qingsong Wu Huihuang * (Dept.of Chem.,State Key Lab.for Phys.Chem.of the Solid surfaces, Xiamen Univ.,Xiamen 361005);Electro oxidation of Phenol on SnO_2/Ti Electrodes Prepared by Thermal Oxidation[J];ELECTROCHEMISTRY;1999-04
8 Shi Ji-min and Shi Songnian(Beijing Center of Physieal andChemical Analysis,Beijing 100081);Rapid Determination of Iodide,Thiocyanate,Thio- sulfate by Eluant-Suppressed Ion Chromatography[J];ANALYTICAL LABORATORY;1994-01
9 Gao Qi(Basic Courses Department,HenanAgricuItural University,Zhengzhou450002);Study on Determination Method forCOD_(cr) Content in Water Samples of the En-vironment by Microwave-Heating Digestion[J];ANALYTICAL LABORATORY;1995-06
10 LI Yue-xiang, LU Gong-xuan, LI Shu-ben(State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, The Chinese Academy of Sciences, Lanzhou 730000, China);Photocatalytic Reduction Rhodamine B over Pt-TiO_2[J];Journal of Molecular Catalysis (China);2001-04
China Proceedings of conference Full-text Database 1 Hits
1 Wu Yu,Chai Liyuan,Shu Yude (School of Metallurgical Science and Engineering,Central South University,Changsha 410083);Low-concentration SO_2 flue gas absorption in sodium sulfide[A];[C];2010
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 LUAN Ye-mei, AN Mao-zhong (Dept. of Applied Chemistry, Harbing Institute of Technology, Harbing 150001, CHN);Properties and Preparation of Semiconductor Nanomaterials[J];Semiconductor Optoelectronics;2003-06
2 LI Weihua\ HAO Yanzhong\ WANG Yanqin\ QIAO Xuebing YANG Maizhi\ CAI Shengmin (College of Chemistry and Molecular Engineering,Peking University,Beijing,100871);A Photoelectrochemistry Study of Nanocrystalline ZnO Nanoporous Film Electrodes Co sensitized by CdS/Ru(Ⅱ) Complex[J];ACTA SCICENTIARUM NATURALUM UNIVERSITIS PEKINESIS;1999-04
3 Sun Fuxia 1, Wu Ming 1, Wang Hong 2, Wang Fudong 1, Gu Wanzhen 1 (1 Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023; 2 Department of Chemistry, Dalian University, Dalian 116622);KINETIC STUDIES ON PHOTOCATALYTIC DEGRADATION OF PHENOL BY NANOMATERIAL TITANIUM DIOXIDE[J];CHINESE JOURNAL OF CATALYSIS;1999-03
4 Liu Ping, Lin Huaxiang, Fu Xianzhi (Research Institute of Photocatalysis, Fuzhou University, Fuzhou 350002) Meng Chun (Department of Bioengineering, Fuzhou University, Fuzhou 350002);PREPARATION OF THE DOPED TiO 2 FILM PHOTOCATALYST AND ITS BACTERICIDAL MECHANISM[J];CHINESE JOURNAL OF CATALYSIS;1999-03
5 Zhang Feng, Li Qinglin (Lanzhou Institute of Chemical Physics, The Chinese Academy of Sciences, Lanzhou 730000) Yang Jianjun, Zhang Zhijun (Lubrication and Functional Material Key Laboratory, Henan University, Kaifeng 475001);STUDY OF VISIBLE SPECTRAL SENSITIZATION OF NANOCRYSTALLINE TiO 2 PHOTOCATALYST[J];CHINESE JOURNAL OF CATALYSIS;1999-03
6 Zhang Tianyong, Li Xiangzhong, Zhao Jincai (Institute of Photographic Chemistry, The Chinese Academy of Sciences, Beijing 100101);INVESTIGATION ON PHOTOCATALYTIC DEGRADATION OF DYE WASTEWATER WITH TITANIA PRODUCED IN CHINA[J];CHINESE JOURNAL OF CATALYSIS;1999-03
7 Li Yuexiang 1, Peng Shaoqin 1, Dai Chao 1, Fritz Wasgestian 2 (1 Department of Chemistry, Nanchang University, Nanchang 330047; 2 Institute of Inorganic Chemistry, University of Cologne, D 50939 Cologne, Germany);PHOTOCATALYTIC REDUCTION OF NITRATE TO AMMONIA ON TITANIA IN THE PRESENCE OF FORMIC ACID[J];CHINESE JOURNAL OF CATALYSIS;1999-03
8 LI Gonghu, MA Hulan, AN Weizhu (Chengdu Institute of Organic Chemistry, The Chinese Academy of Sciences, Chengdu 610041, China);Gas Phase Photocatalytic Oxidation of Trichloroethylene on Nanoscale Titanium Dioxide[J];CHINESE JOURNAL OF CATALYSIS;2000-04
9 WU Hejin, WU Ming, XIE Maosong, LIU Hong, YANG Min, SUN Fuxia, DU Hongzhang (Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, China);The Enhanced Electro assisted Photocatalytic Degradation of Organic Water Contaminants[J];Chinese Journal of Catalysis;2000-05
10 GAO Yuan, XU Anwu *, ZHU Jingyan, LIU Hanqin (Department of Chemistry, Zhongshan University, Guangzhou 510275, China);Study on Photocatalytic Oxidation of Nitrite over RE/TiO_2 Photocatalysts[J];Chinese Journal of Catalysis;2001-01
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 XIA Feng-li et al (College of Chemistry and Chemical Engineering,Lanzhou University,Lanzhou,Gansu 730000);Influencing Factors for Degradation of Methyl Orange by Sm~(3+) Doping TiO_2 Loaded Photocatalyst[J];Journal of Anhui Agricultural Sciences;2010-11
2 Wang Jisena,Feng Zhongbina,Sun Jinquanb,Jia Mingjiana,Song Zhenleia (a. College of Mechanical Engineering;b. College of Materials Engineering,Shandong University of Science and Technology,Qingdao 266510,China);Photocatalytic Mechanism of Nano-TiO_2 and Analysis on Factors Influencing Its Photocatalytic Activity[J];Micronanoelectronic Technology;2008-01
3 LI Huiquan, LI Yuexiang *, ZHOU Xinmu, PENG Shaoqin(Department of Chemistry, Nanchang University, Nanchang 330047, Jiangxi, China);Preparation and Properties of Sm_2O_3-Doped TiO_2 Photocatalyst[J];Chinese Journal of Catalysis;2004-10
4 CHEN Enwei,YIN Donghong~*,SONG Huijuan,GONG Liming,YU Ningya~*(Institute of Fine Catalysis and Synthesis,Hunan Normal University,Changsha 410081,Hunan,China);Preparation of Lanthanide Ions-Doped TiO_2 and Its Photocatalytic Activity for Imidazole Degradation[J];Chinese Journal of Catalysis;2006-04
5 TIAN Yuming,XU Mingxia~*,LIU Xiangzhi,GE Lei,ZHANG Ping(Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education,School of Materials Science and Engineering,Tianjin University,Tianjin 300072,China);Preparation and Photocatalytic Properties of Titania Nanowire Arrays with Shape of String of Candied Haws[J];Chinese Journal of Catalysis;2006-08
6 ZHENG Huarong,CUI Yanjuan,ZHANG Jinshui,DING Zhengxin,WANG Xinchen State Key Laboratory Breeding Base of Photocatalysis,Fuzhou University,Fuzhou 350002,Fujian,China;Influence of Pt Promoter on the Visible Light Photocatalytic Properties of N-Doped TiO_2[J];Chinese Journal of Catalysis;2011-01
7 LI Fanxiu~ 1,2 ,LU Xiaohua~1,MEI Ping~2(1 College of Environmental Science & Engineering, Huazhong University of Science & Technology,Wuhan 430074; 2 College of Chemical & Environmental Engineering, Yangtze University, Jingzhou 434023);Progress in Research on Effects of Metal Ion Dopants on Crystal Phase Transformation of TiO_2[J];Materials Review;2006-09
8 LI Fatang~ 1,2 , ZHAO Dishun~ 1,3 (1 School of Chemical Engineering, Tianjin University, Tianjin 300072; 2 College of Sciences, Hebei University of Science and Technology, Shijiazhuang 050018; 3 College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018);Advances of Preparation for Nanometer TiO_2 Powder by Sol-gel Method[J];Materials Review;2006-S2
9 Liu Fusheng1,2 Wang Sheng3 Wu Min1 Sun Yueming1(1School of Chemistry and Chemical Engineering,Southeast University,Nanjing 210096,China)(2Department of Chemistry and Materials Science,Nanjing Forestry University,Nanjing 210037,China)(3Institute of Chemistry and Chemical Engineering,Nanjing University of Technology,Nanjing 210009,China);Synthesis and characterization of perylene dye and its optical and thermal properties[J];Journal of Southeast University(Natural Science Edition);2008-06
10 HE Xiao-Yun, ZHENG Xi, CHEN Ri-Yao, CHEN Zhen(College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007,China);Photodegradation of Azo-dye by Y_2O_3/TiO_2 Loaded on Carboxymethyl Cellulose (CMC) Films[J];Journal of Fujian Normal University(Natural Science);2005-03
China Proceedings of conference Full-text Database 7 Hits
1 ZHANG Qing-long, SHEN Yi, LI Fei (College of Material Science and Chemical Engineering, China University of Geosciences, Wuhan 430074, China);Influence of Nano TiO_2 by Ag~+/Fe~(3+) Co-doping on Photocatalytic Degradation to Methyl Orange[A];[C];2007
2 Guan Xiurong~(1,2) Shao Zhongca~(2*) Tian Yanwen~1 (1.School of Materials and Metallurgy,Northeast University,Shenyang 110004,China;2.School of Environmental and Chemical Engineering,Shenyang Ligong University,Shenyang 110168,China);Preparing TiO_2 with Doping Rare Earth and Study of Their Photocatalysed Performance[A];[C];2008
3 Xia Huili, Zhang Tao, Xiao Dongchang, Zhuang Huisheng ( College of Environmental Science & Engineering, Donghua University, Shanghai 200051);Photocatalytic Degradation of Acid Blue over CuO-SnO_2 Nanocomposite Oxide Photocatalyst Under the Irridiation of Simulant Sunlight[A];[C];2005
4 ZHANG Junqing, FENG Derong (Material Engineering School, UIST Inner Mongolia. Baotou 014010. China;Baotou Tomorrow Technology Co. , Ltd, Baotou 014010,China);Study on the photocatalysis efficiency of degradation of p-nitraphenol by a praseodymium-doped nanometer TiO_2[A];[C];2005
5 CAO Linhong~(a,b),QU Yufeng~(a,b),XIE Dongmei~(a,c),and JING Chuanyong~c a State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials,Southwest University of Science and Technology,Mianyang 621010,China b Lab for Matter Characteristic Research at Extreme Condition,Southwest University of Science and Technology,Mianyang 621010,China c State Key Laboratory of Environmental Chemistry and Ecotoxicology,Research Center for Eco-Environmental Sciences,Chinese Academy of Sciences,Beijing 100085,China;Preparation and characterization of porous TiO_2 with La_2O_3 load[A];[C];2010
6 Liujun Xu~1,Ningning Yan~1,Zhongqi Zhu~1,Qingju Liu~1 (1 Yunnan Key laboratory of nanomaterials & technology,Yunnan University,Kunming 650091,China,;The Synthesis and Properties of Yb-doping nano TiO_2 Photocatalysts[A];[C];2011
7 Liujun XU,Ningning YAN,Zhongqi ZHU,Qingju LIU Yunnan Key Laboratory of Nanomaterials&Technology,Yunnan University,Kunming,China,650091;The Synthesis and Properties of Yb-Doping Nano TiO_2 Photocatalysts[A];[C];2011
【Secondary Citations】
Chinese Journal Full-text Database 1 Hits
1 LI Yuexiang, L Gongxuan, LI Shuben (State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, The Chinese Academy of Sciences, Lanzhou 730000, China);Photocatalytic Hydrogen Generation over Pt-TiO_2 with Oxalic Acid as Electron Donor[J];Chinese Journal of Catalysis;2001-02
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